Sulfide solid electrolyte particles, method for producing the same, and all-solid-state battery

    公开(公告)号:US11444320B2

    公开(公告)日:2022-09-13

    申请号:US16743204

    申请日:2020-01-15

    发明人: Keiichi Minami

    摘要: Provided are sulfide solid electrolyte particles which have sufficient ion conductivity and which are configured to suppress hydrogen sulfide generation, and an all-solid-state battery comprising the sulfide solid electrolyte particles. Disclosed are sulfide solid electrolyte particles comprising Li, P, S and a halogen as constituent elements and having a Li/P molar ratio of more than 3, wherein an oxygen/sulfur element ratio of a particle surface measured by XPS is 0.29 or more and 0.81 and less, and an oxygen/sulfur element ratio at a depth of 30 nm (in terms of a SiO2 sputter rate) from the particle surface measured by XPS, is 0.29 or less.

    Sulfide solid electrolyte particles and all-solid-state battery

    公开(公告)号:US11532837B2

    公开(公告)日:2022-12-20

    申请号:US16743061

    申请日:2020-01-15

    发明人: Keiichi Minami

    摘要: Provided are sulfide solid electrolyte particles which have sufficient ion conductivity and which are, when used in an all-solid-state battery, configured to suppress a resistance increase rate after charge-discharge cycles, and an all-solid-state battery comprising the sulfide solid electrolyte particles. The sulfide solid electrolyte particles may be sulfide solid electrolyte particles comprising a sulfide solid electrolyte that comprises Li, P, S and a halogen as constituent elements, wherein an oxygen/sulfur element ratio of a particle surface measured by XPS, is 0.79 or more and 1.25 or less, and an oxygen/sulfur element ratio at a depth of 30 nm (in terms of a SiO2 sputter rate) from the particle surface measured by XPS, is 0.58 or less.

    Sulfide solid electrolyte particles, method for producing the same, and all-solid-state battery

    公开(公告)号:US11489196B2

    公开(公告)日:2022-11-01

    申请号:US16743204

    申请日:2020-01-15

    发明人: Keiichi Minami

    摘要: Provided are sulfide solid electrolyte particles which have sufficient ion conductivity and which are configured to suppress hydrogen sulfide generation, and an all-solid-state battery comprising the sulfide solid electrolyte particles. Disclosed are sulfide solid electrolyte particles comprising Li, P, S and a halogen as constituent elements and having a Li/P molar ratio of more than 3, wherein an oxygen/sulfur element ratio of a particle surface measured by XPS is 0.29 or more and 0.81 and less, and an oxygen/sulfur element ratio at a depth of 30 nm (in terms of a SiO2 sputter rate) from the particle surface measured by XPS, is 0.29 or less.