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公开(公告)号:US20170250409A1
公开(公告)日:2017-08-31
申请号:US15444517
申请日:2017-02-28
Applicant: UNIVERSITY OF YAMANASHI
Inventor: Katsuyoshi KAKINUMA , Makoto UCHIDA , Akihiro IIYAMA
CPC classification number: H01M4/921 , C22C5/04 , H01M4/925 , H01M2008/1095 , H01M2250/20 , Y02T90/32
Abstract: To spread the use of catalysts for fuel cells, there is a demand to develop a catalyst that uses less Pt and has a high power generation efficiency. An electrode catalyst includes a support particle containing a metal oxide and a precious-metal alloy supported on the support particle. The support particle includes multiple branches, a hole between the branches, and a pore. The pore is surrounded by the branches and the hole. The precious-metal alloy includes a precious metal element and at least one or more transition elements.
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公开(公告)号:US20240266554A1
公开(公告)日:2024-08-08
申请号:US18294266
申请日:2022-08-04
Applicant: UNIVERSITY OF YAMANASHI , Nikki-Universal Co., Ltd.
Inventor: Toshihiro MIYAO , Hanako NISHINO , Makoto UCHIDA , Akihiro IIYAMA , Naoto KOIZUMI , Kazuya SHIBANUMA , Naoki TONE
CPC classification number: H01M4/926 , C01B32/05 , C01P2006/16 , C01P2006/40 , H01M2004/8689
Abstract: A supported metal catalyst, including: a support that is a collective body of conductive particles; and dispersed active metal particles supported on the conductive particles. The conductive particles include a plurality of pores; an average entrance pore diameter of the pores is 1 to 20 nm; a standard deviation of the average entrance pore diameter is equal to or less than 50% of the average entrance pore diameter; a number fraction of the active metal particles supported in a surface layer region of the conductive particles divided by a total number of the active metal particles is equal to or more than 50%; the surface layer region is a region on a surface of the conductive particles or a region in the pores within a depth of 15 nm from the surface; and an average interparticle distance of the active metal particles is 5 to 20 nm.
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公开(公告)号:US20200164349A1
公开(公告)日:2020-05-28
申请号:US16632657
申请日:2018-07-18
Applicant: UNIVERSITY OF YAMANASHI
Inventor: Katsuyoshi KAKINUMA , Makoto UCHIDA , Akihiro IIYAMA
Abstract: A carrier powder is thermodynamically stable and conductivity can be easily provided thereto. A carrier powder includes an aggregate of carrier fine particles; wherein: the carrier fine particles include a chained portion structured by fusion bonding a plurality of crystallites into a chain; the carrier fine particles contain titanium oxide; and a ratio of anatase phase/rutile phase of the titanium oxide of the carrier powder is 0.2 or lower.
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公开(公告)号:US20230321633A1
公开(公告)日:2023-10-12
申请号:US18042531
申请日:2021-08-20
Applicant: UNIVERSITY OF YAMANASHI
Inventor: Katsuyoshi KAKINUMA , Makoto UCHIDA , Akihiro IIYAMA
CPC classification number: B01J23/14 , B01J35/1014 , B01J35/0013 , B01J23/42 , B01J35/026 , B01J35/0033
Abstract: A supported metal catalyst in which an electric conductivity is enhanced. The supported metal catalyst includes a support powder; and metal fine particles supported by the support powder. The support powder is an aggregate of support fine particles; the support fine particles are provided with a chained portion structured by a plurality of crystallites being fusion-bonded to form a chain; the support fine particles are structured with a metal oxide; and the supported amount of metal fine particles per unit area of the surface area of the support powder calculated based on sphere approximation is 3.4 to 13.7 (mg/m2).
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公开(公告)号:US20230085417A1
公开(公告)日:2023-03-16
申请号:US17795027
申请日:2021-02-05
Applicant: UNIVERSITY OF YAMANASHI , NIKKI-UNIVERSAL CO., LTD.
Inventor: Toshihiro MIYAO , Hanako NISHINO , Kazutoshi HIGASHIYAMA , Makoto UCHIDA , Akihiro IIYAMA , Kazuya SHIBANUMA , Naoto KOIZUMI
Abstract: The present invention provides a supported metal catalyst with excellent effectiveness factor of active metal particles which are also free from deactivation by contacting with ionomer.
According to the present invention, provided is a supported metal catalyst, comprising a support that is a collective body of conductive particles; and dispersed active metal particles supported on the conductive particles, wherein the conductive particles include a plurality of pores, an average entrance pore diameter of the pores is 1 to 20 nm, a standard deviation of the average entrance pore diameter is equal to or less than 50% of the average entrance pore diameter, a number fraction of the active metal particles supported in a surface layer region of the conductive particles divided by the total number of the active metal particles is equal to or more than 50%, and the surface layer region is a region on a surface of the conductive particles or a region in the pores within a depth of 15 nm from the surface.-
公开(公告)号:US20230049745A1
公开(公告)日:2023-02-16
申请号:US17967180
申请日:2022-10-17
Applicant: UNIVERSITY OF YAMANASHI
Inventor: Katsuyoshi KAKINUMA , Makoto UCHIDA , Akihiro IIYAMA
IPC: H01M4/92 , H01M8/1004
Abstract: The carrier metal catalyst achieves suppression of internal resistance of a fuel cell. A carrier metal catalyst includes: a carrier powder; and metal fine particles supported on the carrier powder; wherein: the carrier powder is an aggregates of carrier fine particles; the carrier fine particles includes a chained portion structured by a plurality of crystallites being fusion bonded to form a chain; the carrier fine particles include titanium oxide; the carrier fine particles are doped with an element having a valence different from a valence of titanium; the titanium oxide of the carrier powder has an anatase phase/rutile phase ratio of 0.2 or lower; the metal fine particles have a mean particle size of 3 to 10 nm; the metal fine particles include platinum; and a cell resistance measured under standard conditions of a fuel cell prepared using the carrier metal catalyst is 0.090 Ωcm·2 or lower.
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公开(公告)号:US20250003089A1
公开(公告)日:2025-01-02
申请号:US18711328
申请日:2022-11-22
Applicant: UNIVERSITY OF YAMANASHI
Inventor: Katsuyoshi KAKINUMA , Makoto UCHIDA , Akihiro IIYAMA
IPC: C25B11/037 , C25B1/04 , C25B9/19 , C25B9/40 , C25B11/054 , C25B11/067 , C25B11/081
Abstract: An electrode catalyst, including: a support powder; and active particles supported on the support powder. The support powder is an aggregate of support fine particles having a chained portion structured by a plurality of crystallites being fusion-bonded to form a chain; the support fine particles contain a metal oxide doped with a dopant element; the metal oxide contains tin as a main element; the active particles contain a platinum group oxide containing a platinum group element; and a loading ratio of the active particles is 25 mass % or higher.
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公开(公告)号:US20240055616A1
公开(公告)日:2024-02-15
申请号:US18259304
申请日:2021-12-23
Applicant: UNIVERSITY OF YAMANASHI , NIHON KAGAKU SANGYO CO., LTD.
Inventor: Katsuyoshi KAKINUMA , Akihiro IIYAMA , Makoto UCHIDA , Sumitaka WATANABE , Isao AMEMIYA
CPC classification number: H01M4/925 , H01M4/9075
Abstract: The present invention provides a supported metal catalyst that has an electric conductivity acceptable as a catalyst and can suppress the generation of hydrogen peroxide.
According to the present invention, provided is a supported metal catalyst, comprising: a support powder; and metal fine particles supported on the support powder, wherein: the support powder is an aggregate of support fine particles; the support fine particles have a chained portion structured by a plurality of crystallites being fusion-bonded to form a chain; the support fine particles are structured with a metal oxide; the metal oxide contains cerium; and an electric conductivity of the supported metal catalyst is 10−4 S/cm or higher.-
公开(公告)号:US20230006219A1
公开(公告)日:2023-01-05
申请号:US17782964
申请日:2020-12-10
Applicant: UNIVERSITY OF YAMANASHI , NIHON KAGAKU SANGYO CO., LTD.
Inventor: Katsuyoshi KAKINUMA , Makoto UCHIDA , Akihiro IIYAMA , Isao AMEMIYA , Chisato ARATA , Sumitaka WATANABE
IPC: H01M4/92 , C25B11/067
Abstract: A support and metal catalyst with improved electric conductivity is provided. A support and metal catalyst, including: a support powder; and metal fine particles supported on the support powder; wherein: the support powder is an aggregate of support fine particles; the support fine particles have a chained portion structured by a plurality of crystallites being fusion bonded to form a chain; the support fine particles are structured with metal oxide; and the metal oxide is doped with a dopant element, and an atomic ratio of titanium with respect to total of titanium and tin is 0.30 to 0.80, is provided.
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公开(公告)号:US20200243872A1
公开(公告)日:2020-07-30
申请号:US16774242
申请日:2020-01-28
Applicant: UNIVERSITY OF YAMANASHI
Inventor: Katsuyoshi KAKINUMA , Makoto UCHIDA , Akihiro IIYAMA
IPC: H01M4/92 , H01M8/1004
Abstract: The carrier metal catalyst achieves suppression of internal resistance of a fuel cell. A carrier metal catalyst includes: a carrier powder; and metal fine particles supported on the carrier powder; wherein: the carrier powder is an aggregates of carrier fine particles; the carrier fine particles includes a chained portion structured by a plurality of crystallites being fusion bonded to form a chain; the carrier fine particles include titanium oxide; the carrier fine particles are doped with an element having a valence different from a valence of titanium; the titanium oxide of the carrier powder has an anatase phase/rutile phase ratio of 0.2 or lower; the metal fine particles have a mean particle size of 3 to 10 nm; the metal fine particles include platinum; and a cell resistance measured under standard conditions of a fuel cell prepared using the carrier metal catalyst is 0.090 Ω·cm2 or lower.
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