摘要:
A vulcanizable rubber composition comprising (1) 100 parts by weight of a polymer composition comprising(I) a vinylidene fluoride resin,(II) at least one rubber selected from the group consisting of acrylic rubbers, .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubbers and hydrides of .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubbers, said acrylic rubber consisting of (A) 30 to 99.9% by weight of an alkyl acrylate and/or an alkoxy-substituted alkyl acrylate, (B) 0.1 to 10% by weight of a crosslinkable monomer and (C) 0 to 70% by weight of another ethylenically unsaturated compound copolymerizable with (A) and (B) (the sum of (A), (B) and (C) is 100% by weight) and said .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubber consisting of (D) 10 to 60% by weight of an .alpha.,.beta.-unsaturated nitrile, (E) 15 to 90% by weight of a conjugated diene and (F) 0 to 75% by weight of another ethylenically unsaturated compound copolymerizable with (D) and (E) (the sum of (D), (E) and (F) is 100% by weight, and(III) another blendable polymer,wherein the weight ratio of (I)/[(II)+(III)] is 5/95 to 60/40 and the weight ratio of (II)/(III) is 100/0 to 50/50, and (2) 0 to 40 parts by weight of a plasticizer. Said rubber composition excels not only in heat resistance, gasoline resistance and sour gasoline resistance but also in gasohol resistance and sour gasohol resistance and further is good in tensile strength, elongation and balance between gasoline resistance and low-temperature resistance. Therefore, said rubber composition can be used in the fluid-contacting surface of a diaphragm and can be suitably used as an inner tube of a fuel hose.
摘要:
A vulcanizable rubber composition comprising (1) 100 parts by weight of a polymer composition comprising(I) a vinylidene fluoride resin,(II) at least one rubber selected from the group consisting of acrylic rubbers, .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubbers and hydrides of .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubbers, said acrylic rubber consisting of (A) 30 to 99.9% by weight of an alkyl acrylate and/or an alkoxy-substituted alkyl acrylate, (B) 0.1 to 10% by weight of a crosslinkable monomer and (C) 0 to 70% by weight of another ethylenically unsaturated compound copolymerizable with (A) and (B) (the sum of (A), (B) and (C) is 100% by weight) and said .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubber consisting of (D) 10 to 60% by weight of an .alpha.,.beta.-unsaturated nitrile, (E) 15 to 90% by weight of a conjugated diene and (F) 0 to 75% by weight of another ethylenically unsaturated compound copolymerizable with (D) and (E) (the sum of (D), (E) and (F) is 100% by weight, and(III) another blendable polymer,wherein the weight ratio of (I)/[(II)+(III)] is 5/95 to 60/40 and the weight ratio (II)/(III) is 100/0 to 50/50, and (2) 0 to 40 parts by weight of a plasticizer. Said rubber composition excels not only in heat resistance, gasoline resistance and sour gasoline resistance but also in gasohol resistance and sour gasohol resistance and further is good in tensile strength, elongation and balance between gasoline resistance and low-temperature resistance. Therefore, said rubber composition can be used in the fluid-contacting surface of a diaphragm and can be suitably used as an inner tube of a fuel hose.
摘要:
A resin composition comprising 100 parts by weight of a thermosetting resin and 1 to 100 parts by weight of a functional, rubbery copolymer containing among the monomer units which constitute the copolymer, at least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, said copolymer being prepared by one of three emulsion polymerization processes in which a nonionic surface active agent and/or ionic surface active agent is employed as the emulsifying agent.
摘要:
A multi-component copolymer rubber consisting essentially of (A) 20 to 69.5% by weight of a cyano-substituted alkyl (meth)acrylate, (B) 30 to 79.5% by weight of an alkyl acrylate, (C) 0.5 to 10% by weight of a crosslinkable monomer and (D) 0 to 10% by weight of other ethylenically unsaturated monomer copolymerizable with (A), (B) and (C), excels in heat resistance, ozone resistance, sour gasoline resistance and sour gasohol resistance. These properties of said multi-component copolymer rubber can further be improved by incorporating into the copolymer rubber a crosslinking agent, a metal salt, a vinylidene fluoride polymer, a vinyl chloride resin or other multi-component copolymer rubber.
摘要:
A heat-aging-resistant rubbery polymer composition comprising a rubbery polymer, at least one compound selected from the group consisting of diphenylamine derivatives and phenol derivatives as an age resister for said rubbery polymer, and polyalkylene ether glycol having an average molecular weight of 100-5,000, and optionally a compound represented by the formula, ##STR1## in which R is alkyl having 10 to 20 carbon atoms. Preferably, said at least one compound selected from the group consisting of diphenylamine derivatives and phenol derivatives is chemically linked to said rubbery polymer as a part of the molecular chain. Said rubbery polymer composition is unexpectedly superior in heat-aging-resistance to a composition consisting only of said rubbery polymer and said age resister or a composition consisting only of said rubbery polymer and said polyalkylene ether glycol.
摘要:
A rubber composition consisting essentially of 5-99 parts by weight of a thermosetting resin and 94-1 parts by weight of one of the following functional rubber-like copolymers (I) to (III) having a Mooney viscosity ML.sub.1+4.sup.100 of 20-120:(I) a functional rubber-like copolymer consisting of 1-20% by weight of a monomer having epoxy groups, hydroxyl groups or amino groups, 15-50% by weight of acrylonitrile and 40-80% by weight of butadiene and/or isoprene as monomer units constituting the polymer,(II) a functional rubber-like copolymer consisting of 1-20% by weight of a monomer having epoxy groups, hydroxyl groups or amino groups, 40-99% by weight of an alkyl (meth)acrylate and/or an alkoxyalkyl (meth)acrylate and 0-30% by weight of monomers copolymerizable therewith other than butadiene and isoprene, as the monomer units constituting the polymer, and(III) a functional rubber-like copolymer consisting of 1-20% by weight of a monomer having epoxy groups, hydroxyl groups or amino groups, 15-50% by weight of acrylonitrile, 20-60% by weight of butadiene and/or isoprene and 5-65% by weight of an alkyl (meth)acrylate and/or an alkoxy (meth)acrylate as the monomer units constituting the polymer.Said functional rubber copolymer may include 10% by weight or less of a polyfunctional monomer as a monomer unit constituting the polymer. In this case, the ratio of the thermosetting resin to the functional rubber-like copolymer is 50-99 parts by weight of the former to 1-50 parts by weight of the latter.
摘要:
A rubbery polymer composition comprising (A) a copolymer consisting of 45 to 79% by weight of butadiene, 20 to 55% by weight of acrylonitrile and 0.1 to 10% by weight of at least one compound selected from the group consisting of amide compounds having the formula (I) shown below and imide compounds having the formula (II) shown below, and (B) a vinyl chloride polymer, the weight proportion of said (A) to said (B) being 95-40 to 5-60. Said composition is resistant to ozone and oil, and moreover, is excellent in heat aging resistance and sour gasoline resistance when used in an oil, in a solvent or in the atmosphere at a high temperature: ##STR1## wherein R.sub.1 and R.sub.2 individually represent hydrogen, chlorine, bromine, or alkyl having 1 to 12 carbon atoms; R.sub.3 represents hydrogen, or alkyl having 1 to 4 carbon atoms; and R.sub.4 represents hydrogen, alkyl having 1 to 4 carbon atoms, or aryl having 6 to 12 carbon atoms, ##STR2## wherein R.sub.1, R.sub.2 and R.sub.3 are as defined above, and two R's may be the same or different.
摘要:
A conjugated diene copolymer comprising (A) 10 to 60 mole % of a conjugated diene compound unit, (B) 5 to 50 mole % of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid unit, (C) 0.1 to 20 mole % of a polyfunctional alkenyl compound unit, (D) 0 to 10 mole % of a diene compound unit having cyclic carbon-carbon double bonds and (E) 0 to 80 mole % of a monoolefinically unsaturated compound unit, the sum of the amounts of units (A), (B), (C), (D) and (E) being 100 mole %, said copolymer having an intrinsic viscosity [.eta.] of 0.01 to 3.0 dl/g as measured at 30.degree. C. in dimethylformamide. The copolymer is soluble in aqueous alkali solutions, excels in processability and photosetting property, and has excellent rubber elasticity and transparency even after photosetting. Accordingly, a photosensitive composition comprising the copolymer, a photopolymerizable unsaturated monomer and a photosensitizer can greatly improve the complicated process for the production of conventional rubber relief plates of flexographic printing, and shorten the production time.
摘要:
A multi-component copolymer rubber consisting essentially of (A) 20 to 69.5% by weight of a cyano-substituted alkyl (meth)acrylate, (B) 30 to 79.5% by weight of an alkyl acrylate, (C) 0.5 to 10% by weight of a crosslinkable monomer and (D) 0 to 10% by weight of other ethylenically unsaturated monomer copolymerizable with (A), (B) and (C), excels in heat resistance, ozone resistance, sour gasoline resistance and sour gasohol resistance. There properties of said multi-component copolymer rubber can further be improved by incorporating into the copolymer rubber a crosslinking agent, a metal salt, a vinylidene fluoride polymer, a vinyl chloride resin or other multi-component copolymer rubber.
摘要:
An acrylic rubber obtainable by copolymerizing a monomer mixture of:(A) 70 to 99.99% by weight of at least one compound selected from the group consisting of alkyl acrylates and alkoxyalkyl acrylates,(B) 0.01 to 10% by weight of at least one compound represented by the general formula: ##STR1## wherein R.sup.1 is a hydrogen atom or a methyl group; X is a hydrogen atom, --COOR.sup.6 (R.sup.6 is an alkyl group having 1-10 carbon atoms or an alkoxyalkyl group having 2-14 carbon atoms), or ##STR2## R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen atoms or groups having 1-10 carbon atoms whose carbon atom adjacent to C.dbd.C has no hydrogen; R.sup.5 is a group having 1-10 carbon atoms whose carbon atom adjacent to C.dbd.C has no hydrogen; Y is ##STR3## or --O--; and n is 1 or 0, and (C) 0-20% by weight of at least one compound selected from the group consisting of other unsaturated compounds of the vinyl type, vinylidene type and vinylene type, in the presence of a radical polymerization initiator. Said acrylic rubber, when crosslinked with a crosslinking agent, gives a cured article having good heat resistance and a good compression set property and accordingly suitable for use as a hose or a sealing material.