公开(公告)号：US20110178187A1

公开(公告)日：2011-07-21

申请号：US13121553

申请日：2009-07-29

申请人： Hans Kopetsch

发明人： Hans Kopetsch

IPC分类号： C07C29/152

CPC分类号： C07C29/1516 ,  B01D5/009 ,  B01D5/0093 ,  B01J8/067 ,  B01J2208/00274 ,  B01J2219/0004 ,  C07C31/04

摘要： For producing methanol from a synthesis gas containing hydrogen and carbon oxides the synthesis gas is passed through a first, preferably water-cooled reactor in which a part of the carbon oxides is catalytically converted to methanol, and the resulting mixture containing synthesis gas and methanol vapor is supplied to a second, preferably gas-cooled reactor in which a further part of the carbon oxides is converted to methanol. The mixture withdrawn from the first reactor is guided through a gas/gas heat exchanger in which the mixture is cooled to a temperature below its dew point. Subsequently, methanol is separated from the gas stream in a methanol separator and withdrawn, while the remaining gas stream is supplied to the second reactor.

摘要翻译： 为了从含有氢和碳氧化物的合成气中生产甲醇，合成气通过第一个，优选水冷却的反应器，其中一部分碳氧化物被催化转化成甲醇，所得混合物含有合成气和甲醇蒸汽 被供应到第二，优选气冷反应器，其中另外部分的碳氧化物转化成甲醇。 从第一反应器排出的混合物被引导通过气体/气体热交换器，其中将混合物冷却至低于其露点的温度。 随后，在甲醇分离器中将甲醇从气流中分离出并取出，同时将剩余的气流供应到第二反应器。

公开(公告)号：US20110126542A1

公开(公告)日：2011-06-02

申请号：US12601460

申请日：2008-05-23

申请人： Gerhard Schmitt

发明人： Gerhard Schmitt

IPC分类号： F02C1/00 ,  C21B13/00

CPC分类号： F02C3/28 ,  C10J3/00 ,  C10J3/82 ,  C10J2300/093 ,  C10J2300/16 ,  C10K1/00 ,  C10K1/004 ,  C10K1/165 ,  C21B13/0073 ,  C21B2100/28 ,  C21B2100/282 ,  C21B2100/42 ,  C21B2100/60 ,  C21B2100/62 ,  C21B2100/64 ,  C21C2100/06 ,  Y02P10/122 ,  Y02P10/126 ,  Y02P10/128 ,  Y02P10/132 ,  Y02P10/136

摘要： Upon cooling to 15 to 45° C., a process for the treatment of raw product gas generated by pressure gasification of solid fuels comprises the removal of HCN and NH3 in a preliminary stage, of H2S and COS and possibly other sulfur-containing compounds in a first stage and of CO2 in a second stage by physisorption with cold oxygenate, and the pure product gas is supplied to the direct reduction of iron ore as reduction gas and/or as fuel gas. An improvement of the process consists in that recycle gas loaded with CO2 and steam, which is branched off from the circuit of the recycle gas of the direct reduction of iron ore, is admixed to the desulfurized product gas upon removal of the steam contained therein.

摘要翻译： 在冷却至15至45℃时，用于处理通过固体燃料的压力气化产生的原始气体的方法包括在初级阶段除去H 2 S和COS以及可能的其它含硫化合物中的HCN和NH 3 第一阶段和第二阶段的CO2通过用冷的含氧化合物进行物理吸附，并且纯产物气体被供应到作为还原气体和/或燃料气体的铁矿石的直接还原。 该方法的改进在于，当除去其中包含的蒸汽之后，装载有来自铁矿石直接还原的再循环气体回路的CO 2和蒸汽的循环气体与脱硫产物气体混合。

公开(公告)号：US20110000366A1

公开(公告)日：2011-01-06

申请号：US12744098

申请日：2008-09-05

申请人： Ulrich Koss ,  Manfred Meyer ,  Alexander Schriefl

发明人： Ulrich Koss ,  Manfred Meyer ,  Alexander Schriefl

IPC分类号： B01D53/14 ,  F25D3/00

CPC分类号： B01D53/002 ,  B01D53/77 ,  B01D2256/22 ,  B01D2257/102 ,  B01D2257/108 ,  B01D2257/304 ,  B01D2257/308 ,  B01D2257/502 ,  C01B3/506 ,  C01B2203/025 ,  C01B2203/04 ,  C01B2203/0475 ,  C10J3/82 ,  C10J2300/1615 ,  C10J2300/1621 ,  C10L3/10 ,  C10L3/102 ,  F25J3/0223 ,  F25J3/0266 ,  F25J3/08 ,  F25J2200/02 ,  F25J2200/70 ,  F25J2215/04 ,  F25J2220/82 ,  F25J2245/02 ,  F25J2270/90 ,  F25J2290/12 ,  Y02C10/06 ,  Y02C10/12 ,  Y02P20/152

摘要： From the CO2-containing stream of process gas obtained in a process for the treatment of a CO2-containing stream of process gas, which is obtained in the production of pure synthesis gas from raw gas in the partial oxidation of heavy oils, petroleum coke or wastes, or in the gasification of coal, or when processing natural gas or accompanying natural gas, CO2 is removed physisorptively or chemisorptively, and the solvent loaded with CO2 is expanded to a lower pressure for the desorption of CO2. In order to generate CO2 as pure as possible, the contaminated CO2 is condensed to at least 60 bar[a] or below its critical temperature to at least 70 bar[a], and the impurities contained in the liquid CO2 are removed by stripping with gaseous CO2 guided in counterflow.

摘要翻译： 从在重油的部分氧化中生产来自原始气体的纯合成气中获得的处理气体的处理气体过程中获得的含二氧化碳气流，石油焦炭或 或者在煤的气化中，或在加工天然气或伴随的天然气时，以物理或化学吸附的方式去除二氧化碳，将负载二氧化碳的溶剂膨胀到较低的压力以解吸二氧化碳。 为了产生尽可能纯净的二氧化碳，被污染的CO 2会冷凝至至少60巴[a]或低于其临界温度至至少70巴[a]，并且通过汽提除去液态CO 2中所含的杂质 逆流中引导的气态CO 2。

公开(公告)号：US07589227B2

公开(公告)日：2009-09-15

申请号：US10571476

申请日：2004-07-16

申请人： Henning Buchold ,  Jürgen Eberhardt ,  Ulrich Wagner ,  Hans-Jörg Wölk

发明人： Henning Buchold ,  Jürgen Eberhardt ,  Ulrich Wagner ,  Hans-Jörg Wölk

IPC分类号： C07C69/96

CPC分类号： C07C68/00 ,  C07C69/96

摘要： The invention relates to a method for the production of monomer organic carbonates, wherein urea, substituted urea, a salt or an ester of carbamide acid or one of the N-substituted derivatives thereof is reacted in a first step in a polyalkylene glycol, a polyester-polyol or a polyether-polyol of general formula (I), wherein R represents a linear or branched alkylene group having 2-12 carbon atoms and n is a number between (2) and (20), or in a completely or partially hydrolysed polyvinyl alcohol of general formula (II) wherein R′ represents an alkyl group, an aryl group or an acyl group having 1-12 carbon atoms, p and q are numbers between 1 and 20, or in mixtures of said compounds in the presence of a catalyst facilitating the separation of ammonia in order to form a mixture containing carbonates and carbamates, the ammonia becomes free or the amine is removed form the reaction mixture by means of a strip gas. In a second reaction step (transesterification), the mixture containing the carbonates and carbamates is reacted with a monomer alcohol or a phenol whereby monomer carbonates are formed and polymer polyalcohols of formulae (I) or (II) are reformed. HO—RnOH  (I)

摘要翻译： 本发明涉及一种制备单体有机碳酸酯的方法，其中脲，取代的脲，脲或其中的一种或多种N-取代的衍生物的脲或其酯之一在第一步骤中在聚亚烷基二醇，聚酯 - 多元醇或通式（I）的聚醚多元醇，其中R表示具有2-12个碳原子的直链或支链亚烷基，n是（2）和（20）之间的数，或者在完全或部分水解的 通式（II）的聚乙烯醇，其中R'表示烷基，芳基或具有1-12个碳原子的酰基，p和q是1至20之间的数字，或所述化合物在存在下的 促进氨分离以形成含有碳酸酯和氨基甲酸酯的混合物的催化剂，氨变得游离，或者通过带状气体从反应混合物中除去胺。 在第二反应步骤（酯交换）中，将含有碳酸酯和氨基甲酸酯的混合物与单体醇或苯酚反应，由此形成单体碳酸酯，并且将式（I）或（II）的聚合物多元醇重整。 <？in-line-formula description =“In-line Formulas”end =“lead”？> H OR nOH（I）<？ in-line-formula description =“In-line Formulas”end =“tail”？>