Abstract:
The invention provides a solid oxide fuel cell device and a fuel cell system incorporating a plurality of the fuel devices, each device including an elongate substrate having a first cold end region adjacent a first end, a second cold end region adjacent a second end, and a hot reaction zone between the first and second cold end regions, wherein the hot reaction zone is configured to be heated to an operating reaction temperature, and the first and second cold end regions are configured to remain at a low temperature below the operating reaction temperature. A fuel inlet is positioned in the first cold end region with a respective fuel outlet positioned in either the hot reaction zone or the second cold end region, and an elongate fuel passage is coupled therebetween at least partially extending through the hot reaction zone. Similarly, an oxidizer inlet is positioned in the second cold end region with a respective oxidizer outlet positioned in either the hot reaction zone or the first cold end region, and an elongate oxidizer passage is coupled therebetween at least partially extending through the hot reaction zone in parallel and opposing relation to the elongate fuel passage. An anode is positioned adjacent the fuel passage in the hot reaction zone and is electrically coupled to a first exterior contact surface on the elongate substrate in at least one of the first and second cold end regions. A cathode is positioned adjacent the oxidizer passage in the hot reaction zone and is electrically coupled to a second exterior contact surface on the elongate substrate in at least one of the first and second cold end regions. Electrical connections are made to the exterior contact surfaces.
Abstract:
A method of making a monolithic or essentially monolithic single layer capacitor with high structural strength and capacitance. Sheets of green-state ceramic dielectric material and ceramic/metal composite material are laminated together, diced into individual chips, and fired to sinter the ceramic together. The composite material may contain an amount of metal sufficient to render the composite conductive whereby the composite may be used for one or both electrodes and for mounting the capacitor to the pc board. Alternatively, the composite material may contain an amount of metal insufficient to render the composite conductive but sufficient to act as seed points for an electroplating process wherein the composite is preferentially coated with conductive metal, and the coated composite is mounted to the pc board and the coating provides an electrical connection to an internal electrode. Vertically-oriented surface mountable capacitors and hybrid capacitors are provided.
Abstract:
A capacitor including at least one interior metallization plane or plate and a multiplicity of vias for forming multiple redundant electrical connections within the capacitor. Series capacitors are provided having at least two interior plates redundantly electrically connected to at least two respective exterior plates. R-C devices are provided having multiple redundant vias filled with resistor material and/or conductor material to provide a resistor either in series with or parallel to a capacitor. Capacitors and R-C devices are provided having end terminations for applying voltage differential. Further, a method for making single capacitors, multiple parallel array capacitors, series capacitors and R-C devices is provided in which the chips are formed from the bottom up.
Abstract:
A monolithic or essentially monolithic single layer capacitor with high structural strength and capacitance. Sheets of green-state ceramic dielectric material and ceramic/metal composite material are laminated together, diced into individual chips, and fired to sinter the ceramic together. The composite material may contain an amount of metal sufficient to render the composite conductive whereby the composite may be used for one or both electrodes and for mounting the capacitor. Alternatively, the composite material may contain an amount of metal insufficient to render the composite conductive but sufficient to act as seed points for an electroplating process wherein the composite is preferentially coated with conductive metal, the coated composite is mounted, and the coating provides an electrical connection to an internal electrode. Vertically-oriented surface mountable capacitors and hybrid capacitors are provided.
Abstract:
The invention provides solid oxide fuel cell devices and systems, each including an elongate substrate having an active end region for heating to an operating reaction temperature, and a non-active end region that remains at a low temperature below the operating reaction temperature when the active end region is heated. An electrolyte is disposed between anodes and cathodes in the active end region, and the anodes and cathodes each have an electrical pathway extending to an exterior surface in the non-active end region for electrical connection at low temperature. The system further includes the devices positioned with their active end regions in a hot zone chamber and their non-active end regions extending outside the chamber. A heat source is coupled to the chamber to heat the active end regions to the operating reaction temperature, and fuel and air supplies are coupled to the substrates in the non-active end regions.
Abstract:
A fuel cell device is prepared by dispensing and drying electrode and ceramic pastes around two pluralities of removable physical structures to form electrode layers having constant width and a shape that conforms lengthwise to a curvature of the physical structures. An electrolyte ceramic layer is positioned between electrode layers, forming an active cell portion where anode is in opposing relation to cathode with electrolyte therebetween, and passive cell portions where ceramic is adjacent the active cell portion. The layers are laminated, the physical structures pulled out, and the lamination sintered to form an active cell with active passages in anodes and cathodes and passive support structure with passive passages in ceramic. End portions of at least one of the two pluralities of physical structures are curved away from the same end portion of the other of the two pluralities resulting in a split end in the fuel cell device.
Abstract:
Fuel cell devices and fuel cell systems are provided. The fuel cell devices may include one or more active layers containing active cells that are connected electrically in series. The active cells include anodes and cathodes spaced apart along the length, with each including a porous portion and a non-porous conductor portion. The active cells reside between opposing porous anode and cathode portions. The electrical series connections between active cells are made between the non-porous conductor portions. In certain embodiments, the electrical series connections are made by direct contact between the non-porous conductor portions. In certain embodiments, the electrical series connections are made by non-porous conductive vias or elements that extend through an intervening support structure that separates the non-porous anode conductor portions from the non-porous cathode conductor portions.
Abstract:
Fuel cell devices and systems are provided. In certain embodiments, the devices include a ceramic support structure having a length, a width, and a thickness with the length direction being the dominant direction of thermal expansion. A reaction zone having at least one active layer therein is spaced from the first end and includes first and second opposing electrodes, associated active first and second gas passages, and electrolyte. The active first gas passage includes sub-passages extending in the y direction and spaced apart in the x direction. An artery flow passage extends from the first end along the length and into the reaction zone and is fluidicly coupled to the sub-passages of the active first gas passage. The thickness of the artery flow passage is greater than the thickness of the sub-passages. In other embodiments, fuel cell devices include second sub-passages for the active second gas passage and a second artery flow passage coupled thereto, and extending from either the first end or the second end into the reaction zone. In yet other embodiments, one or both electrodes of a fuel cell device are segmented.
Abstract:
The invention provides tubular solid oxide fuel cell devices and a fuel cell system incorporating a plurality of the fuel devices, each device including an elongate tube having a reaction zone for heating to an operating reaction temperature, and at least one cold zone that remains at a low temperature below the operating reaction temperature when the reaction zone is heated. An electrolyte is disposed between anodes and cathodes in the reaction zone, and the anode and cathode each have an electrical pathway extending to an exterior surface in a cold zone for electrical connection at low temperature. In one embodiment, the tubular device is a spiral rolled structure, and in another embodiment, the tubular device is a concentrically arranged device. The system further includes the devices positioned with their reaction zones in a hot zone chamber and their cold zones extending outside the hot zone chamber. A heat source is coupled to the hot zone chamber to heat the reaction zones to the operating reaction temperature, and fuel and air supplies are coupled to the tubes in the cold zones.
Abstract:
Two active cell structures are prepared each comprising anode/electrolyte/cathode layers, each anode and cathode layer having embedded spaced-apart physical structures therein. Two interconnect sublayers are prepared, each comprising a layer of non-conductive material with holes formed therein and a conductor layer formed on one surface. The sublayers are placed together with the conductor layers in contact and with the holes offset to form an interconnect layer, which is then stacked between the two active cell structures. The multi-layer stack is laminated together and the anode layer of one active cell structure and the cathode layer of the other active cell structure fill the adjacent holes in the interconnect layer. The physical structures are pulled out to reveal embedded gas passages, and the multi-layer stack is sintered to form two active cells connected in series by the interconnect layer.