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    Cyclohexenone oxime ethers
    92.
    发明授权
    Cyclohexenone oxime ethers 失效
    环己烯酮肟醚

    公开(公告)号：US5604183A

    公开(公告)日：1997-02-18

    申请号：US523682

    申请日：1995-09-05

    申请人： Ulf Misslitz ,  Norbert Meyer ,  Juergen Kast ,  Matthias Bratz ,  Albrecht Harreus ,  Helmut Walter ,  Karl-Otto Westphalen ,  Matthias Gerber

    发明人： Ulf Misslitz ,  Norbert Meyer ,  Juergen Kast ,  Matthias Bratz ,  Albrecht Harreus ,  Helmut Walter ,  Karl-Otto Westphalen ,  Matthias Gerber

    IPC分类号： A01N35/10 ,  A01N39/00 ,  C07C317/30 ,  C07C323/47 ,  C07D333/16 ,  C07D333/28 ,  C07C251/50 ,  C07C251/52

    CPC分类号： A01N39/00 ,  A01N35/10 ,  C07C317/30 ,  C07C323/47 ,  C07D333/16 ,  C07D333/28 ,  C07C2101/02 ,  C07C2101/14 ,  C07C2101/16

    摘要： Cyclohexenone oxime ethers I ##STR1## where n is from 0 to 5, m is from 0 to 2, R.sup.1 is C.sub.1 -C.sub.6 -alkyl, R.sup.2 is C.sub.1 -C.sub.4 -alkyl or benzyl, A is unsubstituted or substituted C.sub.1 -C.sub.6 -alkylene, unsubstituted or substituted C.sub.3 -C.sub.6 -alkenylene, unsubstituted or substituted C.sub.3 -C.sub.6 -alkynylene or an unsubstituted or substituted C.sub.3 -C.sub.6 -alkylene or C.sub.4 -C.sub.6 -alkenylene chain, where in each case a methylene group may be replaced with O, S, SO, SO.sub.2 or --N(R.sup.a)--, R.sup.a is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, Z is phenyl, a 5-membered heteroaromatic radical or a 6-membered heteroaromatic radical having from 1 to 4 nitrogen atoms, X is NO.sub.2, CN, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkoxy, COOH, C.sub.1 -C.sub.4 -alkoxycarbonyl, unsubstituted or substituted benzyloxycarbonyl, unsubstituted or substituted phenyl, unsubstituted or substituted pyridyl or --NR.sup.b R.sup.c, R.sup.b is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl and R.sup.c is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -acyl or unsubstituted or substituted benzoyl, and the agriculturally useful salts and esters of C.sub.1 -C.sub.10 -carboxylic acids and inorganic acids are suitable as herbicides.

    摘要翻译： 环己烯酮肟醚I其中n为0至5，m为0至2，R 1为C 1 -C 6烷基，R 2为C 1 -C 4 - 烷基或苄基，A为未取代或取代的C 1 -C 6 - 亚烷基，未取代或取代的C 3 -C 6亚烯基，未取代或取代的C 3 -C 6亚炔基或未取代或取代的C 3 -C 6亚烷基或C 4 -C 6亚烯基链，其中在每种情况下亚甲基可以被O， S，SO，SO2或-N（Ra） - ，Ra是H，C1-C4-烷基，C3-C6-烯基或C3-C6-炔基，Z是苯基，5元杂芳族基团或6元 具有1至4个氮原子的杂芳族基团，X是NO 2，CN，卤素，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷氧基，COOH， C 1 -C 4烷氧基羰基，未取代或取代的苄氧基羰基，未取代或取代的苯基，未取代或取代的吡啶基或-NRbRc，Rb是H，C1-C4-烷基，C3-C6-烯基或C3-C6-炔基，Rc是H， C 1 -C 4 - 烷基，C 3 -C 6 - 烯基，C 3 -C 6炔基，C 1 -C 6 - 酰基或不饱和的 取代或取代的苯甲酰基，C1-C10-羧酸和无机酸的农业上有用的盐和酯适合作为除草剂。

    Thiocarboxylic acid derivatives
    94.
    发明授权
    Thiocarboxylic acid derivatives 失效
    硫代羧酸衍生物

    公开(公告)号：US5318945A

    公开(公告)日：1994-06-07

    申请号：US994254

    申请日：1992-12-21

    申请人： Ernst Baumann ,  Thomas Saupe ,  Joachim Rheinheimer ,  Uwe J. Vogelbacher ,  Matthias Bratz ,  Norbert Meyer ,  Matthias Gerber ,  Karl-Otto Westphalen ,  Uwe Kardorff ,  Andreas Landis ,  Helmut Walter

    发明人： Ernst Baumann ,  Thomas Saupe ,  Joachim Rheinheimer ,  Uwe J. Vogelbacher ,  Matthias Bratz ,  Norbert Meyer ,  Matthias Gerber ,  Karl-Otto Westphalen ,  Uwe Kardorff ,  Andreas Landis ,  Helmut Walter

    IPC分类号： A01N43/54 ,  A01N43/66 ,  C07D239/46 ,  C07D239/60 ,  C07D251/30 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D413/12 ,  C07D417/12 ,  C07D491/048 ,  C07D239/52 ,  C07D239/34

    CPC分类号： C07D409/12 ,  A01N43/54 ,  A01N43/66 ,  C07D239/60 ,  C07D251/30

    摘要： Thiocarboxylic acid derivatives useful as herbicides or plant growth regulators are of the general formula I ##STR1## where R.sup.1 is unsubstituted or substituted alkyl, unsubstituted or substituted cycloalkyl or cycloalkenyl, unsubstituted or substituted alkenyl or alkynyl or unsubstituted or substituted phenyl;R.sup.2 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio;X is nitrogen or CR.sup.6, where R.sup.6 is hydrogen or, together with R.sup.3, forms a C.sub.3 - or C.sub.4 -alkylene chain or C.sub.3 - or C.sub.4 -alkenylene chain in which a methylene group is replaced with oxygen;R.sup.3 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio or R.sup.3 is bonded to R.sup.6 as stated above to give a 5-membered or 6-membered ring;R.sup.4 is unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl or alkynyl, an unsubstituted or substituted 5-membered or 6-membered heteroaromatic structure containing from one to three nitrogen atoms and/or one sulfur or oxygen atom, or unsubstituted or substituted phenyl or naphthyl;R.sup.4 and R.sup.5 together with the adjacent carbon atom form a 3-membered to 6-membered ring which may contain an oxygen or sulfur atom and may be substituted;R.sup.5 is hydrogen, alkyl, haloalkyl, alkoxy, haloalkoxy, or alkylthio;and Y and Z are each oxygen or sulfur.

    摘要翻译： 可用作除草剂或植物生长调节剂的二羧酸衍生物具有通式I其中R 1为未取代或取代的烷基，未取代或取代的环烷基或环烯基，未取代或取代的烯基或炔基或未取代或取代的苯基; R2是卤素，烷基，卤代烷基，烷氧基，卤代烷氧基或烷硫基; X是氮或CR 6，其中R6是氢或与R3一起形成其中亚甲基被氧取代的C3-或C4-亚烷基链或C3-或C4-亚烯基链; R3是卤素，烷基，卤代烷基，烷氧基，卤代烷氧基或烷硫基，或R3如上所述与R6键合，得到5元或6元环; R4是未取代或取代的烷基，未取代或取代的烯基或炔基，含有1至3个氮原子和/或一个硫或氧原子的未取代或取代的5元或6元杂芳族结构，或未取代或取代的苯基或萘基 ; R4和R5与相邻的碳原子一起形成可含有氧或硫原子并且可以被取代的3元至6元环; R5是氢，烷基，卤代烷基，烷氧基，卤代烷氧基或烷硫基; Y和Z各自为氧或硫。

    O-(oximino)ethylcyclohexenone oxime ethers and their use as herbicides
    97.
    发明授权
    O-(oximino)ethylcyclohexenone oxime ethers and their use as herbicides 失效
    O-（肟基）乙基环己烯酮肟醚及其作为除草剂的用途

    公开(公告)号：US5739085A

    公开(公告)日：1998-04-14

    申请号：US435450

    申请日：1995-05-05

    申请人： Ulf Misslitz ,  Albrecht Harreus ,  Hartmann Konig ,  Helmut Walter ,  Karl-Otto Westphalen ,  Matthias Gerber

    发明人： Ulf Misslitz ,  Albrecht Harreus ,  Hartmann Konig ,  Helmut Walter ,  Karl-Otto Westphalen ,  Matthias Gerber

    IPC分类号： A01N35/10 ,  A01N41/06 ,  A01N43/16 ,  A01N43/18 ,  A01N43/56 ,  A01N43/80 ,  C07C251/38 ,  C07C251/52 ,  C07C251/54 ,  C07C251/58 ,  C07C311/05 ,  C07C323/19 ,  C07C323/47 ,  C07D231/12 ,  C07D261/08 ,  C07D309/06 ,  C07D335/02 ,  A01N33/24

    CPC分类号： A01N35/10 ,  A01N43/16 ,  A01N43/18 ,  C07C251/38 ,  C07C251/52 ,  C07C251/58 ,  C07C323/19 ,  C07C323/47 ,  C07D309/06 ,  C07D335/02 ,  C07C2101/02 ,  C07C2101/16

    摘要： O-(Oximino)ethylcyclohexenone oxime ethers I ##STR1## (R.sup.1 and R.sup.2 =C.sub.1 -C.sub.6 -alkyl; R.sup.3 =unsubstituted or substituted phenyl, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.4 -alkenyl or C.sub.3 -C.sub.4 -alkynyl, which in each case can be substituted by halogen, C.sub.1 -C.sub.3 -alkyl, unsubstituted or substituted phenyl or unsubstituted or substituted phenoxy; R.sup.4 =C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.4 -alkylthio-C.sub.1 -C.sub.6 -alkyl, unsubstituted or substituted phenylthio-C.sub.1 -C.sub.6 -alkyl, N-(C.sub.1 -C.sub.4 -alkylsulfonyl)-N-(C.sub.1 -C.sub.4 -alkyl)aminomethyl, unsubstituted or substituted C.sub.3 -C.sub.7 -cycloalkyl or C.sub.5 -C.sub.7 -cycloalkenyl, 5-membered saturated heterocyclyl having one or two oxygen and/or sulfur atoms, which can carry one to three substituents, saturated or unsaturated 6-/7-membered heterocyclyl having 1 or 2 non-adjacent oxygen and/or sulfur atoms, which can carry 1 to 3 substituents, 5-membered heteroaryl, containing 1 to 2 nitrogen atoms and an oxygen or sulfur atom, where the heteroaromatic can carry 1 to 3 substituents, phenyl or pyridyl, which can carry 1 to 3 of the following substituents: halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyloxy and --NR.sup.a R.sup.b ; R.sup.a =H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl; R.sup.b =H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -acyl or unsubstituted or substituted benzoyl) and their agriculturally utilizable salts and esters are described.

    摘要翻译： O-（肟基）乙基环己烯酮肟醚I（R1和R2 = C1-C6-烷基; R3 =未取代或取代的苯基，C1-C4-烷基，C3-C4-烯基或C3-C4-炔基，其中 在每种情况下可以被卤素，C 1 -C 3 - 烷基，未取代或取代的苯基或未取代或取代的苯氧基取代; R 4 = C 1 -C 4 - 烷氧基-C 1 -C 6烷基或C 1 -C 4 - 烷硫基-C 1 -C 6烷基 ，未取代或取代的苯硫基-C 1 -C 6烷基，N-（C 1 -C 4 - 烷基磺酰基）-N-（C 1 -C 4 - 烷基）氨基甲基，未取代或取代的C 3 -C 7 - 环烷基或C 5 -C 7 - 环烯基， 具有一个或两个氧和/或硫原子的五元饱和杂环基，其可以携带一至三个取代基，具有1或2个不相邻的氧和/或硫原子的饱和或不饱和的6-元/ 7元杂环基，其可携带1 包含1至2个氮原子和氧或硫原子的3个取代基，5元杂芳基，其中杂芳族可以带有1-3个取代基，苯基或吡啶基，其可以携带1至3个 C 1 -C 4烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷基，C 3 -C 6 - 烯氧基，C 3 -C 6 - 炔氧基和-NR a R b;取代基：卤素，硝基，氰基， R a = H，C 1 -C 4 - 烷基，C 3 -C 6 - 烯基或C 3 -C 6炔基; 描述了Rb = H，C 1 -C 4 - 烷基，C 3 -C 6 - 烯基，C 3 -C 6炔基，C 1 -C 6酰基或未取代或取代的苯甲酰基）和它们的农业可利用的盐和酯。

    5-hydroxypyrazol-4-ylcarbonyl-substituted saccharin derivatives
    98.
    发明授权
    5-hydroxypyrazol-4-ylcarbonyl-substituted saccharin derivatives 失效
    5-羟基吡唑-4-基羰基取代的糖精衍生物

    公开(公告)号：US5723415A

    公开(公告)日：1998-03-03

    申请号：US776576

    申请日：1997-02-03

    申请人： Peter Plath ,  Wolfgang von Deyn ,  Stefan Engel ,  Uwe Kardorff ,  Hartmann Konig ,  Harald Rang ,  Matthias Gerber ,  Helmut Walter ,  Karl-Otto Westphalen

    发明人： Peter Plath ,  Wolfgang von Deyn ,  Stefan Engel ,  Uwe Kardorff ,  Hartmann Konig ,  Harald Rang ,  Matthias Gerber ,  Helmut Walter ,  Karl-Otto Westphalen

    IPC分类号： A01N43/80 ,  A01P13/00 ,  C07D417/06

    CPC分类号： C07D417/06 ,  A01N43/80

    摘要： 5-Hydroxypyrazol-4-ylcarbonyl-substituted saccharin derivatives of the formula I ##STR1## where the substituents have the following meanings: L and M are hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, chlorine, cyano, methylsulfonyl, nitro or trifluoromethyl; Z is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.5 -alkynyl, C.sub.1 -C.sub.4 -acyl, benzyl or phenyl, the phenyl rings in each case being unsubstituted or substituted by halogen or C.sub.1 -C.sub.4 -alkyl; Q is a radical CO--J, J is a 4-linked 5-hydroxypyrazole ring of the formula II ##STR2## where R .sup.1 is C.sub.1 -C.sub.4 -alkyl and R .sup.2 is hydrogen or methyl, and agriculturally customary salts of the compounds I are described.

    摘要翻译： PCT No.PCT / EP95 / 02974 Sec。 371日期1997年2月3日 102（e）日期1997年2月3日PCT提交1995年7月27日PCT公布。 出版物WO96 / 05197 日期：1992年2月22日 - 式I的羟基吡唑-4-基羰基取代的糖精衍生物其中取代基具有以下含义：L和M是氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基， C 1 -C 4 - 烷硫基，氯，氰基，甲基磺酰基，硝基或三氟甲基; Z是氢，C 1 -C 4 - 烷基，C 3 -C 8 - 环烷基，C 3 -C 6 - 烯基，C 3 -C 5 - 炔基，C 1 -C 4 - 酰基，苄基或苯基，每种情况下的苯环是未取代的或被卤素 或C 1 -C 4烷基; Q是基团CO-J，J是式II其中R 1是C 1 -C 4 - 烷基和R 2是氢或甲基的4-连接的5-羟基吡唑环，以及化合物的农业常规盐 我被描述

    3-(Het)aryloxy(thio)carboxylic acid derivatives, their preparation and intermediates for their preparation
    99.
    发明授权
    3-(Het)aryloxy(thio)carboxylic acid derivatives, their preparation and intermediates for their preparation 失效
    3-（Het）芳氧基（硫代）羧酸衍生物，其制备方法及其制备中间体

    公开(公告)号：US5661106A

    公开(公告)日：1997-08-26

    申请号：US537759

    申请日：1995-10-19

    申请人： Ernst Baumann ,  Joachim Rheinheimer ,  Uwe Josef Vogelbacher ,  Matthias Bratz ,  Norbert Meyer ,  Matthias Gerber ,  Karl-Otto Westphalen ,  Helmut Walter ,  Wilhelm Rademacher

    发明人： Ernst Baumann ,  Joachim Rheinheimer ,  Uwe Josef Vogelbacher ,  Matthias Bratz ,  Norbert Meyer ,  Matthias Gerber ,  Karl-Otto Westphalen ,  Helmut Walter ,  Wilhelm Rademacher

    IPC分类号： C07D251/34 ,  A01N43/54 ,  A01N43/60 ,  A01N43/66 ,  A01P13/00 ,  C07C69/712 ,  C07C69/734 ,  C07D239/26 ,  C07D239/30 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D251/30 ,  C07D307/54 ,  C07D333/24 ,  C07D491/048 ,  H01N43/54 ,  C07D239/52

    CPC分类号： C07C69/734 ,  A01N43/54 ,  C07C69/712 ,  C07D239/60 ,  C07D251/30

    摘要： 3-(Het)aryloxy(thio)carboxylic acid derivatives of the formula I ##STR1## where R.sup.1 is hydrogen, COOH or a radical which can be hydrolyzed to give COOH;R.sup.2 and R.sup.3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio;X is nitrogen or CR.sup.14, where R.sup.14 is hydrogen or, together with R.sup.3, forms a 3-membered or 4-membered alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen;R.sup.4 is alkyl, cycloalkyl, cycloalkenyl, alkenyl or alkynyl, each of which is unsubstituted or substituted;an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom;unsubstituted or substituted phenyl or naphthyl;R.sup.4 and R.sup.5, together with the neighboring carbon atom, form a 3-membered to 8-membered ring which may contain an oxygen or sulfur atom and which is unsubstituted or substituted;R.sup.5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl, each of which is unsubstituted or substituted;R.sup.6 is unsubstituted or substituted phenyl or naphthyl or an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom;Y is sulfur or oxygen or a single bond; andZ is sulfur or oxygen.

    摘要翻译： PCT No.PCT / EP94 / 01156 Sec。 371 1995年10月19日日期 102（e）1995年10月19日PCT PCT 1994年4月14日PCT公布。 WO94 / 25443 PCT出版物 日期：1943年11月10日 - （Het）式I的芳氧基（硫代）羧酸衍生物其中R 1是氢，COOH或可被水解得到COOH的基团; R2和R3各自为卤素，烷基，卤代烷基，烷氧基，卤代烷氧基或烷硫基; X是氮或CR 14，其中R 14是氢或与R 3一起形成3元或4元亚烷基或亚烯基链，其中亚甲基被氧代替; R4是烷基，环烷基，环烯基，烯基或炔基，其各自为未取代或取代的; 含有一至三个氮原子或一个硫或氧原子的未取代或取代的五元或六元杂芳族结构; 未取代或取代的苯基或萘基; R 4和R 5与相邻的碳原子一起形成可含有氧或硫原子且未被取代或取代的3元至8元环; R5是氢，烷基，烯基，炔基，环烷基，卤代烷基，烷氧基烷基，烷硫基烷基或苯基，各自为未取代或取代的; R6是未取代或取代的苯基或萘基或含1-3个氮原子或一个硫或氧原子的未取代或取代的五元或六元杂芳族结构; Y是硫或氧或单键; Z是硫或氧。