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    3-(Het)aryloxy(thio)carboxylic acid derivatives, their preparation and intermediates for their preparation
    1.
    发明授权
    3-(Het)aryloxy(thio)carboxylic acid derivatives, their preparation and intermediates for their preparation 失效
    3-（Het）芳氧基（硫代）羧酸衍生物，其制备方法及其制备中间体

    公开(公告)号：US5661106A

    公开(公告)日：1997-08-26

    申请号：US537759

    申请日：1995-10-19

    申请人： Ernst Baumann ,  Joachim Rheinheimer ,  Uwe Josef Vogelbacher ,  Matthias Bratz ,  Norbert Meyer ,  Matthias Gerber ,  Karl-Otto Westphalen ,  Helmut Walter ,  Wilhelm Rademacher

    发明人： Ernst Baumann ,  Joachim Rheinheimer ,  Uwe Josef Vogelbacher ,  Matthias Bratz ,  Norbert Meyer ,  Matthias Gerber ,  Karl-Otto Westphalen ,  Helmut Walter ,  Wilhelm Rademacher

    IPC分类号： C07D251/34 ,  A01N43/54 ,  A01N43/60 ,  A01N43/66 ,  A01P13/00 ,  C07C69/712 ,  C07C69/734 ,  C07D239/26 ,  C07D239/30 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D251/30 ,  C07D307/54 ,  C07D333/24 ,  C07D491/048 ,  H01N43/54 ,  C07D239/52

    CPC分类号： C07C69/734 ,  A01N43/54 ,  C07C69/712 ,  C07D239/60 ,  C07D251/30

    摘要： 3-(Het)aryloxy(thio)carboxylic acid derivatives of the formula I ##STR1## where R.sup.1 is hydrogen, COOH or a radical which can be hydrolyzed to give COOH;R.sup.2 and R.sup.3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio;X is nitrogen or CR.sup.14, where R.sup.14 is hydrogen or, together with R.sup.3, forms a 3-membered or 4-membered alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen;R.sup.4 is alkyl, cycloalkyl, cycloalkenyl, alkenyl or alkynyl, each of which is unsubstituted or substituted;an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom;unsubstituted or substituted phenyl or naphthyl;R.sup.4 and R.sup.5, together with the neighboring carbon atom, form a 3-membered to 8-membered ring which may contain an oxygen or sulfur atom and which is unsubstituted or substituted;R.sup.5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl, each of which is unsubstituted or substituted;R.sup.6 is unsubstituted or substituted phenyl or naphthyl or an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom;Y is sulfur or oxygen or a single bond; andZ is sulfur or oxygen.

    摘要翻译： PCT No.PCT / EP94 / 01156 Sec。 371 1995年10月19日日期 102（e）1995年10月19日PCT PCT 1994年4月14日PCT公布。 WO94 / 25443 PCT出版物 日期：1943年11月10日 - （Het）式I的芳氧基（硫代）羧酸衍生物其中R 1是氢，COOH或可被水解得到COOH的基团; R2和R3各自为卤素，烷基，卤代烷基，烷氧基，卤代烷氧基或烷硫基; X是氮或CR 14，其中R 14是氢或与R 3一起形成3元或4元亚烷基或亚烯基链，其中亚甲基被氧代替; R4是烷基，环烷基，环烯基，烯基或炔基，其各自为未取代或取代的; 含有一至三个氮原子或一个硫或氧原子的未取代或取代的五元或六元杂芳族结构; 未取代或取代的苯基或萘基; R 4和R 5与相邻的碳原子一起形成可含有氧或硫原子且未被取代或取代的3元至8元环; R5是氢，烷基，烯基，炔基，环烷基，卤代烷基，烷氧基烷基，烷硫基烷基或苯基，各自为未取代或取代的; R6是未取代或取代的苯基或萘基或含1-3个氮原子或一个硫或氧原子的未取代或取代的五元或六元杂芳族结构; Y是硫或氧或单键; Z是硫或氧。

    Subtituted lactic acid derivatives having an N-organic radical in the .beta .
    4.
    发明授权
    Subtituted lactic acid derivatives having an N-organic radical in the .beta . 失效
    在β位具有N-有机基团的取代的乳酸衍生物

    公开(公告)号：US5750469A

    公开(公告)日：1998-05-12

    申请号：US605141

    申请日：1996-03-01

    申请人： Ernst Baumann ,  Joachim Rheinheimer ,  Uwe Josef Vogelbacher ,  Matthias Gerber ,  Wilhelm Rademacher ,  Helmut Walter ,  Karl-Otto Westphalen

    发明人： Ernst Baumann ,  Joachim Rheinheimer ,  Uwe Josef Vogelbacher ,  Matthias Gerber ,  Wilhelm Rademacher ,  Helmut Walter ,  Karl-Otto Westphalen

    IPC分类号： C07D239/28 ,  A01N25/32 ,  A01N35/10 ,  A01N43/54 ,  A01N43/90 ,  A01N47/12 ,  C07C229/34 ,  C07C233/47 ,  C07C247/12 ,  C07C251/42 ,  C07D239/34 ,  C07D239/60 ,  C07D401/12

    CPC分类号： C07D401/12 ,  A01N25/32 ,  A01N43/54 ,  C07C229/34 ,  C07C233/47 ,  C07C247/12 ,  C07C251/42 ,  C07D239/60 ,  C07C2101/16

    摘要： Substituted lactic acid derivatives having an N-organic radical in the .beta.-position, of the formula I ##STR1## where substituents R to R.sup.5, X and Y have the meanings mentioned in the description and N is one of the radicals: a) --N.sub.3, --NC, --NCS or --NCO b) ##STR2## where R.sup.14 and R.sup.15 have the meanings described in the description c) ##STR3## in which R.sup.16 is hydrogen, alkyl, haloalkyl, alkenyl, alkynyl, cycloalkyl or unsubstituted or substituted phenyl; and B is a group ##STR4## OR.sup.19 or --NR.sup.14 R.sup.15, where R.sup.14, R.sup.15, R.sup.17 and R.sup.19 have the meanings described in the description, or ##STR5## where R.sup.14 and R.sup.15.sub.1, have the abovementioned meanings; or ##STR6## where R.sup.20 and R.sup.21, which can be identical or different, are: hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl or phenyl, where the organic radicals can in each case be substituted; or R.sup.20 and R.sup.21 together form an unsubstituted or substituted C.sub.4 -C.sub.7 -alkylene chain which is closed to give a ring or together form an unsubstituted or substituted C.sub.3 -C.sub.6 -alkylene chain which is closed to give a ring and has a heteroatom selected from the group consisting of oxygen, sulfur and nitrogen are described.

    摘要翻译： PCT No.PCT / EP94 / 02825 Sec。 371日期1996年3月1日 102（e）1996年3月1日PCT 1994年9月25日PCT公布。 公开号WO95 / 07266 日期1995年3月16日在β位具有N-有机基团的式I的取代的乳酸衍生物，其中取代基R至R5，X和Y具有说明书中提到的含义，+ E，crc N + EE是自由基之一：a）-N3，-NC，-NCS或-NCO b）其中R14和R15具有其中R 16是氢的描述c）＆lt; IMAGE＆gt;中描述的含义，烷基 ，卤代烷基，烯基，炔基，环烷基或未取代或取代的苯基; 并且B是一个 OR 19或-NR 14 R 15基团，其中R 14，R 15，R 17和R 19具有说明书中描述的含义，或者其中R14和R151具有上述含义的 或者其中可以相同或不同的R20和R21是：氢，烷基，烯基，炔基，环烷基或苯基，其中有机基团可以在每种情况下被取代; 或R 20和R 21一起形成未取代或取代的C 4 -C 7亚烷基链，其被封闭以形成环或一起形成未取代或取代的C3-C6-亚烷基链，其闭合以产生环并且具有选自以下的杂原子 描述了由氧，硫和氮组成的组。

    Thiocarboxylic acid derivatives
    6.
    发明授权
    Thiocarboxylic acid derivatives 失效
    硫代羧酸衍生物

    公开(公告)号：US5318945A

    公开(公告)日：1994-06-07

    申请号：US994254

    申请日：1992-12-21

    申请人： Ernst Baumann ,  Thomas Saupe ,  Joachim Rheinheimer ,  Uwe J. Vogelbacher ,  Matthias Bratz ,  Norbert Meyer ,  Matthias Gerber ,  Karl-Otto Westphalen ,  Uwe Kardorff ,  Andreas Landis ,  Helmut Walter

    发明人： Ernst Baumann ,  Thomas Saupe ,  Joachim Rheinheimer ,  Uwe J. Vogelbacher ,  Matthias Bratz ,  Norbert Meyer ,  Matthias Gerber ,  Karl-Otto Westphalen ,  Uwe Kardorff ,  Andreas Landis ,  Helmut Walter

    IPC分类号： A01N43/54 ,  A01N43/66 ,  C07D239/46 ,  C07D239/60 ,  C07D251/30 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D413/12 ,  C07D417/12 ,  C07D491/048 ,  C07D239/52 ,  C07D239/34

    CPC分类号： C07D409/12 ,  A01N43/54 ,  A01N43/66 ,  C07D239/60 ,  C07D251/30

    摘要： Thiocarboxylic acid derivatives useful as herbicides or plant growth regulators are of the general formula I ##STR1## where R.sup.1 is unsubstituted or substituted alkyl, unsubstituted or substituted cycloalkyl or cycloalkenyl, unsubstituted or substituted alkenyl or alkynyl or unsubstituted or substituted phenyl;R.sup.2 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio;X is nitrogen or CR.sup.6, where R.sup.6 is hydrogen or, together with R.sup.3, forms a C.sub.3 - or C.sub.4 -alkylene chain or C.sub.3 - or C.sub.4 -alkenylene chain in which a methylene group is replaced with oxygen;R.sup.3 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio or R.sup.3 is bonded to R.sup.6 as stated above to give a 5-membered or 6-membered ring;R.sup.4 is unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl or alkynyl, an unsubstituted or substituted 5-membered or 6-membered heteroaromatic structure containing from one to three nitrogen atoms and/or one sulfur or oxygen atom, or unsubstituted or substituted phenyl or naphthyl;R.sup.4 and R.sup.5 together with the adjacent carbon atom form a 3-membered to 6-membered ring which may contain an oxygen or sulfur atom and may be substituted;R.sup.5 is hydrogen, alkyl, haloalkyl, alkoxy, haloalkoxy, or alkylthio;and Y and Z are each oxygen or sulfur.

    摘要翻译： 可用作除草剂或植物生长调节剂的二羧酸衍生物具有通式I其中R 1为未取代或取代的烷基，未取代或取代的环烷基或环烯基，未取代或取代的烯基或炔基或未取代或取代的苯基; R2是卤素，烷基，卤代烷基，烷氧基，卤代烷氧基或烷硫基; X是氮或CR 6，其中R6是氢或与R3一起形成其中亚甲基被氧取代的C3-或C4-亚烷基链或C3-或C4-亚烯基链; R3是卤素，烷基，卤代烷基，烷氧基，卤代烷氧基或烷硫基，或R3如上所述与R6键合，得到5元或6元环; R4是未取代或取代的烷基，未取代或取代的烯基或炔基，含有1至3个氮原子和/或一个硫或氧原子的未取代或取代的5元或6元杂芳族结构，或未取代或取代的苯基或萘基 ; R4和R5与相邻的碳原子一起形成可含有氧或硫原子并且可以被取代的3元至6元环; R5是氢，烷基，卤代烷基，烷氧基，卤代烷氧基或烷硫基; Y和Z各自为氧或硫。

    Cyclohexenone oxime ethers
    10.
    发明授权
    Cyclohexenone oxime ethers 失效
    环己烯酮肟醚

    公开(公告)号：US5604183A

    公开(公告)日：1997-02-18

    申请号：US523682

    申请日：1995-09-05

    申请人： Ulf Misslitz ,  Norbert Meyer ,  Juergen Kast ,  Matthias Bratz ,  Albrecht Harreus ,  Helmut Walter ,  Karl-Otto Westphalen ,  Matthias Gerber

    发明人： Ulf Misslitz ,  Norbert Meyer ,  Juergen Kast ,  Matthias Bratz ,  Albrecht Harreus ,  Helmut Walter ,  Karl-Otto Westphalen ,  Matthias Gerber

    IPC分类号： A01N35/10 ,  A01N39/00 ,  C07C317/30 ,  C07C323/47 ,  C07D333/16 ,  C07D333/28 ,  C07C251/50 ,  C07C251/52

    CPC分类号： A01N39/00 ,  A01N35/10 ,  C07C317/30 ,  C07C323/47 ,  C07D333/16 ,  C07D333/28 ,  C07C2101/02 ,  C07C2101/14 ,  C07C2101/16

    摘要： Cyclohexenone oxime ethers I ##STR1## where n is from 0 to 5, m is from 0 to 2, R.sup.1 is C.sub.1 -C.sub.6 -alkyl, R.sup.2 is C.sub.1 -C.sub.4 -alkyl or benzyl, A is unsubstituted or substituted C.sub.1 -C.sub.6 -alkylene, unsubstituted or substituted C.sub.3 -C.sub.6 -alkenylene, unsubstituted or substituted C.sub.3 -C.sub.6 -alkynylene or an unsubstituted or substituted C.sub.3 -C.sub.6 -alkylene or C.sub.4 -C.sub.6 -alkenylene chain, where in each case a methylene group may be replaced with O, S, SO, SO.sub.2 or --N(R.sup.a)--, R.sup.a is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, Z is phenyl, a 5-membered heteroaromatic radical or a 6-membered heteroaromatic radical having from 1 to 4 nitrogen atoms, X is NO.sub.2, CN, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkoxy, COOH, C.sub.1 -C.sub.4 -alkoxycarbonyl, unsubstituted or substituted benzyloxycarbonyl, unsubstituted or substituted phenyl, unsubstituted or substituted pyridyl or --NR.sup.b R.sup.c, R.sup.b is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl and R.sup.c is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -acyl or unsubstituted or substituted benzoyl, and the agriculturally useful salts and esters of C.sub.1 -C.sub.10 -carboxylic acids and inorganic acids are suitable as herbicides.

    摘要翻译： 环己烯酮肟醚I其中n为0至5，m为0至2，R 1为C 1 -C 6烷基，R 2为C 1 -C 4 - 烷基或苄基，A为未取代或取代的C 1 -C 6 - 亚烷基，未取代或取代的C 3 -C 6亚烯基，未取代或取代的C 3 -C 6亚炔基或未取代或取代的C 3 -C 6亚烷基或C 4 -C 6亚烯基链，其中在每种情况下亚甲基可以被O， S，SO，SO2或-N（Ra） - ，Ra是H，C1-C4-烷基，C3-C6-烯基或C3-C6-炔基，Z是苯基，5元杂芳族基团或6元 具有1至4个氮原子的杂芳族基团，X是NO 2，CN，卤素，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷氧基，COOH， C 1 -C 4烷氧基羰基，未取代或取代的苄氧基羰基，未取代或取代的苯基，未取代或取代的吡啶基或-NRbRc，Rb是H，C1-C4-烷基，C3-C6-烯基或C3-C6-炔基，Rc是H， C 1 -C 4 - 烷基，C 3 -C 6 - 烯基，C 3 -C 6炔基，C 1 -C 6 - 酰基或不饱和的 取代或取代的苯甲酰基，C1-C10-羧酸和无机酸的农业上有用的盐和酯适合作为除草剂。