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    Thiocarboxylic acid derivatives
    1.
    发明授权
    Thiocarboxylic acid derivatives 失效
    硫代羧酸衍生物

    公开(公告)号：US5318945A

    公开(公告)日：1994-06-07

    申请号：US994254

    申请日：1992-12-21

    申请人： Ernst Baumann ,  Thomas Saupe ,  Joachim Rheinheimer ,  Uwe J. Vogelbacher ,  Matthias Bratz ,  Norbert Meyer ,  Matthias Gerber ,  Karl-Otto Westphalen ,  Uwe Kardorff ,  Andreas Landis ,  Helmut Walter

    发明人： Ernst Baumann ,  Thomas Saupe ,  Joachim Rheinheimer ,  Uwe J. Vogelbacher ,  Matthias Bratz ,  Norbert Meyer ,  Matthias Gerber ,  Karl-Otto Westphalen ,  Uwe Kardorff ,  Andreas Landis ,  Helmut Walter

    IPC分类号： A01N43/54 ,  A01N43/66 ,  C07D239/46 ,  C07D239/60 ,  C07D251/30 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D413/12 ,  C07D417/12 ,  C07D491/048 ,  C07D239/52 ,  C07D239/34

    CPC分类号： C07D409/12 ,  A01N43/54 ,  A01N43/66 ,  C07D239/60 ,  C07D251/30

    摘要： Thiocarboxylic acid derivatives useful as herbicides or plant growth regulators are of the general formula I ##STR1## where R.sup.1 is unsubstituted or substituted alkyl, unsubstituted or substituted cycloalkyl or cycloalkenyl, unsubstituted or substituted alkenyl or alkynyl or unsubstituted or substituted phenyl;R.sup.2 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio;X is nitrogen or CR.sup.6, where R.sup.6 is hydrogen or, together with R.sup.3, forms a C.sub.3 - or C.sub.4 -alkylene chain or C.sub.3 - or C.sub.4 -alkenylene chain in which a methylene group is replaced with oxygen;R.sup.3 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio or R.sup.3 is bonded to R.sup.6 as stated above to give a 5-membered or 6-membered ring;R.sup.4 is unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl or alkynyl, an unsubstituted or substituted 5-membered or 6-membered heteroaromatic structure containing from one to three nitrogen atoms and/or one sulfur or oxygen atom, or unsubstituted or substituted phenyl or naphthyl;R.sup.4 and R.sup.5 together with the adjacent carbon atom form a 3-membered to 6-membered ring which may contain an oxygen or sulfur atom and may be substituted;R.sup.5 is hydrogen, alkyl, haloalkyl, alkoxy, haloalkoxy, or alkylthio;and Y and Z are each oxygen or sulfur.

    摘要翻译： 可用作除草剂或植物生长调节剂的二羧酸衍生物具有通式I其中R 1为未取代或取代的烷基，未取代或取代的环烷基或环烯基，未取代或取代的烯基或炔基或未取代或取代的苯基; R2是卤素，烷基，卤代烷基，烷氧基，卤代烷氧基或烷硫基; X是氮或CR 6，其中R6是氢或与R3一起形成其中亚甲基被氧取代的C3-或C4-亚烷基链或C3-或C4-亚烯基链; R3是卤素，烷基，卤代烷基，烷氧基，卤代烷氧基或烷硫基，或R3如上所述与R6键合，得到5元或6元环; R4是未取代或取代的烷基，未取代或取代的烯基或炔基，含有1至3个氮原子和/或一个硫或氧原子的未取代或取代的5元或6元杂芳族结构，或未取代或取代的苯基或萘基 ; R4和R5与相邻的碳原子一起形成可含有氧或硫原子并且可以被取代的3元至6元环; R5是氢，烷基，卤代烷基，烷氧基，卤代烷氧基或烷硫基; Y和Z各自为氧或硫。

    Substituted 2-benzoyl-cyclohexan-1,3-diones with herbicidal effect
    9.
    发明授权
    Substituted 2-benzoyl-cyclohexan-1,3-diones with herbicidal effect 失效
    取代的具有除草效果的2-苯甲酰基 - 环己烷-1,3-二酮

    公开(公告)号：US06576596B1

    公开(公告)日：2003-06-10

    申请号：US09331639

    申请日：1999-06-23

    申请人： Regina Luise Hill ,  Uwe Kardorff ,  Michael Rack ,  Ernst Baumann ,  Wolfgang von Deyn ,  Stefan Engel ,  Guido Mayer ,  Martina Otten ,  Joachim Rheinheimer ,  Matthias Witschel ,  Ulf Misslitz ,  Helmut Walter ,  Karl-Otto Westphalen

    发明人： Regina Luise Hill ,  Uwe Kardorff ,  Michael Rack ,  Ernst Baumann ,  Wolfgang von Deyn ,  Stefan Engel ,  Guido Mayer ,  Martina Otten ,  Joachim Rheinheimer ,  Matthias Witschel ,  Ulf Misslitz ,  Helmut Walter ,  Karl-Otto Westphalen

    IPC分类号： A01N3510

    CPC分类号： A01N41/10 ,  A01N35/10 ,  A01N37/52 ,  C07C251/48 ,  C07C259/10 ,  C07C317/32 ,  C07C317/44 ,  C07C2601/16

    摘要： The invention relates to 2-benzoylcyclohexane-1,3-diones of the formula I where R1, R2 are each hydrogen, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, alkoxyalkyl, alkenyl, alkynyl, —OR5, —OCOR6, —OSO2R6, —SH, —S(O)nR7, —SO2OR5, —SO2NR5R8, —NR8SO2R6 or —NR8COR6; R3 is hydrogen, cyano, alkyl, haloalkyl, —OR7, —SR7 or —NR7R10; R4 is hydrogen, substituted or unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, —COR9, —CO2R9, —COSR9 or —CONR8R9; X is oxygen or NR8; n is 0, 1 or 2; R5 is hydrogen, alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R6 is alkyl or haloalkyl; R7 is alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R8 is hydrogen or alkyl; R9 is alkyl, alkenyl, alkynyl, phenyl or benzyl; R10 is alkyl, haloalkyl, alkenyl or alkynyl; Q is a cyclohexane-1,3-dione ring with or without substitution attached in position 2; and agriculturally useful salts thereof; to processes and intermediates for preparing the compounds of the formula I; to compositions comprising them; and to the use of these derivatives or compositions comprising them for controlling undesirable plants.

    摘要翻译： 本发明涉及式I的2-苯甲酰基环己烷-1,3-二酮，其中R 1，R 2各自为氢，硝基，卤素，氰基，氰硫基，烷基，卤代烷基，烷氧基烷基，烯基，炔基，-OR 5，-OCOR 6，-OSO 2 R 6， -SH，-S（O）nR7，-SO2OR5，-SO2NR5R8，-NR8SO2R6或-NR8COR6; R3是氢，氰基，烷基，卤代烷基，-OR7，-SR7或-NR7R10; R4是氢，取代或未取代的烷基， 环烷基，烯基，环烯基，炔基，-COR 9，-CO 2 R 9，-COSR 9或-CONR 8 R 9; X是氧或NR 8; n是0,1或2; R 5是氢，烷基，卤代烷基，烷氧基烷基，烯基或炔基; 烷基或卤代烷基; R 7是烷基，卤代烷基，烷氧基烷基，烯基或炔基; R 8是氢或烷基; R 9是烷基，烯基，炔基，苯基或苄基; R 10是烷基，卤代烷基，烯基或炔基; Q是环己烷-1 具有或不具有取代基的2-二酮环;和其农业上有用的盐;制备式I化合物的方法和中间体; 包含它们的组合物; 以及使用这些衍生物或包含它们的组合物来控制不期望的植物。