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公开(公告)号：US4522757A
公开(公告)日：1985-06-11
申请号：US527892
申请日：1983-08-30
申请人： Chao-Yang Hsu , James E. Lyons
发明人： Chao-Yang Hsu , James E. Lyons
摘要： Phenol or a substituted phenol is oxidized to the corresponding benzoquinone or substituted benzoquinone in the presence of a copper halide or copper nitrate catalyst promoted with an oxide or hydroxide of a Group II metal.
摘要翻译： 在用II族金属的氧化物或氢氧化物促进的卤化铜或硝酸铜催化剂的存在下，苯酚或取代的苯酚被氧化成相应的苯醌或取代的苯醌。
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公开(公告)号：US4519948A
公开(公告)日：1985-05-28
申请号：US527891
申请日：1983-08-30
申请人： Chao-Yang Hsu , James E. Lyons
发明人： Chao-Yang Hsu , James E. Lyons
CPC分类号： B01J31/0237 , B01J31/0214 , B01J31/28 , B01J31/30 , C07C46/08 , C07C50/02 , B01J2231/70 , B01J27/122
摘要： Phenol or a substituted phenol is oxidized to the corresponding benzoquinone or substituted benzoquinone in a nitroalkane solvent in the presence of a copper ion catalyst promoted with a base selected from alkali metal phenoxides, and secondary or tertiary lower alkyl amines.
摘要翻译： 苯酚或取代的酚在硝基烷烃溶剂中，在用选自碱金属苯氧化物和仲或叔低级烷基胺的碱催化的铜离子催化剂的存在下，氧化成相应的苯醌或取代的苯醌。
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93.发明授权
公开(公告)号：US4485246A
公开(公告)日：1984-11-27
申请号：US437725
申请日：1982-10-29
申请人： James E. Lyons
发明人： James E. Lyons
IPC分类号： C07D315/00 , C07D307/20 , C07D307/83
CPC分类号： C07D315/00
摘要： The rate of selective hydrogenation of carboxylic acid anhydrides to esters or lactones in the presence of a ruthenium organophosphorous catalyst which contains or liberates a hydrogen halide during the hydrogenation, is improved by providing in the reaction medium prior to or during the hydrogenation a basic amino compound to remove the hydrogen halide.
摘要翻译： 在氢化期间含有或释放卤化氢的钌有机磷催化剂存在下，羧酸酐对酯或内酯的选择性加氢速率通过在氢化之前或期间在反应介质中提供碱性氨基化合物 以除去卤化氢。
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公开(公告)号：US4478752A
公开(公告)日：1984-10-23
申请号：US423984
申请日：1982-09-27
申请人： Chao-Yang Hsu , James E. Lyons
发明人： Chao-Yang Hsu , James E. Lyons
IPC分类号： C07C50/04 , B01J23/72 , B01J27/10 , B01J27/122 , C07B61/00 , C07C45/00 , C07C46/08 , C07C50/26 , C07C67/00
CPC分类号： B01J27/10 , B01J23/72 , C07C46/08 , Y02P20/582
摘要： In the process of oxidizing phenol to p-benzoquinone with a bivalent copper ion catalyst, the improvement of promoting the catalyst with a base to obtain improved conversion and/or selectivity. The preferred bases used are alkali metal hydroxides and phenates and secondary and tertiary lower alkyl amines.
摘要翻译： 在用二价铜离子催化剂将酚氧化成对苯醌的过程中，用碱改善催化剂以改善转化率和/或选择性。 所用的碱是碱金属氢氧化物和酚盐以及仲和叔低级烷基胺。
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95.发明授权
公开(公告)号：US4237310A
公开(公告)日：1980-12-02
申请号：US957614
申请日：1978-11-03
申请人： George Suld , James E. Lyons , Robert W. Shinn
发明人： George Suld , James E. Lyons , Robert W. Shinn
IPC分类号： C07C37/055 , C07C45/36 , C07C45/41 , C07C45/54 , C07C51/56 , C07C67/00 , C07C67/05 , C07C69/14 , C07C67/39 , C07C69/157
CPC分类号： C07C69/14 , C07C37/0555 , C07C45/36 , C07C45/41 , C07C45/54 , C07C51/56 , C07C67/00 , C07C67/05
摘要： The oxidation of methyl benzenes, such as toluene, with air or oxygen in the presence of acetic anhydride and sulfuric acid catalyst to form a phenolic acetate and methylene diacetate may be carried out under mild conditions when small amounts of benzaldehyde are added to the reaction.The resulting acetates may then be pyrolyzed to yield phenolic compounds and formaldehyde, respectively.
摘要翻译： 在乙酸酐和硫酸催化剂的存在下，甲苯等甲苯与空气或氧气氧化形成酚类乙酸酯和亚甲基二乙酸酯可以在温和条件下，当向反应中加入少量苯甲醛时进行。 然后将所得的乙酸酯热解，分别产生酚类化合物和甲醛。
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公开(公告)号：US4169863A
公开(公告)日：1979-10-02
申请号：US888905
申请日：1978-03-22
CPC分类号： C07C13/68 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Norbornadiene and an alkyne are catalytically codimerized in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl alluminum chloride. Also, novel codimers of norbornadiene and an alkyne containing at least three carbons are disclosed. After hydrogenation, resulting codimers can be used as high energy fuels or diluents for such fuels.
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97.发明授权Ion-exchanged transition metal catalysts for the direct oxidation of olefins to epoxyalcohols 失效用于将烯烃直接氧化成环氧醇的离子交换过渡金属催化剂
公开(公告)号：US4021369A
公开(公告)日：1977-05-03
申请号：US547424
申请日：1975-02-05
申请人： James E. Lyons
发明人： James E. Lyons
IPC分类号： B01J31/08 , B01J31/10 , C07D303/14 , B01J31/02 , B01J29/06 , C07D301/24
CPC分类号： C07D303/14 , B01J31/10 , B01J2231/72
摘要： Acylic or cyclic epoxyalcohols can be prepared by direct oxidation of an olefin when there is employed a ion-exchanged bimetallic catalyst, wherein one metal is from Groups IB or VIII, and the other from Group V or VI.
摘要翻译： 酰基或环状环氧醇可以通过使用离子交换双金属催化剂直接氧化烯烃来制备，其中一种金属来自IB或VIII族，另一种来自V或VI族。
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公开(公告)号：US3972953A
公开(公告)日：1976-08-03
申请号：US542998
申请日：1975-01-22
申请人： James E. Lyons
发明人： James E. Lyons
CPC分类号： C07F15/065 , B01J31/20 , B01J31/2404 , C07C17/202 , C07F15/004 , C07F15/0053 , C07F15/008 , B01J2231/40 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/827 , B01J2531/845
摘要： Alkyl halide exchange may be catalyzed under mild conditions in homogeneous solution by ligand stabilized, low valent, coordinatively unsaturated d.sup.6 or d.sup.8 Group VIII metal complexes of the formulaM.sup.n X.sub.n L.sub.xwherein M is a metal of Group VIII of the Periodic Table; X is chloride, bromide or iodide; n is 1 or 2; L is a neutral ligand such as CO; trialkyl or triaryl- phosphines, arsines, amines, or stibines and the like; x is an integer from 2-4 and L.sub.x represents x neutral ligands which may be the same or different.In this manner the halide group of one alkyl halide may be replaced by the halogen of another alkyl halide by a process of alkyl halide exchange.
摘要翻译： 烷基卤交换可以在温和条件下在均相溶液中通过配位体稳定的低价，配位不饱和的d 6或d 8式VIII的金属络合物MnXnLx WHEREIN M是元素周期表的第Ⅷ族金属; X是氯化物，溴化物或碘化物; n为1或2; L是中性配体如CO; 三烷基或三芳基膦，胂，胺或苯乙烯等; x是2-4的整数，Lx表示可以相同或不同的x中性配体。
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公开(公告)号：US3960914A
公开(公告)日：1976-06-01
申请号：US575096
申请日：1975-05-06
申请人： James E. Lyons
发明人： James E. Lyons
IPC分类号： C07C263/12 , C07C118/04
CPC分类号： C07C263/00
摘要： Formamides of formula R--NHCHO where R is a lower alkyl, cycloalkyl, aryl or aralkyl can be converted to isocyanates of the formula R--N=C=O when contacted with certain ruthenium, palladium, or platinum dehydrogenation catalysts.
摘要翻译： 当与某些钌，钯或铂脱氢催化剂接触时，其中R为低级烷基，环烷基，芳基或芳烷基的式R-NHCHO的甲酰胺可转化为式R-N = C = O的异氰酸酯。
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