摘要:
Isoxazole(isothiazole)-5-carboxamides of the formula ##STR1## where X is oxygen or sulfur,R.sup.1 is hydrogen, substituted or unsubstituted alkyl, alkoxy, substituted or unsubstituted cycloalkyl, a 5- or 6-membered heterocyclic radical having one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, and which may be substituted, or substituted or unsubstituted phenyl, orR.sup.2 is formyl, 4,5-dihydrooxazol-2-yl or a radical of the formula COYR.sup.5 or CONR.sup.6 R.sup.7, whereY is oxygen or sulfur,R.sup.5 ishydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted alkenyl, haloalkenyl, substituted or unsubstituted alkynyl,cycloalkyl,cycloalkenyl,substituted or unsubstituted phenyl,a 5- or 6-membered heterocyclic radical having one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen,cycloalkanimino, phthalimido, succinimido, or a radical ##STR2## R.sup.3 and R.sup.4 have the meanings defined herein, or their agriculturally acceptable salts possess herbicidal activity.
摘要:
N-((6-Trifluoromethylpyrimidin-2-yl)- aminocarbonyl)-2-carboalkoxybenzenesulfonamides of the general formula Ia ##STR1## where the substituents have the following meanings: R.sup.1 is hydrogen or halogen;R.sup.2 is hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.3 -C.sub.4 -alkenyl, C.sub.3 -C.sub.4 -alkynyl, C.sub.1 -C.sub.5 -haloalkyl, C.sub.3 -C.sub.5 -alkoxyalkyl, C.sub.3 -C.sub.5 -haloalkoxyalkyl or C.sub.5 -C.sub.6 -cycloalkyl,R.sup.3 is hydrogen, C.sub.1 -C.sub.2 -alkyl, allyl, propargyl or C.sub.1 -C.sub.5 -alkoxy,R.sup.4 is halogen, C.sub.1 -C.sub.2 -alkyl, C.sub.1 -C.sub.3 -alkylthio or C.sub.1 -C.sub.3 -alkylamino,R.sup.3 not denoting hydrogen or C.sub.1 -C.sub.2 -alkyl when R.sup.4 is C.sub.1 -C.sub.2 -alkyl, and their environmentally tolerated salts, processes for their manufacture, and their use.
摘要:
4-Aryl-2-haloimidazole-5-carboxylic esters of the general formula Ia and Ib ##STR1## where R.sup.1 is C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl,R.sub.2 is C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl,Hal is chlorine or bromine,n is 0 to 3,x is C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, C.sub.1 -C.sub.4 -haloalkylthio, cyano, nitro, carbo-C.sub.1 -C.sub.4 -alkoxy, N,N-di-C.sub.1 -C.sub.4 -alkylcarbamoyl and/or halogen,processes for their manufacture, and their use in herbicidal agents as safeners in combination with at least one herbicidal active ingredient from the group consisting ofa) 2-(4-heteroaryloxy)- or 2-(4-aryloxy)-phenoxyacetic acid or -propionic acid derivatives andb) cyclohexenone derivatives.
摘要:
Isoxazole(isothiazole)-5-carboxamides, having herbicidal activity, of the formula ##STR1## where X is oxygen or sulfur,R.sup.1 is hydrogen, substituted or unsubstituted alkyl, alkoxy, substituted or unsubstituted cycloalkyl, a 5- or 6-membered heterocyclic radical having one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, and which may be substituted, or substituted or unsubstituted phenyl, orR.sup.2 is formyl, 4,5-dihydrooxazol-2-yl or a radical of the formula COYR.sup.5 or CONR.sup.6 R.sup.7.
摘要:
2-Phenylpyridazin-3-one compounds of the formulae ##STR1## where R is C.sub.1 -C.sub.8 -alkyl; substituted or unsubstituted benzyl; substituted or unsubstituted C.sub.3 -C.sub.8 -cycloalkyl; a 4- to 6-membered heteroaliphatic ring containing an oxygen or a sulfur atom or an N--CH.sub.3 group as ring member; substituted or unsubstituted styryl; a substituted or unsubstituted 5- or 6-membered aromatic or heteroaromatic ring which may be benzofused, processes for their manufacture, and their use.
摘要:
[[(1,3,5-Triazin-2-yl)aminocarbonyl]aminosulfonyl]benzoic esters of the general formula I ##STR1## where R.sup.1 and R.sup.2 are methyl or ethyl, and R.sup.3 is hydrogen, fluorine or chlorine, agriculturally useful salts thereof, processes for their manufacture, and their use.
摘要:
Substituted sulfonylureas of the formula I ##STR1## where the substituents and indices have the following meanings: x is oxygen or sulfur;z is nitrogen or methine (=CH--);R.sup.1 is halogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxycarbonyl or C.sub.1 -C.sub.3 -alkoxy, or a radical --CONR.sup.6 R.sup.7, whereR.sup.6 is hydrogen, C.sub.1 -C.sub.8 -alkyl or C.sub.1 -C.sub.6 -alkoxy andR.sup.7 is hydrogen or C.sub.1 -C.sub.8 -alkyl;R.sup.2 is halogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkyl;R.sup.3 is C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkylthio, halogen, cyano, nitro, amino, mono-C.sub.1 -C.sub.4 -alkylamino, di-C.sub.1 -C.sub.4 -alkylamino, C.sub.2 -C.sub.6 -alkenyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkanoyl or benzyl; a 5- or 6-membered saturated heterocycle which is attached by its nitrogen atom and which, besides methylene and a nitrogen, may also contain an oxygen or a sulfur atom; or, bonded to adjacent ring positions, --OCRR'O--, where R and R' are each hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.5 is halogen C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio or C.sub.1 -C.sub.4 -haloalkyl;m is from 0 to 3 or, when R.sup.3 is halogen, from 0 to 5, differences among the R.sup.3 radicals being possible when m is 2 or 3; andn is from 0 to 2, a difference between the R.sup.5 radicals being possible when n is 2;and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.
摘要:
Substituted sulfonylureas of the formula I ##STR1## where the substituents and indices have the following meanings: X is oxygen or sulfur;Z is nitrogen or methine (.dbd.CH--);R.sup.1 is halogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxycarbonyl or C.sub.1 -C.sub.3 -alkoxy, or a radical --CONR.sup.6 R.sup.7, whereR.sup.6 is hydrogen, C hd 1-C.sub.8 -alkyl or C.sub.1 -C.sub.6 -alkoxy andR.sup.7 is hydrogen or C.sub.1 -C.sub.8 -alkyl;R.sup.2 is halogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkyl;R.sup.3 is C.sub.1 -C.sub.4 -alkyl, C hd 1-C.sub.4 -alkylthio, C hd 1-C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkylthio, halogen, cyano, nitro, amino, mono-C.sub.1 -C.sub.4 -alkylamino, di-C.sub.1 -C.sub.4 -alkylamino, C hd 2-C.sub.6 -alkenyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkanoyl or benzyl; a 5- or 6-membered saturated heterocycle which is attached by its nitrogen atom and which, besides methylene and a nitrogen, may also contain an oxygen or a sulfur atom; or, bonded to adjacent ring positions, --OCRR'O--, where R and R' are each hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.5 is halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio or C.sub.1 -C.sub.4 -haloalkyl;m is from 0 to 3 or, when R.sup.3 is halogen, from 0 to 5, differences among the R.sup.3 radicals being possible when m is 2 or 3; andn is from 0 to 2, a difference between the R.sup.5 radicals being possible when n is 2;and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.
摘要:
Pyridine derivatives of the formulae ##STR1## wherein W, X, Y and Z are each C--R.sup.4, N or N.fwdarw.O, with the proviso that the ring contains only one heteroatom, and the substituents R.sup.1, R.sup.2 and R.sup.3 have the following meanings:R.sup.1 is alkoxy, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, or substituted or unsubstituted alkynyl,R.sup.2 is hydrogen,R.sup.3 is formyl, 4,5-dihydrooxazol-2-yl or --CO--A--R.sup.5 or --CO--NR.sup.6.sup.R.sup.7, whereR.sup.4 is halogen, nitro, cyano, substituted or unsubstituted alkyl, substituted or unsubstituted benzyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted alkynyl, alkoxy, alkylthio, haloalkoxy, haloalkylthio, alkenyloxy, alkynyloxy, alkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, substituted or unsubstituted phenoxy or phenylthio, a substituted or unsubstituted 5- or 6-membered heterocyclic radical having one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, or is substituted or unsubstituted phenyl,A is oxygen or sulfur,R.sup.5 is hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted benzyl, cycloalkyl, substituted or unsubstituted phenyl,one equivalent of a cation or the radical --N.dbd.CR.sup.8 R.sup.9 andR.sup.6 and R.sup.7 are hydrogen or alkyl or together denote a methylene chain having 4 or 5 members,their agriculturally utilizable salts, and their use for controlling unwanted plant growth.
摘要:
Carboxamides Ia, Ib, Ic and Id ##STR1## (X=O, S; R.sup.1 =H, halogen, substituted or unsubstituted alkyl, substituted or unsubstituted benzyl, alkoxy, alkylthio, haloalkoxy, haloalkylthio, substituted or unsubstituted phenyl, substituted or unsubstituted phenoxy or phenylthio, a substituted or unsubstituted 5- or 6-membered heterocyclic radical containing one or two heteroatoms, cycloalkyl-substituted alkyl, substituted or unsubstituted alkenyl which may be epoxidized, substituted or unsubstituted alkynyl, substituted or unsubstituted cycloalkyl or cycloalkenyl; R.sup.1 '=cycloalkyl-substituted alkyl, substituted or unsubstituted alkenyl which may be epoxidized, substituted or unsubstituted cycloalkenyl; R.sup.2 =CHO, 4,5-dihydrooxazol-2-yl, COYR.sup.5, CONR.sup.6 R.sup.7 ; Y=O, S; R.sup.5 =H, substituted or unsubstituted alkyl, cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted cycloalkenyl, substituted or unsubstituted alkynyl, substituted or unsubstituted phenyl, a 5- or 6-membered heterocyclic radical containing up to 3 heteroatoms, benzotriazole, N-phthalimido, tetrahydrophthalimido, succinimido, maleiimido, 2,2-dimethyl-1,3-dioxolan-4-ylmethyl, 1,3-dioxolan-2-on-4-ylmethyl, and when Y.dbd.O: one equivalent of a cation from the group of the alkali or alkaline earth metals, Mn, Cu, Fe ammonium and substituted ammonium, a radical --N.dbd.CR.sup.8 R.sup.9 or --W--Z; R.sup.8, R.sup.9 .dbd.H, substituted or unsubstituted alkyl, substituted or unsubstituted haloalkyl, cycloalkyl, alkoxy, furanyl, substituted or unsubstituted phenyl; R.sup.8 +R.sup.9 =4-7-membered methylene chain; W=alkylene chain, ethoxyethylene chain, butylene, butynylene chain; Z=a molecular moiety bonded to W in the .omega.-position and is the same as that linked to W in the .alpha.-position of W; R.sup.6 .dbd.H, alkyl, cycloalkyl; R.sup.7 .dbd.H; alkyl; --C(O-alkyl).dbd.N--H or --(O--alkyl).dbd.N--alkyl; R.sup.6 +R.sup.7 =4-5-membered methylene chain; R.sup.3 .dbd.H, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl; R.sup.4 .dbd.H, OH, alkoxy, subsituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted alkynyl, di-(C.sub.1 -C.sub.4)-alkylamino, a substituted or unsubstituted 5- or 6-membered heterocyclic radical containing one or two heteroatoms, substituted or unsubstituted phenyl, substituted or unsubstituted naphthyl; R.sub.3 +R.sub.4 =4-7-membered methylene chain which may be interrupted by O, S or N--CH.sub.3, or --(CH.sub.2).sub.3 --CO--)and their environmentally tolerated salts.The compounds Ia to Id are suitable as herbicides.