Isoxazole(isothiazole)-5-carboxamides
    91.
    发明授权
    Isoxazole(isothiazole)-5-carboxamides 失效
    异佛唑(异噻唑)-5-羧酰胺

    公开(公告)号:US5080708A

    公开(公告)日:1992-01-14

    申请号:US337640

    申请日:1989-04-13

    摘要: Isoxazole(isothiazole)-5-carboxamides of the formula ##STR1## where X is oxygen or sulfur,R.sup.1 is hydrogen, substituted or unsubstituted alkyl, alkoxy, substituted or unsubstituted cycloalkyl, a 5- or 6-membered heterocyclic radical having one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, and which may be substituted, or substituted or unsubstituted phenyl, orR.sup.2 is formyl, 4,5-dihydrooxazol-2-yl or a radical of the formula COYR.sup.5 or CONR.sup.6 R.sup.7, whereY is oxygen or sulfur,R.sup.5 ishydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted alkenyl, haloalkenyl, substituted or unsubstituted alkynyl,cycloalkyl,cycloalkenyl,substituted or unsubstituted phenyl,a 5- or 6-membered heterocyclic radical having one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen,cycloalkanimino, phthalimido, succinimido, or a radical ##STR2## R.sup.3 and R.sup.4 have the meanings defined herein, or their agriculturally acceptable salts possess herbicidal activity.

    摘要翻译: 其中X是氧或硫,R 1是氢,取代或未取代的烷基,烷氧基,取代或未取代的环烷基,具有一个或两个的5-或6-元杂环基的异噻唑(异噻唑)-5-甲酰胺, 选自氧,硫和氮的杂原子,并且其可以被取代,或取代或未取代的苯基,或R 2是甲酰基,4,5-二氢恶唑-2-基或式COYR 5或CONR 6 R 7的基团,其中 Y是氧或硫,R5是氢,取代或未取代的烷基,取代或未取代的烯基,卤代烯基,取代或未取代的炔基,环烷基,环烯基,取代或未取代的苯基,具有一个或两个杂原子的5-或6-元杂环基 选自氧,硫和氮,环亚烷基亚氨基,邻苯二甲酰亚氨基,琥珀酰亚胺基或自由基,CH 2 CH(OH)CH 2(OH)等,R 3和R 4具有本文定义的含义或其农业 超可接受的盐具有除草活性。

    N-((6-trifluoromethyl
pyrimidin-2-yl)-aminocarbonyl)-2-carboalkoxybenzenesulfonamides
    92.
    发明授权
    N-((6-trifluoromethyl pyrimidin-2-yl)-aminocarbonyl)-2-carboalkoxybenzenesulfonamides 失效
    N - ((6-三氟甲基吡啶-2-基) - 氨基羰基)-2-羧酸甲苯磺酰胺

    公开(公告)号:US5069710A

    公开(公告)日:1991-12-03

    申请号:US337866

    申请日:1989-04-14

    IPC分类号: A01N47/36 C07D521/00

    CPC分类号: C07D521/00 A01N47/36

    摘要: N-((6-Trifluoromethylpyrimidin-2-yl)- aminocarbonyl)-2-carboalkoxybenzenesulfonamides of the general formula Ia ##STR1## where the substituents have the following meanings: R.sup.1 is hydrogen or halogen;R.sup.2 is hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.3 -C.sub.4 -alkenyl, C.sub.3 -C.sub.4 -alkynyl, C.sub.1 -C.sub.5 -haloalkyl, C.sub.3 -C.sub.5 -alkoxyalkyl, C.sub.3 -C.sub.5 -haloalkoxyalkyl or C.sub.5 -C.sub.6 -cycloalkyl,R.sup.3 is hydrogen, C.sub.1 -C.sub.2 -alkyl, allyl, propargyl or C.sub.1 -C.sub.5 -alkoxy,R.sup.4 is halogen, C.sub.1 -C.sub.2 -alkyl, C.sub.1 -C.sub.3 -alkylthio or C.sub.1 -C.sub.3 -alkylamino,R.sup.3 not denoting hydrogen or C.sub.1 -C.sub.2 -alkyl when R.sup.4 is C.sub.1 -C.sub.2 -alkyl, and their environmentally tolerated salts, processes for their manufacture, and their use.

    摘要翻译: 具有通式Ia的N - ((6-三氟甲基嘧啶-2-基) - 氨基羰基)-2-烷氧羰基苯磺酰胺其中取代基具有以下含义:R 1是氢或卤素; R2是氢,C1-C5-烷基,C3-C4-烯基,C3-C4-炔基,C1-C5-卤代烷基,C3-C5-烷氧基烷基,C3-C5-卤代烷氧基烷基或C5-C6-环烷基,R3是氢, C 1 -C 2 - 烷基,烯丙基,炔丙基或C 1 -C 5 - 烷氧基,R 4是卤素,C 1 -C 2烷基,C 1 -C 3 - 烷硫基或C 1 -C 3烷基氨基,R 3不表示氢或C 1 -C 2烷基 是C 1 -C 2烷基,及其环境耐受的盐,其制备方法及其用途。

    4-arryl-2-haloimidazole-5-carboxylic esters, the preparation and use
thereof
    93.
    发明授权
    4-arryl-2-haloimidazole-5-carboxylic esters, the preparation and use thereof 失效
    4-芳基-2-卤代咪唑-5-羧酸酯的制备和应用

    公开(公告)号:US5211737A

    公开(公告)日:1993-05-18

    申请号:US666483

    申请日:1991-03-06

    IPC分类号: A01N25/32 C07D233/90

    CPC分类号: A01N25/32 C07D233/90

    摘要: 4-Aryl-2-haloimidazole-5-carboxylic esters of the general formula Ia and Ib ##STR1## where R.sup.1 is C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl,R.sub.2 is C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl,Hal is chlorine or bromine,n is 0 to 3,x is C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, C.sub.1 -C.sub.4 -haloalkylthio, cyano, nitro, carbo-C.sub.1 -C.sub.4 -alkoxy, N,N-di-C.sub.1 -C.sub.4 -alkylcarbamoyl and/or halogen,processes for their manufacture, and their use in herbicidal agents as safeners in combination with at least one herbicidal active ingredient from the group consisting ofa) 2-(4-heteroaryloxy)- or 2-(4-aryloxy)-phenoxyacetic acid or -propionic acid derivatives andb) cyclohexenone derivatives.

    摘要翻译: 其中R 1是C 1 -C 6 - 烷基,C 3 -C 6 - 烯基或C 3 -C 6 - 炔基,R 2是(C 1 -C 6) - 烷基,C 3 -C 6 - 烯基或C 3 -C 6炔基的4-芳基-2-卤代咪唑-5-羧酸酯 C 1 -C 6 - 烷基,C 3 -C 6 - 烯基或C 3 -C 6炔基,Hal为氯或溴,n为0至3,x为C 1 -C 4烷基,C 1 -C 4卤代烷基,C 1 -C 4 - 烷氧基, C 1 -C 4 - 卤代烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4烷基亚磺酰基,C 1 -C 4烷基磺酰基,C 1 -C 4卤代烷硫基,氰基,硝基,C 1 -C 4 - 烷氧基,N, C4-烷基氨基甲酰基和/或卤素,其制备方法和它们在除草剂中的用途作为安全剂与至少一种除草活性成分组合,所述除草活性成分包括a)2-(4-杂芳氧基) - 或2-(4 - 芳氧基) - 苯氧基乙酸或 - 丙酸衍生物,和b)环己烯酮衍生物。

    Substituted sulfonylureas
    97.
    发明授权
    Substituted sulfonylureas 失效
    取代磺酰脲类

    公开(公告)号:US5032167A

    公开(公告)日:1991-07-16

    申请号:US448984

    申请日:1989-12-12

    CPC分类号: C07D521/00 A01N47/36

    摘要: Substituted sulfonylureas of the formula I ##STR1## where the substituents and indices have the following meanings: x is oxygen or sulfur;z is nitrogen or methine (=CH--);R.sup.1 is halogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxycarbonyl or C.sub.1 -C.sub.3 -alkoxy, or a radical --CONR.sup.6 R.sup.7, whereR.sup.6 is hydrogen, C.sub.1 -C.sub.8 -alkyl or C.sub.1 -C.sub.6 -alkoxy andR.sup.7 is hydrogen or C.sub.1 -C.sub.8 -alkyl;R.sup.2 is halogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkyl;R.sup.3 is C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkylthio, halogen, cyano, nitro, amino, mono-C.sub.1 -C.sub.4 -alkylamino, di-C.sub.1 -C.sub.4 -alkylamino, C.sub.2 -C.sub.6 -alkenyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkanoyl or benzyl; a 5- or 6-membered saturated heterocycle which is attached by its nitrogen atom and which, besides methylene and a nitrogen, may also contain an oxygen or a sulfur atom; or, bonded to adjacent ring positions, --OCRR'O--, where R and R' are each hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.5 is halogen C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio or C.sub.1 -C.sub.4 -haloalkyl;m is from 0 to 3 or, when R.sup.3 is halogen, from 0 to 5, differences among the R.sup.3 radicals being possible when m is 2 or 3; andn is from 0 to 2, a difference between the R.sup.5 radicals being possible when n is 2;and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.

    摘要翻译: 取代基和指数具有以下含义的式I的取代磺酰脲类:x是氧或硫; z是氮或次甲基(= CH-); R 1是卤素或取代或未取代的C 1 -C 4 - 烷氧基羰基或C 1 -C 3 - 烷氧基或基团-CONR 6 R 7,其中R 6是氢,C 1 -C 8 - 烷基或C 1 -C 6 - 烷氧基,并且R 7是氢或C 1 -C 8 - 烷基; R2是卤素或取代或未取代的C1-C4-烷氧基或C1-C4-烷基; R 3是C 1 -C 4烷基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷基,C 1 -C 4卤代烷氧基,C 1 -C 4卤代烷硫基,卤素,氰基,硝基,氨基,单-C 1 -C 4烷基氨基, C 1 -C 4 - 烷基氨基,C 2 -C 6 - 烯基,C 1 -C 4 - 烷氧基羰基,C 1 -C 4 - 烷酰基或苄基; 通过其氮原子连接的5-或6-元饱和杂环,除了亚甲基和氮之外,还可以含有氧或硫原子; 或者,与相邻的环位置键合,-OCRR'O-,其中R和R'各自为氢或C1-C4-烷基; R4是氢或C1-C4-烷基; R5是卤素C1-C4-烷基,C1-C4-烷氧基,C1-C4-烷硫基或C1-C4卤代烷基; m为0至3,或当R3为卤素时为0至5,当m为2或3时,R3基团之间的差异是可能的; n为0〜2,当n为2时,R5基团之间的差异是可能的; 及其环境可接受的盐,其制备方法,以及它们作为除草剂的用途。

    Substituted sulfonylureas
    98.
    发明授权
    Substituted sulfonylureas 失效
    取代的SULFONYLUREAS

    公开(公告)号:US5100459A

    公开(公告)日:1992-03-31

    申请号:US622487

    申请日:1990-12-05

    CPC分类号: C07D521/00 A01N47/36

    摘要: Substituted sulfonylureas of the formula I ##STR1## where the substituents and indices have the following meanings: X is oxygen or sulfur;Z is nitrogen or methine (.dbd.CH--);R.sup.1 is halogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxycarbonyl or C.sub.1 -C.sub.3 -alkoxy, or a radical --CONR.sup.6 R.sup.7, whereR.sup.6 is hydrogen, C hd 1-C.sub.8 -alkyl or C.sub.1 -C.sub.6 -alkoxy andR.sup.7 is hydrogen or C.sub.1 -C.sub.8 -alkyl;R.sup.2 is halogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkyl;R.sup.3 is C.sub.1 -C.sub.4 -alkyl, C hd 1-C.sub.4 -alkylthio, C hd 1-C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -haloalkylthio, halogen, cyano, nitro, amino, mono-C.sub.1 -C.sub.4 -alkylamino, di-C.sub.1 -C.sub.4 -alkylamino, C hd 2-C.sub.6 -alkenyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkanoyl or benzyl; a 5- or 6-membered saturated heterocycle which is attached by its nitrogen atom and which, besides methylene and a nitrogen, may also contain an oxygen or a sulfur atom; or, bonded to adjacent ring positions, --OCRR'O--, where R and R' are each hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.5 is halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio or C.sub.1 -C.sub.4 -haloalkyl;m is from 0 to 3 or, when R.sup.3 is halogen, from 0 to 5, differences among the R.sup.3 radicals being possible when m is 2 or 3; andn is from 0 to 2, a difference between the R.sup.5 radicals being possible when n is 2;and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.

    Pyridine derivatives and their use for controlling undesirable plant
growth
    99.
    发明授权
    Pyridine derivatives and their use for controlling undesirable plant growth 失效
    吡啶衍生物及其用于控制​​不希望的植物生长的用途

    公开(公告)号:US5262387A

    公开(公告)日:1993-11-16

    申请号:US783310

    申请日:1991-11-20

    摘要: Pyridine derivatives of the formulae ##STR1## wherein W, X, Y and Z are each C--R.sup.4, N or N.fwdarw.O, with the proviso that the ring contains only one heteroatom, and the substituents R.sup.1, R.sup.2 and R.sup.3 have the following meanings:R.sup.1 is alkoxy, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, or substituted or unsubstituted alkynyl,R.sup.2 is hydrogen,R.sup.3 is formyl, 4,5-dihydrooxazol-2-yl or --CO--A--R.sup.5 or --CO--NR.sup.6.sup.R.sup.7, whereR.sup.4 is halogen, nitro, cyano, substituted or unsubstituted alkyl, substituted or unsubstituted benzyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted alkynyl, alkoxy, alkylthio, haloalkoxy, haloalkylthio, alkenyloxy, alkynyloxy, alkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, substituted or unsubstituted phenoxy or phenylthio, a substituted or unsubstituted 5- or 6-membered heterocyclic radical having one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, or is substituted or unsubstituted phenyl,A is oxygen or sulfur,R.sup.5 is hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted benzyl, cycloalkyl, substituted or unsubstituted phenyl,one equivalent of a cation or the radical --N.dbd.CR.sup.8 R.sup.9 andR.sup.6 and R.sup.7 are hydrogen or alkyl or together denote a methylene chain having 4 or 5 members,their agriculturally utilizable salts, and their use for controlling unwanted plant growth.

    摘要翻译: 其中W,X,Y和Z各自为C-R 4,N或N-> O的吡啶衍生物,条件是环仅含有一个杂原子,并且取代基R 1,R 2和 R3具有以下含义:R 1是烷氧基,取代或未取代的烷基,取代或未取代的环烷基,取代或未取代的烯基,或取代或未取代的炔基,R 2是氢,R 3是甲酰基,4,5-二氢恶唑-2-基或 - CO-A-R5或-CO-NR6R7,其中R4是卤素,硝基,氰基,取代或未取代的烷基,取代或未取代的苄基,取代或未取代的环烷基,取代或未取代的烯基,取代或未取代的炔基,烷氧基,烷硫基,卤代烷氧基 卤代烷硫基,烯氧基,炔氧基,烷基亚磺酰基,烷基磺酰基,卤代烷基磺酰基,取代或未取代的苯氧基或苯硫基,取代或未取代的具有一个或两个选自基团的杂原子的5-或6-元杂环基 氧,硫和氮的取代基,或者是取代或未取代的苯基,A是氧或硫,R5是氢,取代或未取代的烷基,取代或未取代的苄基,环烷基,取代或未取代的苯基,1当量的阳离子或基团 -N = CR8R9,R6和R7是氢或烷基或一起表示具有4或5个成员的亚甲基链,它们的农业上可利用的盐,以及它们用于控制不想要的植物生长的用途。

    Carboxamides
    100.
    发明授权

    公开(公告)号:US5201932A

    公开(公告)日:1993-04-13

    申请号:US877365

    申请日:1992-05-04

    摘要: Carboxamides Ia, Ib, Ic and Id ##STR1## (X=O, S; R.sup.1 =H, halogen, substituted or unsubstituted alkyl, substituted or unsubstituted benzyl, alkoxy, alkylthio, haloalkoxy, haloalkylthio, substituted or unsubstituted phenyl, substituted or unsubstituted phenoxy or phenylthio, a substituted or unsubstituted 5- or 6-membered heterocyclic radical containing one or two heteroatoms, cycloalkyl-substituted alkyl, substituted or unsubstituted alkenyl which may be epoxidized, substituted or unsubstituted alkynyl, substituted or unsubstituted cycloalkyl or cycloalkenyl; R.sup.1 '=cycloalkyl-substituted alkyl, substituted or unsubstituted alkenyl which may be epoxidized, substituted or unsubstituted cycloalkenyl; R.sup.2 =CHO, 4,5-dihydrooxazol-2-yl, COYR.sup.5, CONR.sup.6 R.sup.7 ; Y=O, S; R.sup.5 =H, substituted or unsubstituted alkyl, cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted cycloalkenyl, substituted or unsubstituted alkynyl, substituted or unsubstituted phenyl, a 5- or 6-membered heterocyclic radical containing up to 3 heteroatoms, benzotriazole, N-phthalimido, tetrahydrophthalimido, succinimido, maleiimido, 2,2-dimethyl-1,3-dioxolan-4-ylmethyl, 1,3-dioxolan-2-on-4-ylmethyl, and when Y.dbd.O: one equivalent of a cation from the group of the alkali or alkaline earth metals, Mn, Cu, Fe ammonium and substituted ammonium, a radical --N.dbd.CR.sup.8 R.sup.9 or --W--Z; R.sup.8, R.sup.9 .dbd.H, substituted or unsubstituted alkyl, substituted or unsubstituted haloalkyl, cycloalkyl, alkoxy, furanyl, substituted or unsubstituted phenyl; R.sup.8 +R.sup.9 =4-7-membered methylene chain; W=alkylene chain, ethoxyethylene chain, butylene, butynylene chain; Z=a molecular moiety bonded to W in the .omega.-position and is the same as that linked to W in the .alpha.-position of W; R.sup.6 .dbd.H, alkyl, cycloalkyl; R.sup.7 .dbd.H; alkyl; --C(O-alkyl).dbd.N--H or --(O--alkyl).dbd.N--alkyl; R.sup.6 +R.sup.7 =4-5-membered methylene chain; R.sup.3 .dbd.H, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl; R.sup.4 .dbd.H, OH, alkoxy, subsituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted alkynyl, di-(C.sub.1 -C.sub.4)-alkylamino, a substituted or unsubstituted 5- or 6-membered heterocyclic radical containing one or two heteroatoms, substituted or unsubstituted phenyl, substituted or unsubstituted naphthyl; R.sub.3 +R.sub.4 =4-7-membered methylene chain which may be interrupted by O, S or N--CH.sub.3, or --(CH.sub.2).sub.3 --CO--)and their environmentally tolerated salts.The compounds Ia to Id are suitable as herbicides.