Separation of polar gases from nonpolar gases
    91.
    发明授权
    Separation of polar gases from nonpolar gases 失效
    极性气体与非极性气体的分离

    公开(公告)号:US4608060A

    公开(公告)日:1986-08-26

    申请号:US723398

    申请日:1985-04-15

    摘要: Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

    摘要翻译: 通过在分离条件下将极性和非极性气体的混合物通过多组分膜的表面,可以将极性气体如硫化氢,二氧化硫和氨与非极性气体如甲烷,氮气,氢气或二氧化碳分离。 用于进行分离的多组分膜将包含分子量为约200至约600的二醇增塑剂和多孔载体上浇铸的有机聚合物的混合物。 在聚砜上复合的聚乙二醇和硅橡胶所示的这种膜的使用将允许在分离过程中伴随着高通量速率的更大的选择性。

    Process for separating C.sub.6 olefin hydrocarbons
    92.
    发明授权
    Process for separating C.sub.6 olefin hydrocarbons 失效
    分离C6烯烃的方法

    公开(公告)号:US4486618A

    公开(公告)日:1984-12-04

    申请号:US522759

    申请日:1983-08-12

    IPC分类号: C07C7/13 C10G25/00

    CPC分类号: C10G25/003 C07C7/13

    摘要: A process for separating a normal C.sub.6 olefin hydrocarbon from a mixture of the same with a C.sub.6 olefin branched chain and/or cyclic hydrocarbon. The process comprises contacting the mixture at separation conditions with a molecular sieve comprising a crystalline silica. The normal C.sub.6 olefin hydrocarbon is selectively retained and will be recovered from the molecular sieve by displacement with a displacement material comprising pentene-1 or butene-1. The process preferably employs a simulated moving bed.

    摘要翻译: 从C 6烯烃支链和/或环状烃与其混合物中分离正常C 6烯烃的方法。 该方法包括在分离条件下将混合物与包含结晶二氧化硅的分子筛接触。 选择性地保留正常的C 6烯烃,并通过用包含戊烯-1或丁烯-1的置换材料置换而从分子筛中回收。 该方法优选采用模拟移动床。

    Separation of sucrose from thick juice
    93.
    发明授权
    Separation of sucrose from thick juice 失效
    从浓汁中分离蔗糖

    公开(公告)号:US4475954A

    公开(公告)日:1984-10-09

    申请号:US485350

    申请日:1983-04-15

    IPC分类号: C13B20/14 C13D3/14

    CPC分类号: C13B20/148

    摘要: Sucrose which is found in thick juice such as obtained from sugar beet or sugar cane may be selectively extracted therefrom by passing an aqueous solution of the thick juice over a solid adsorbent comprising a stabilized type Y zeolite such as Union Carbide Corporation LZ-Y20 adsorbent, preferably bound with a water permeable organic polymer. The sucrose will be selectively adsorbed thereon and separated from other thick juice ingredients such as raffinose, KCl and betaine. The sucrose is then removed from the adsorbent by treatment with a desorbent material comprising an alcohol. The desorbent is flushed from the adsorbent with water prior to the subsequent contact of the adsorbent with the feed stream.

    摘要翻译: 可以通过将稠汁的水溶液通过包含稳定型Y沸石的固体吸附剂(例如Union Carbide Corporation LZ-Y20吸附剂)来选择性地从其中提取从糖甜菜或甘蔗获得的浓汁中的蔗糖, 优选与水可渗透的有机聚合物结合。 蔗糖将被选择性地吸附在其上并与其他浓汁成分如棉子糖,KCl和甜菜碱分离。 然后通过用包含醇的解吸材料处理从吸附剂中除去蔗糖。 在吸附剂随后与进料流接触之前,将解吸剂从吸附剂中冲洗。

    Zeolite molecular sieve having reduced solubility in an aqueous system
    94.
    发明授权
    Zeolite molecular sieve having reduced solubility in an aqueous system 失效
    沸石分子筛在水性体系中的溶解度降低

    公开(公告)号:US4406819A

    公开(公告)日:1983-09-27

    申请号:US360098

    申请日:1982-03-19

    摘要: This invention relates to an improved adsorbent comprising a crystalline aluminosilicate, method of manufacture of the adsorbent and improved process for separating a component from a feed mixture comprising an aqueous solution of a mixture of different components, such as a mixture of saccharides. In the process the mixture is contacted with the adsorbent, which selectively adsorbs a component from the feed mixture. The adsorbed component is then recovered by contacting the adsorbent with a desorbent material such as water to effect the desorption of the adsorbed component from the adsorbent. There is an undesirable tendency for the silicon constituent of the crystalline aluminosilicate to dissolve in the aqueous system. The improvement to the adsorbent and process comprises the incorporation of a binder material in the adsorbent comprising a cellulose ether which substantially reduces the undesirable dissolution. The adsorbent is manufactured by mixing together powder of the crystalline aluminosilicate, powders of the binder, and a liquid organic solvent, extruding the mixture into an extrudate and drying the extrudate.

    摘要翻译: 本发明涉及包含结晶硅铝酸盐的改进的吸附剂,制备吸附剂的方法和用于从包含不同组分的混合物的水溶液如糖的混合物的进料混合物中分离组分的改进方法。 在该过程中,混合物与吸附剂接触,吸附剂从进料混合物中选择性吸附组分。 然后通过使吸附剂与解吸材料如水接触来回收吸附的组分,以实现吸附组分从吸附剂的解吸附。 结晶硅铝酸盐的硅成分溶解在水性体系中是不希望的。 对吸附剂和方法的改进包括在包含纤维素醚的吸附剂中引入粘合剂材料,其基本上减少不期望的溶解。 吸附剂通过将结晶硅铝酸盐的粉末,粘合剂的粉末和液体有机溶剂混合在一起来制造,将混合物挤出成挤出物并干燥挤出物。

    Process for separating fatty acids from rosin acids
    95.
    发明授权
    Process for separating fatty acids from rosin acids 失效
    将脂肪酸与松香酸分离的方法

    公开(公告)号:US4404145A

    公开(公告)日:1983-09-13

    申请号:US407672

    申请日:1982-08-12

    IPC分类号: C07C51/47 C11C1/08

    CPC分类号: C07C51/47 C11C1/08

    摘要: This invention comprises a process for separating a fatty acid from a mixture comprising a fatty acid and a rosin acid, which process comprises contacting the mixture at separation conditions with a molecular sieve comprising silicalite, thereby selectively retaining the fatty acid. The fatty acid may be recovered from the molecular sieve by displacement with a displacement fluid. It is preferred that the displacement fluid comprise a liquid having a minimum polarity index.

    摘要翻译: 本发明包括从包含脂肪酸和松香酸的混合物中分离脂肪酸的方法,该方法包括使分离条件下的混合物与包含硅沸石的分子筛接触,从而选择性地保留脂肪酸。 脂肪酸可以通过用置换流体置换从分子筛中回收。 优选地,排量流体包括具有最小极性指数的液体。

    Use of activated carbon for separation of ethanol from water
    96.
    发明授权
    Use of activated carbon for separation of ethanol from water 失效
    使用活性炭将乙醇与水分离

    公开(公告)号:US4382001A

    公开(公告)日:1983-05-03

    申请号:US316363

    申请日:1981-10-29

    摘要: An adsorptive separation process for separating ethanol from a feed mixture comprising ethanol and water, which process comprises contacting the feed mixture with an adsorbent comprising activated carbon, selectively adsorbing substantially all of the ethanol to be separated to the substantial exclusion of the water and thereafter recovering high purity ethanol. A desorption step is used to desorb the adsorbed ethanol with the desorbent selected being capable of direct blending into motor fuel.

    摘要翻译: 一种用于从包含乙醇和水的进料混合物中分离乙醇的吸附分离方法,该方法包括使进料混合物与包含活性炭的吸附剂接触,所述吸附剂基本上吸附要分离的基本上所有的乙醇以实质上排除水,然后回收 高纯度乙醇。 使用解吸步骤解吸吸附的乙醇,所选择的解吸剂能够直接混合到马达燃料中。

    Zeolite molecular sieve adsorbent for an aqueous system
    97.
    发明授权
    Zeolite molecular sieve adsorbent for an aqueous system 失效
    沸石分子筛吸附剂用于水系统

    公开(公告)号:US4372876A

    公开(公告)日:1983-02-08

    申请号:US353683

    申请日:1982-03-01

    摘要: An improved adsorbent comprising a crystalline aluminosilicate, method of manufacture of the adsorbent and improved process for separating a component from a feed mixture comprising an aqueous solution of a mixture of different components, such as a mixture of saccharides. In the process the mixture is contacted with the adsorbent, which selectively adsorbs a component from the feed mixture. The adsorbed component is then recovered by contacting the adsorbent with a desorbent material such as water to effect the desorption of the adsorbed component from the adsorbent. There is an undesirable tendency for the silicon constituent of the crystalline aluminosilicate to dissolve in the aqueous system. The improvement to the adsorbent and process comprises the coating of the adsorbent with ethylcellulose which substantially reduces the undeirable dissolution. The adsorbent is manufactured by mixing together the uncoated precursor of the adsorbent with the organic polymer dissolved in a liquid organic solvent, and removing the solvent.

    摘要翻译: 一种改进的吸附剂,包括结晶硅铝酸盐,制造吸附剂的方法和用于从包含不同组分的混合物的水溶液如糖的混合物的进料混合物中分离组分的改进方法。 在该过程中,混合物与吸附剂接触,吸附剂从进料混合物中选择性吸附组分。 然后通过使吸附剂与解吸材料如水接触来回收吸附的组分,以实现吸附组分从吸附剂的解吸附。 结晶硅铝酸盐的硅成分溶解在水性体系中是不希望的。 对吸附剂和方法的改进包括用乙基纤维素涂覆吸附剂,其基本上降低了不可取的溶解度。 吸附剂通过将未涂覆的吸附剂前体与溶解在液体有机溶剂中的有机聚合物混合在一起并除去溶剂来制造。

    Process for separating normal paraffins using silicalite adsorbent
    98.
    发明授权
    Process for separating normal paraffins using silicalite adsorbent 失效
    使用硅沸石吸附剂分离正链烷烃的方法

    公开(公告)号:US4367364A

    公开(公告)日:1983-01-04

    申请号:US288570

    申请日:1981-07-30

    CPC分类号: C10G25/003 C07C7/13

    摘要: A process for separating a normal paraffin from a mixture of the same with another structural class of hydrocarbon selected from the cyclic hydrocarbons having greater than six carbons per molecule and the branched chain hydrocarbons. The process comprises contacting the mixture at adsorption conditions with an adsorbent comprising silicalite. The normal paraffin is selectively adsorbed and will preferably be recovered from the adsorbent by desorption with a desorbent material.

    摘要翻译: 将正链烷烃与其它结构类别的烃的混合物分离开来的方法,该烃类选自每分子具有大于6个碳的环状烃和支链烃。 该方法包括在吸附条件下将混合物与包含硅沸石的吸附剂接触。 常规石蜡选择性吸附,并且优选通过用解吸剂材料解吸从吸附剂中回收。

    Separation process using cellulose acetate butyrate bound zeolite
adsorbents
    99.
    发明授权
    Separation process using cellulose acetate butyrate bound zeolite adsorbents 失效
    分离方法采用醋酸丁酸纤维素结合沸石吸附剂

    公开(公告)号:US4363672A

    公开(公告)日:1982-12-14

    申请号:US252663

    申请日:1981-04-09

    IPC分类号: B01J20/18 C13K13/00 C13D3/14

    CPC分类号: B01J20/183 C13K13/007

    摘要: An improved process for separating a component from a feed mixture comprising an aqueous solution of a mixture of different components, such as a mixture of saccharides. In the process the mixture is contacted with an adsorbent comprising a crystalline aluminosilicate, which selectively adsorbs a component from the feed mixture. The adsorbed component is then recovered by contacting the adsorbent with a desorbent material such as water to effect the desorption of the adsorbed component from the adsorbent. There is an undesirable tendency for the silicon constituent of the crystalline aluminosilicate to dissolve in the aqueous system. The improvement to the adsorbent and process comprises the incorporation of a binder material in the adsorbent comprising cellulose acetate butyrate which substantially reduces the undesirable dissolution. The adsorbent is manufactured by mixing together powder of the crystalline aluminosilicate, powders of the binder, and a liquid organic solvent, extruding the mixture into an extrudate and drying the extrudate.

    摘要翻译: 用于从包含不同组分的混合物的水溶液的进料混合物中分离组分的改进方法,例如糖的混合物。 在该过程中,混合物与包含结晶硅铝酸盐的吸附剂接触,该结晶硅铝酸盐选择性地从进料混合物中吸附组分。 然后通过使吸附剂与解吸材料如水接触来回收吸附的组分,以实现吸附组分从吸附剂的解吸附。 结晶硅铝酸盐的硅成分溶解在水性体系中是不希望的。 对吸附剂和方法的改进包括在包含乙酸丁酸纤维素的吸附剂中引入粘合剂材料,其基本上减少了不期望的溶解。 吸附剂通过将结晶硅铝酸盐的粉末,粘合剂的粉末和液体有机溶剂混合在一起来制造,将混合物挤出成挤出物并干燥挤出物。

    Ethylene Production By Steam Cracking of Normal Paraffins
    100.
    发明申请
    Ethylene Production By Steam Cracking of Normal Paraffins 有权
    乙烷生产通过蒸汽裂解正常石蜡

    公开(公告)号:US20110245556A1

    公开(公告)日:2011-10-06

    申请号:US12749817

    申请日:2010-03-30

    IPC分类号: C07C4/02

    摘要: A simulated moving bed adsorptive separation process for preparing the separate feed streams charged to naphtha reforming unit and a steam cracking unit has been developed. The feed stream to the overall unit is passed into the adsorptive separation unit. The desorbent in the adsorptive separation is C12 hydrocarbons. The simulated moving bed adsorptive separation separates the components of the feed stream into a normal paraffin stream, which is charged to the steam cracking process, and non-normal hydrocarbons which are passed into a reforming zone. The desorbent is readily separated from the normal paraffin stream and from the non-normal paraffin stream and the simulated moving bed adsorption zone is operated at an A/Fn ratio of from about 0.90 to about 0.92.

    摘要翻译: 已经开发了用于制备装载到石脑油重整单元和蒸汽裂解装置的单独进料流的模拟移动床吸附分离方法。 到整个单元的进料流被送入吸附分离单元。 吸附分离中的解吸剂是C12烃。 模拟的移动床吸附分离将进料流的组分分离成正常的石蜡流,将其装入蒸汽裂解过程,并将非正常烃进入重整区。 解吸剂容易地与正链烷烃流和非正构链烷烃流分离,并且模拟移动床吸附区以约0.90至约0.92的A / Fn比操作。