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公开(公告)号：US4475954A
公开(公告)日：1984-10-09
申请号：US485350
申请日：1983-04-15
CPC分类号： C13B20/148
摘要： Sucrose which is found in thick juice such as obtained from sugar beet or sugar cane may be selectively extracted therefrom by passing an aqueous solution of the thick juice over a solid adsorbent comprising a stabilized type Y zeolite such as Union Carbide Corporation LZ-Y20 adsorbent, preferably bound with a water permeable organic polymer. The sucrose will be selectively adsorbed thereon and separated from other thick juice ingredients such as raffinose, KCl and betaine. The sucrose is then removed from the adsorbent by treatment with a desorbent material comprising an alcohol. The desorbent is flushed from the adsorbent with water prior to the subsequent contact of the adsorbent with the feed stream.
摘要翻译： 可以通过将稠汁的水溶液通过包含稳定型Y沸石的固体吸附剂（例如Union Carbide Corporation LZ-Y20吸附剂）来选择性地从其中提取从糖甜菜或甘蔗获得的浓汁中的蔗糖， 优选与水可渗透的有机聚合物结合。 蔗糖将被选择性地吸附在其上并与其他浓汁成分如棉子糖，KCl和甜菜碱分离。 然后通过用包含醇的解吸材料处理从吸附剂中除去蔗糖。 在吸附剂随后与进料流接触之前，将解吸剂从吸附剂中冲洗。
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公开(公告)号：US4524029A
公开(公告)日：1985-06-18
申请号：US534911
申请日：1983-09-22
CPC分类号： C11C1/005
摘要： This invention comprises a process for separating a saturated fatty acid from a feed mixture comprising saturated and unsaturated fatty acids, which process comprises contacting the mixture at separation conditions with a molecular sieve comprising a crystalline silica, thereby selectively retaining the saturated fatty acid. The saturated fatty acid is recovered from the molecular sieve by displacement at displacement conditions with a displacement fluid comprising a diluent soluble in the feed mixture and having a polarity index of at least 3.5. Amorphous silica is a preferred binder for the molecular sieve.
摘要翻译： 本发明包括从包含饱和和不饱和脂肪酸的进料混合物中分离饱和脂肪酸的方法，该方法包括在分离条件下将混合物与包含结晶二氧化硅的分子筛接触，由此选择性地保留饱和脂肪酸。 饱和脂肪酸通过在包含可溶于进料混合物中并具有至少3.5的极性指数的稀释剂的置换流体的置换条件下从分子筛中回收。 无定形二氧化硅是用于分子筛的优选粘合剂。
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公开(公告)号：US5127925A
公开(公告)日：1992-07-07
申请号：US346256
申请日：1989-04-28
CPC分类号： B01D53/22 , B01D53/228 , B01D67/0079 , B01D69/147 , B01D69/148 , B01D71/028 , B01D71/70
摘要： A fluid feed mixture, either liquid or gaseous in nature, may be subjected to a gas enrichment separation process. The process is effected by contacting the mixture with the upstream face of a mixed matrix membrane which comprises an organic polymer having a solid particulate adsorbent incorporated therein, the permeability coefficient of the organic polymer being compatible with the permeability coefficient of the adsorbent. The permeate which emanates from the downstream face of the membrane comprises a fluid product mixture in which the proportion of the first fluid component of the feed mixture, which possesses a greater steady state permeability in relation to the second fluid component, is greater than the proportion present in the original fluid feed mixture.
摘要翻译： 本质上液体或气体的流体进料混合物可以进行气体富集分离过程。 该方法通过使混合物与混合基质膜的上游面接触来实现，该混合基质膜包含其中结合有固体颗粒吸附剂的有机聚合物，有机聚合物的渗透系数与吸附剂的渗透系数相适应。 从膜的下游面发出的渗透物包括流体产物混合物，其中相对于第二流体组分具有更大的稳态渗透性的进料混合物的第一流体组分的比例大于比例 存在于原始流体进料混合物中。
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公开(公告)号：US4524030A
公开(公告)日：1985-06-18
申请号：US539859
申请日：1983-10-07
IPC分类号： C11C1/08
摘要： This invention comprises a process for separating a fatty acid from a mixture comprising a fatty acid and a rosin acid, which process comprises contacting the mixture at separation conditions with a molecular sieve comprising a crystalline silica, thereby selectively retaining the fatty acid. The fatty acid is recovered from the molecular sieve by displacement with a displacement fluid comprising an ester containing less than six carbon atoms per molecule. Once the rosin acid is removed from the feed mixture, the process is also effective in separating the fatty acids from each other, using the same molecular sieve and displacement fluid.
摘要翻译： 本发明包括从包含脂肪酸和松香酸的混合物中分离脂肪酸的方法，该方法包括在分离条件下使混合物与包含结晶二氧化硅的分子筛接触，从而选择性地保留脂肪酸。 通过置换含有每分子含有少于6个碳原子的酯的置换液从分子筛中回收脂肪酸。 一旦从进料混合物中除去松香酸，该方法也有效地使用相同的分子筛和置换流体彼此分离脂肪酸。
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公开(公告)号：US4519952A
公开(公告)日：1985-05-28
申请号：US533463
申请日：1983-09-19
IPC分类号： C11C1/08
CPC分类号： C11C1/08
摘要： This invention comprises a process for separating a fatty acid from a mixture comprising a fatty acid and an unsaponifiable compound, which process comprises contacting the mixture at separation conditions with a molecular sieve comprising a crystalline silica having a silica to alumina mole ratio of at least 12, thereby selectively retaining the fatty acid. The fatty acid is recovered from the molecular sieve by displacement at displacement conditions with a displacement fluid soluble in the feed mixture and having a polarity index of at least 3.5.
摘要翻译： 本发明包括从包含脂肪酸和不皂化合物的混合物中分离脂肪酸的方法，该方法包括在分离条件下将混合物与包含二氧化硅与氧化铝摩尔比为至少12的结晶二氧化硅的分子筛 ，从而选择性地保留脂肪酸。 脂肪酸通过在置换条件下置换而从分子筛中回收，其中位移流体可溶于进料混合物并具有至少3.5的极性指数。
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公开(公告)号：US4511514A
公开(公告)日：1985-04-16
申请号：US435134
申请日：1982-10-18
CPC分类号： C07C51/47 , C11B13/005 , C11C1/08 , Y02W30/74
摘要： This invention comprises a process for separating oleic acid from a feed mixture comprising an oleic acid and linoleic acid, which process comprises contacting the mixture at separation conditions with a molecular sieve comprising silicalite, thereby selectively retaining the oleic acid. The oleic acid may be recovered from the molecular sieve by displacement with a displacement fluid. The feed mixture may also contain rosin acids in which case a first molecular sieve comprising silicalite is used to separate the fatty acids from the rosin acids.
摘要翻译： 本发明包括从包含油酸和亚油酸的进料混合物中分离油酸的方法，该方法包括在分离条件下将混合物与包含硅沸石的分子筛接触，从而选择性地保留油酸。 可以通过用置换流体置换从分子筛中回收油酸。 进料混合物还可以含有松香酸，在这种情况下，使用包含硅沸石的第一分子筛将脂肪酸与松香酸分离。
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公开(公告)号：US4343623A
公开(公告)日：1982-08-10
申请号：US219121
申请日：1980-12-22
摘要： An adsorptive separation process for separating ethanol from a feed mixture comprising ethanol and water, which process comprises contacting the feed mixture with an adsorbent comprising esterified silica selectively adsorbing substantially all of the ethanol to be separated to the substantial exclusion of the water and thereafter recovering high purity ethanol. A desorption step may be used to desorb the adsorbed ethanol.
摘要翻译： 用于从包含乙醇和水的进料混合物中分离乙醇的吸附分离方法，该方法包括使进料混合物与包含酯化二氧化硅的吸附剂接触，所述吸附剂选择性地吸附要分离的基本上所有的乙醇以实质上排除水，然后回收高 纯乙醇。 解吸步骤可用于解吸吸附的乙醇。
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公开(公告)号：US4329280A
公开(公告)日：1982-05-11
申请号：US252745
申请日：1981-04-10
IPC分类号： C11B7/00 , B01D15/00 , B01D15/08 , B01J20/10 , B01J20/34 , C07C51/00 , C07C51/42 , C07C51/47 , C07C57/12 , C07C67/00 , C07C67/48 , C07C67/56 , C07C69/003 , C07C69/753 , C09F1/00 , C09F1/02 , C11B1/00 , C11B3/10 , C11C20060101 , C11C1/08 , C09F1/04
CPC分类号： C11C1/08 , C07C51/47 , C07C67/56 , C07C2103/26
摘要： This invention comprises a process for separating an ester of a fatty acid from a mixture comprising an ester of a fatty acid and an ester of a rosin acid, which process comprises contacting the mixture at adsorption conditions with an adsorbent comprising silicalite, thereby selectively adsorbing the ester of a fatty acid. Preferably the ester of a fatty acid will be recovered from the adsorbent by desorption with a desorbent material.
摘要翻译： 本发明包括从包含脂肪酸酯和松香酸酯的混合物中分离脂肪酸酯的方法，该方法包括在吸附条件下将混合物与包含硅沸石的吸附剂接触，从而选择性地吸附 脂肪酸酯。 优选地，脂肪酸的酯将通过用解吸剂材料的解吸从吸附剂中回收。
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公开(公告)号：US4740219A
公开(公告)日：1988-04-26
申请号：US858321
申请日：1986-05-01
CPC分类号： B01D69/141 , B01D53/228
摘要： A fluid feed mixture, either liquid or gaseous in nature, may be subjected to a gas enrichment separation process. The process is effected by contacting the mixture with the upstream face of a mixed matrix membrane which comprises an organic polymer having a solid particulate adsorbent incorporated therein, the permeability coefficient of the organic polymer being compatible with the permeability coefficient of the adsorbent. The permeate which emanates from the downstream face of the membrane comprises a fluid product mixture in which the proportion of the first fluid component of the feed mixture, which possesses a greater steady state permeability in relation to the second fluid component, is greater than the proportion present in the original fluid feed mixture.
摘要翻译： 本质上液体或气体的流体进料混合物可以进行气体富集分离过程。 该方法通过使混合物与混合基质膜的上游面接触来实现，该混合基质膜包含其中结合有固体颗粒吸附剂的有机聚合物，有机聚合物的渗透系数与吸附剂的渗透系数相适应。 从膜的下游面发出的渗透物包括流体产物混合物，其中相对于第二流体组分具有更大的稳态渗透性的进料混合物的第一流体组分的比例大于比例 存在于原始流体进料混合物中。
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公开(公告)号：US4455444A
公开(公告)日：1984-06-19
申请号：US441142
申请日：1982-11-12
CPC分类号： C10G25/003 , C07C7/13
摘要： A process for separating a normal paraffin hydrocarbon from a mixture of the same with a cyclic and/or branched chain paraffin hydrocarbon. The process comprises contacting the mixture at a temperature of from about 120.degree. C. to about 140.degree. C. with a zeolite free molecular sieve comprising silicalite. The normal paraffin hydrocarbon is selectively retained and will preferably be recovered from the molecular sieve by displacement with a displacement material.
摘要翻译： 将正链烷烃与其与环烷烃和/或支链链烷烃烃的混合物分离的方法。 该方法包括使混合物在约120℃至约140℃的温度下与不含沸石的分子筛包含硅沸石接触。 正常的链烷烃被选择性地保留，并且优选通过用置换材料置换从分子筛中回收。
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