摘要:
Processes and apparatuses for producing a C8 aromatic isomer product are provided. The process comprises introducing a reformate stream comprising aromatic hydrocarbons to a reformate splitter column to provide a plurality of streams. One or more streams comprising at least one stream from the plurality of streams is passed to a reformate upgrading unit to obtain an upgraded reformate stream. The upgraded reformate stream is passed to an aromatics stripper column to provide an aromatics stripper sidedraw stream comprising C8 aromatic hydrocarbons. The aromatics stripper sidedraw stream is passed to a xylene separation unit to provide the C8 aromatic isomer product and a raffinate product stream. At least a portion of the raffinate product stream is processed in a liquid phase isomerization unit to obtain an isomerized stream.
摘要:
Disclosed herein is a process for catalytically reforming naphtha, comprising, in the presence of hydrogen gas, contacting naphtha with at least one reforming catalyst under the conditions of a pressure ranging from 0.15 to 3.0 MPa, a temperature ranging from 300 to 540° C., a volume space velocity ranging from 2.1 to 50 h−1, to carry out a shallow catalytic reforming reaction so as to achieve a naphthene conversion ratio of greater than 85 mass %, and a conversion ratio of paraffins to arenes and C4− hydrocarbons of less than 30 mass %.
摘要:
Disclosed herein is a method of simultaneously removing sulfur and mercury from a hydrocarbon material, including: hydrotreating the hydrocarbon material containing sulfur and mercury in the presence of a catalyst including a metal supported with a carrier to convert sulfur into hydrogen sulfide, and adsorb mercury on a metal active site or a carrier of the catalyst in the form of mercury sulfide.
摘要:
A novel catalytic absorbent composition is prepared with a synthetic copper or silver carbonate-containing material. The absorbent is useful for removing hydrogen sulfide and mercaptan sulfur from hydrocarbon oils, especially from feedstreams to a reformer.
摘要:
A reforming process is disclosed which comprises contacting a sulfur-containing hydrocarbon material in at least one liquid phase scavenging or sulfur removal zone with at least one manganese-containing composition at conditions to remove at least a portion of said sulfur from said hydrocarbon material to produce a hydrocarbon feedstock having a reduced concentration of sulfur; and contacting said hydrocarbon feedstock with a catalyst comprising a minor catalytically effective amount of at least one platinum-group metal component, optionally, a major amount of a porous solid support, optionally, a minor catalytically effective amount of at least one halogen component, and optionally, at least one rhenium component in the presence of hydrogen at hydrocarbon reforming conditions to obtain a hydrocarbon reformate product.
摘要:
An improved aromatics extraction process is disclosed. Key feature of the present invention is use of the fractionator in the hydrodealkylation unit or other unit with a benzene fraction to fractionate not only hydrodealkylated benzene but also extracted benzene. The extracted benzene is used as "pseudo" reflux in the hydrodealkylation unit fractionator, thereby reducing the reflux requirement. The conventional re-run fractionator for clay treated benzene extract is eliminated, since polymerized olefins in this extract are removed as a bottoms fraction from the hydrodealkylation fractionator.
摘要:
A PROCESS FOR UPGRADING WIDE RANGE GASOLINE STOCKS IS DISCLOSED WHEREIN THE FEED IS SEPARATED INTO C5, C6-C8 AND C9+ FRACTIONS, THE C6-C8 AND C9+ FRACTIONS ARE SEPARATELY REFORMED, REFORMATE FROM THE C9+ FRACTION IS DISTILLED TO REMOVE C5-C8 MATERIAL AND YIELD A HEAVY AROMATIC PRODUCT OF HIGH ANTIKNOCK VALUE, SAID C5-C8 MATERIAL IS COMBINED WITH REFORMATE FROM SAID C6-C8 FRACTION AND WITH AROMATIC DEHYDROCYCLIZATE FROM A SUBSEQUENT STEP, THE RESULTING MIXTURE IS EXTRACTED WITH AN AROMATIC-SELECTIVE SOLVENT TO YIELD A RAFFINATE AND C6-C8 AROMATIC PRODUCT OF HIGH PURITY AND ANTIKNOCK VALUE, THE RAFFINATE IS DISTILLED TO OBTAIN A C5-C6 PARAFFINIC FRACTION AND A HEAVY PARAFFINIC FRACTION, THE LATTER IS CATALYTICALLY DEHYDROCYCLIZED TO YIELD SAID AROMATIC DEHYDROCYCLIZATE, THE C5-C6 PARAFFINIC FRACTION IS COMBINED WITH SAID C5 FRACTION AND THE MIXTURE IS CATALYTICALLY ISOMERIZED.
摘要:
A PROCESS FOR PRODUCING GASOLINE FROM A HEXANE-RICH HYDROCARBON FEED WHICH COMPRISES AVERAGING HEXANE WITH ONE OR MORE ALKANES SELECTED FROM THE GROUP CONSISTING OF PROPANE OR BUTANES OR C10+HYDROCARBONS OR MIXTURES OF THE FOREGOING HYDROCARBONS TO OBTAIN AT LEAST C7+HYDROCARBONS, AND CATALYTICALLY REFORMING THE C7+HYDROCARBONS TO OBTAIN REFORMATE. PREFERABLY AT LEAST A PORTION OF THE HYDROCARBONS AVERAGED WITH THE HEXANE IS RAFFINATE DERIVED FROM EXTRACTION FOLLOWING THE CATALYTIC REFORMING STEP. PREFERABLY, A PORTION OF THE N-PENTANE PRODUCED IN HEXANE AVERAGING IS ISOMERIZED TO ISOPENTANE.
摘要:
A HIGH OCTANE, UNLEADED GASOLINE POOL IS PRODUCED VIA AN INTEGRATED REFINERY OPERTION. THE INDIVIDUAL PROCESSES INTEGRATED IN COMBINATION WITH EACH OTHER RE HYDROCRACKING, LOW SEVERITY CATALYTIC REFORMING, SATURATE CRACKING AND ALKYLATION. CATALYTIC REFORMING IS EFFECTED AT LOW SEVERITY CONDITIONS TO MAXIMIZE THE REACTION OF NAPHTHENE DEHYDROGENATION TO PRODUCE AROMATICS WHICH SIMULTANEOUSLY INHIBITING HE DEHYDROCYCLIZATION AND CRACKING OF PARAFFINIC HYDROCARBONS.
摘要:
A process for improved production of aromatics-rich naphtha from crude oils: crude oil is fractionated to produce a virgin naphtha, gas oil is combined with paraffinic raffinate and cracked, and bottoms which is combined with fractionator cycle oil and cracked. Products of cracking are combined and fractionated into cracked naphtha, cycle oil, and decant oil. The naphtha cuts are combined, hydrodesulfurized, reformed, and separated into paraffinic raffinate and the aromatics-rich extract naphtha as product.