摘要:
In a hydrogen absorbing alloy electrode containing hydrogen absorbing alloy powder and a binding agent, employed as the binding agent is a copolymer of aromatic vinyl and at least one of acrylic ester and methacrylic acid ester, in which the total content of acrylic ester units and methacrylic acid ester units is in the range of 43 to 90% by weight of the whole copolymer, and the hydrogen absorbing alloy electrode is used as a negative electrode of a nickel-metal hydride battery.
摘要:
A nonaqueous electrolyte secondary cell having a rolled-up electrode unit housed in a cell can and comprising a positive electrode and a negative electrode each formed by coating a surface of a striplike current collector with an electrode material. According to a first embodiment, the current collector of at least one of the positive electrode and the negative electrode comprises a plurality of current collector pieces 42 arranged along one direction and a PTC element 5 interconnecting each pair of adjacent current collector pieces 42. Alternatively with a second embodiment, at least one of the positive electrode and the negative electrode comprises a PTC element held between opposed faces of an uncoated portion of the current collector thereof and a base end portion of a current collector tab. The PTC element serves to prevent continuous occurrence of a current in excess of a predetermined value and realizes a high energy density.
摘要:
A lithium secondary battery of this invention includes a positive electrode using, as an active material, a lithium-containing manganese composite oxide with a spinel structure having a composition, during charge and discharge, represented by a formula, LixMn2-y-zNiyMzO4, in which M is at least one element selected from the group consisting of Fe, Co, Ti, V, Mg, Zn, Ga, Nb, Mo and Cu; 0.02≦×≦1.10, whereas x changes in accordance with occlusion and discharge of lithium ions during charge and discharge; 0.25≦y≦0.60; and 0
摘要翻译:本发明的锂二次电池包括使用具有由式LixMn2-y-zNiyMzO4表示的充电和放电组成的尖晶石结构的含锂锰复合氧化物作为活性材料的正极, 其中M为选自Fe,Co,Ti,V,Mg,Zn,Ga,Nb,Mo和Cu中的至少一种元素; 0.02 <= x <= 1.10,而x在充放电期间根据锂离子的闭塞和放电而改变; 0.25 <= y <= 0.60; 0
摘要:
A nonaqueous electrolyte battery having improved storage stability is disclosed. The battery includes a positive electrode; s negative electrode in which the active material is lithium or a compound capable of absorbing and desorbing lithium; and a nonaqueous electrolyte containing an organic solvent, at least 10 wt % of which is dioxolane, a solute and a storage stabilizing additive which is an oxygen acid ester, isoxazole, oxazole or oxazoline or a derivative thereof. The additive reduces the self-discharge rate of the battery during storage.
摘要:
A polyelectrolytic battery wherein a porous film having a polyelectrolyte impregnated into its cavities is interposed between a positive electrode and a negative electrode, the porous film having a porosity of not less than 80% and the polyelectrolyte impregnated therein at a ratio of 20 to 90% by volume of the cavities thereof. Another polyelectrolytic battery includes a positive electrode, a negative electrode including a carbon material, and a polyelectrolytic film interposed between the positive and negative electrodes, the positive and negative electrodes each containing a polyelectrolyte composed of a high polymer having a polystyrene main chain and a side chain of polyethlene oxide and a lithium salt.
摘要:
A non-aqueous electrolyte battery according to the invention includes a positive electrode using a lithium-metal compound oxide as a positive electrode material, a negative electrode and a non-aqueous electrolyte solution, the battery employing a positive electrode material composed of the lithium-metal compound oxide which contains at least Ni, Co and Mn, and has a peak with a full width at half maximum of not greater than 0.22.degree. in a range of 2.theta.=18.71.+-.0.25.degree. as measured by the powder X-ray diffraction analysis using a Cu-K.alpha. X-ray source or employing a positive electrode material composed of a lithium-metal compound oxide which contains at least Ni, Co and Mn, and a non-aqueous electrolyte solution which includes a solvent containing ethylene carbonate and a solute containing at least one type of fluorine-containing compound.
摘要:
Disclosed is a nonaqueous electrolyte secondary battery including a negative electrode prepared by coating a substrate with a slurry comprising a carbon material, an alkali metal salt of carboxymethylcellulose, and a styrene-butadiene rubber and drying it, the alkali metal salt accounting for 0.5.about.2 weight % of the total weight of the carbon material, styrene-butadiene rubber, and CMC alkali metal salt. Because of the higher electrical conductivity of the CMC alkali metal salt used as the thickening agent than the conventional carboxymethylcellulose or its ammonium salt, the secondary battery of the invention including the above negative electrode has an excellent load characteristic.
摘要:
The present invention aims to provide the following non-aqueous electrolyte secondary cell having excellent safety. A non-aqueous electrolyte secondary cell comprises an electrode assembly having positive and negative electrodes. The positive electrode has a core exposed portion (formed by exposing at least one side edge of a belt-shaped core along the longitudinal direction of the core), a active material layer formed on the core, and a protective layer (formed on the core exposed portion near the active material layer and having a lower conductivity than the core). The negative electrode has first and second negative electrode core exposed portions, in which both side edges of a belt-shaped negative electrode core are exposed along the longitudinal direction of the core, and a negative electrode active material layer formed on the negative electrode core. And the whole of the second negative electrode core exposed portion is opposite to the protective layer.
摘要:
The present invention aims to productively provide a non-aqueous electrolyte secondary cell having high capacity. This object can be achieved by adopting the following configuration. A non-aqueous electrolyte secondary cell comprises a non-aqueous electrolyte and an electrode assembly having a positive electrode, a negative electrode and a separator; the positive electrode has a positive electrode core and a positive electrode active material layer; the negative electrode has a negative electrode core and a negative electrode active material layer; a protective layer is provided on the positive electrode active material layer and/or the negative electrode active material layer; the total thickness of the protective layers is 10 to 40% of that of the separator; a porosity of the protective layer is larger than that of any of the positive and negative electrode active material layer; and the non-aqueous electrolyte contains a non-aqueous solvent and two or more kinds of lithium compounds.