摘要:
Provided is a nonaqueous battery having an active material of a positive electrode formed from a composite powder consisting of Li.sub.1-x Mn.sub.2 O.sub.4 (0.ltoreq.X.ltoreq.1) and Li.sub.2 MnO.sub.3. Because the active material has the form of a composite, this battery allows little of the manganese to dissolve out during charge and hence has excellent charge-discharge characteristics.
摘要:
In a non-aqueous electrolyte secondary battery provided with a positive electrode 1, a negative electrode 2, and a non-aqueous electrolyte solution, a lithium-containing composite nickel oxide is used as a chief component of the positive electrode material for the positive electrode, a lithium-containing titanium oxide is used as a chief component of the negative electrode material for the negative electrode, and the solvent of the non-aqueous electrolyte solution contains a cyclic carbonic ester and a chain carbonic ester in such a manner that the cyclic carbonic ester and chain carbonic ester are contained in amounts of not less than 10% by volume of the whole solvent, respectively, and the total content of the cyclic carbonic ester and the chain carbonic ester is not less than 60% by volume of the whole solvent.
摘要:
The opening to be sealed in a battery is sealed with an electrical insulating sealant S by placing an electrical insulating sealing material C, including a first sealing material A that is soften by heat applied for sealing and a second sealing material B that is more difficult to soften by the heat applied for sealing than the first sealing material A, and by heating and successively cooling the electrical insulating sealing material C. The second sealing material B is in the form of a mesh. Thus, a sealed battery with few defectives such as a sealing failure and a short-circuit can be manufactured in a high yield rate.
摘要:
The present invention provides a lithium secondary battery using, as a lithium ion occluding agent for a negative electrode, a substantially amorphous oxide powder in which a product V·d of a total volume V in cm3/g of pores with a diameter of 100 nm or less and a true density d in g/cm3 measured by a helium displacement method is 0.1 through 0.5. Thus, the lithium secondary battery can attain an excellent charge-discharge cycle characteristic.
摘要翻译:本发明提供一种锂二次电池,其使用作为负极的锂离子吸留剂的基本上无定形的氧化物粉末,其中总体积V的产物Vd为cm3 / g,直径为100nm以下的孔 并且通过氦置换法测量的以g / cm 3表示的真密度d为0.1至0.5。 因此,锂二次电池可以获得良好的充放电循环特性。
摘要:
A nonaqueous electrolyte secondary cell having a rolled-up electrode unit housed in a cell can and comprising a positive electrode and a negative electrode each formed by coating a surface of a striplike current collector with an electrode material. According to a first embodiment, the current collector of at least one of the positive electrode and the negative electrode comprises a plurality of current collector pieces 42 arranged along one direction and a PTC element 5 interconnecting each pair of adjacent current collector pieces 42. Alternatively with a second embodiment, at least one of the positive electrode and the negative electrode comprises a PTC element held between opposed faces of an uncoated portion of the current collector thereof and a base end portion of a current collector tab. The PTC element serves to prevent continuous occurrence of a current in excess of a predetermined value and realizes a high energy density.
摘要:
A lithium secondary battery of this invention includes a positive electrode using, as an active material, a lithium-containing manganese composite oxide with a spinel structure having a composition, during charge and discharge, represented by a formula, LixMn2-y-zNiyMzO4, in which M is at least one element selected from the group consisting of Fe, Co, Ti, V, Mg, Zn, Ga, Nb, Mo and Cu; 0.02≦×≦1.10, whereas x changes in accordance with occlusion and discharge of lithium ions during charge and discharge; 0.25≦y≦0.60; and 0
摘要翻译:本发明的锂二次电池包括使用具有由式LixMn2-y-zNiyMzO4表示的充电和放电组成的尖晶石结构的含锂锰复合氧化物作为活性材料的正极, 其中M为选自Fe,Co,Ti,V,Mg,Zn,Ga,Nb,Mo和Cu中的至少一种元素; 0.02 <= x <= 1.10,而x在充放电期间根据锂离子的闭塞和放电而改变; 0.25 <= y <= 0.60; 0
摘要:
A nonaqueous electrolyte battery having improved storage stability is disclosed. The battery includes a positive electrode; s negative electrode in which the active material is lithium or a compound capable of absorbing and desorbing lithium; and a nonaqueous electrolyte containing an organic solvent, at least 10 wt % of which is dioxolane, a solute and a storage stabilizing additive which is an oxygen acid ester, isoxazole, oxazole or oxazoline or a derivative thereof. The additive reduces the self-discharge rate of the battery during storage.
摘要:
A polyelectrolytic battery wherein a porous film having a polyelectrolyte impregnated into its cavities is interposed between a positive electrode and a negative electrode, the porous film having a porosity of not less than 80% and the polyelectrolyte impregnated therein at a ratio of 20 to 90% by volume of the cavities thereof. Another polyelectrolytic battery includes a positive electrode, a negative electrode including a carbon material, and a polyelectrolytic film interposed between the positive and negative electrodes, the positive and negative electrodes each containing a polyelectrolyte composed of a high polymer having a polystyrene main chain and a side chain of polyethlene oxide and a lithium salt.
摘要:
A non-aqueous electrolyte battery according to the invention includes a positive electrode using a lithium-metal compound oxide as a positive electrode material, a negative electrode and a non-aqueous electrolyte solution, the battery employing a positive electrode material composed of the lithium-metal compound oxide which contains at least Ni, Co and Mn, and has a peak with a full width at half maximum of not greater than 0.22.degree. in a range of 2.theta.=18.71.+-.0.25.degree. as measured by the powder X-ray diffraction analysis using a Cu-K.alpha. X-ray source or employing a positive electrode material composed of a lithium-metal compound oxide which contains at least Ni, Co and Mn, and a non-aqueous electrolyte solution which includes a solvent containing ethylene carbonate and a solute containing at least one type of fluorine-containing compound.