Enzymatic synthesis of sugar acrylates
    93.
    发明授权
    Enzymatic synthesis of sugar acrylates 有权
    糖丙糖酸酯的酶合成

    公开(公告)号:US07767425B2

    公开(公告)日:2010-08-03

    申请号:US10495580

    申请日:2002-11-15

    IPC分类号: C12P19/02

    CPC分类号: C07H13/04

    摘要: A process is described for the enzymatic synthesis of sugar acrylates, and a process is described for preparing polymeric sugar acrylates, the polymers obtainable by this process and their use for preparing, for example, cosmetics, drugs, laundry detergents, thickeners, protecting colloids, superabsorbents and textile sizes.

    摘要翻译: 描述了用于糖类丙烯酸酯的酶促合成的方法,并且描述了制备聚合糖丙烯酸酯的方法,可通过该方法获得的聚合物及其用于制备例如化妆品,药​​物,衣物洗涤剂,增稠剂,保护胶体, 超吸收剂和纺织品尺寸。

    Process for preparing 1,4-butanediol
    95.
    发明授权
    Process for preparing 1,4-butanediol 有权
    制备1,4-丁二醇的方法

    公开(公告)号:US07759531B2

    公开(公告)日:2010-07-20

    申请号:US12527139

    申请日:2007-03-14

    IPC分类号: C07C29/17

    摘要: The present invention provides an integrated process for continuously preparing 1,4-butanediol, which comprises the following stages: (I) reacting formaldehyde with acetylene in the presence of a copper catalyst at a pH of from 5 to 8 and a molar ratio of formaldehyde to acetylene of at most 2:1, (II) intermediately buffering the resulting butynediol-containing aqueous mixture for from 0.1 to 100 h, (III) hydrogenating the mixture obtained after the intermediate buffering and (IV) distilling the hydrogenation product obtained in stage III to obtain 1,4-butanediol.

    摘要翻译: 本发明提供连续制备1,4-丁二醇的一体化方法,其包括以下步骤:(I)在铜催化剂存在下,在5至8的pH下与甲醛与乙炔反应,并且甲醛的摩尔比 至最多2:1的乙炔,(II)将所得的含丁炔二醇的含水混合物中间缓冲0.1至100小时,(III)将中间缓冲后获得的混合物氢化,并且(IV)蒸馏阶段中获得的氢化产物 III得到1,4-丁二醇。

    Method for converting perylen-3,4:9,10-tetracarboxylic acid diimides into a form suitable for use as a fluorescent dye
    96.
    发明授权
    Method for converting perylen-3,4:9,10-tetracarboxylic acid diimides into a form suitable for use as a fluorescent dye 有权
    将苝-3,4:9,10-四羧酸二酰亚胺转化为适合用作荧光染料的形式的方法

    公开(公告)号:US07753967B2

    公开(公告)日:2010-07-13

    申请号:US10514564

    申请日:2003-06-06

    IPC分类号: C09B3/14 C07B63/00

    CPC分类号: C09B67/0014 C09B67/0025

    摘要: Novel crystalline forms of and a process for converting perylene-3,4:9,10-tetracarboximide of the general formula I to a form used as a fluorescent dye. The process including: a) dissolving or suspending the perylene-3,4:9,10-tetracarboximide in a solvent to obtain a solution or suspension; and b1) cooling the solution obtained in step a) to a temperature at or below the crystallization temperature of the perylene-3,4:9,10-tetracarboximide and, if the solvent is organic, removing excess solvent until the first crystals form, otherwise, adding water or dilute aqueous solutions of the solvent until the first crystals form, and maintaining the solution at that temperature for further crystallization; or b2) cooling the suspension obtained in step a) to or below the crystallization temperature when the temperature in step a) was above the crystallization temperature, and maintaining the suspension at the temperature for further crystallization to form one or more solvate crystals.

    摘要翻译: 将通式I的苝-3,4:9,10-四甲酰亚胺转化为用作荧光染料的形式的新型晶型和方法。 该方法包括:a)将苝-3,4:9,10-四甲酰亚胺溶解或悬浮在溶剂中以获得溶液或悬浮液; 和b1)将步骤a)中获得的溶液冷却至等于或低于苝-3,4:9,10-四甲酰亚胺的结晶温度的温度,如果溶剂是有机的,则除去多余的溶剂直到形成第一晶体, 否则,加入水或稀释的溶剂水溶液直到形成第一晶体,并将溶液保持在该温度下进一步结晶; 或b2)当步骤a)中的温度高于结晶温度时,将步骤a)中获得的悬浮液冷却至或低于结晶温度,并将悬浮液保持在该温度下进一步结晶以形成一种或多种溶剂化物晶体。

    Polymers based on fluoranthene and their use
    98.
    发明授权
    Polymers based on fluoranthene and their use 有权
    基于荧蒽的聚合物及其用途

    公开(公告)号:US07737236B2

    公开(公告)日:2010-06-15

    申请号:US11077199

    申请日:2005-03-11

    摘要: Polymers comprising repeating units of the formula I where the variables are defined as follows: a is an integer from 0 to 3, R1, R2, R3 are identical or different and are selected independently from among hydrogen, C1-C20-alkyl, C1-C20-alkyl containing one or more Si, N, P, O or S atoms, C6-C30-aryl, preferably C6-C14-aryl, C4-C14-heteroaryl, —N(C6-C14-aryl)2, and Y1, where Y1 may be identical or different and are selected from among —CH═CH2, trans- or cis-CH═CH—C6H5, acryloyl, methacryloyl, methylstyryl, O—CH═CH2 and glycidyl, where Y2 is selected from among —CH═CH2, trans- or cis-CH═CH—C6H5, acryloyl, methacryloyl, methylstyryl, —O—CH═CH2 and glycidyl, and one or more groups Y1 or Y2 may be crosslinked to one another.

    摘要翻译: 包含式I重复单元的聚合物,其中变量定义如下:a是0-3的整数,R1,R2,R3相同或不同,独立地选自氢,C1-C20烷基,C1- 含有一个或多个Si,N,P,O或S原子的C 20 - 烷基,C 6 -C 30 - 芳基,优选C 6 -C 14 - 芳基,C 4 -C 14 - 杂芳基,-N(C 6 -C 14 - 芳基)2和Y 1 其中Y 1可以相同或不同,并且选自-CH 2 CH 2,反式或顺式-CH = CH-C 6 H 5,丙烯酰基,甲基丙烯酰基,甲基苯乙烯基,O-CH = CH 2和缩水甘油基,其中Y 2选自 - CH 2 CH 2,反式或顺式-CH = CH-C 6 H 5,丙烯酰基,甲基丙烯酰基,甲基苯乙烯基,-O-CH = CH 2和缩水甘油基,以及一个或多个Y 1或Y 2基团可彼此交联。

    Water-absorbent crosslinked polymers
    99.
    发明授权
    Water-absorbent crosslinked polymers 失效
    吸水交联聚合物

    公开(公告)号:US07732528B2

    公开(公告)日:2010-06-08

    申请号:US11815791

    申请日:2006-03-03

    CPC分类号: C08F220/06

    摘要: Water-absorbent crosslinked polymers bearing acid groups, some or all of the acid groups being present as carboxylate groups having at least two different types of cations as counterions, processes for their preparation and mixtures of water-absorbent crosslinked polymers.

    摘要翻译: 含酸基团的吸水性交联聚合物,部分或全部酸基团以羧酸盐基团存在,其具有至少两种不同类型的阳离子作为抗衡离子,其制备方法和吸水交联聚合物的混合物。