公开(公告)号：US4256566A

公开(公告)日：1981-03-17

申请号：US68278

申请日：1979-08-20

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/656 ,  C10G35/09 ,  C10G35/08

CPC分类号： B01J23/6567 ,  C10G35/09 ,  C07C2521/04 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/656 ,  C07C2527/126

摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a novel attenuated superactive multimetallic catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonylcomponent with a porous carrier material containing a uniform dispersion of a catalytically effective amount of a platinum group component, which is maintained in the elemental metallic state during the incorporation and pyrolysis of the rhenium carbonyl component, and of a tin component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, tin component and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, about 0.005 to about 5 wt. % tin and about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of a tin component and of a platinum group component maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligands associated with the rhenium reagent. A specific example of the type of hydrocarbon conversion process disclosed herein is a process for the catalytic reforming of a low octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the attenuated superactive multimetallic catalytic composite at reforming conditions.

摘要翻译： 碳氢化合物通过在烃转化条件下与它们接触来转化，所述新型减毒超活性多金属催化复合材料包含催化有效量的热解铼羰基组分与含有催化有效量的铂族组分的均匀分散体的多孔载体材料的组合 ，其在羰基铼组分和锡组分的引入和热解过程中保持在元素金属状态。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 铂族组分，热解的铼羰基组分，锡组分和任选的卤素组分优选以基于元素计算的量存在于多金属催化复合物中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％铼，约0.005至约5wt。 ％锡和约0.1至约3.5重量％ ％卤素。 与本发明的催化复合材料的制备相关的主要特征是羰基钌合物与含有均匀分散的锡组分和保持在元素状态的铂族组分的多孔载体材料的反应，由此铼的相互作用 与铂族部分的部分由于与铼试剂相关的一氧化碳配体的铂嗜性（即铂寻求）倾向而最大化。 本文公开的烃转化方法的具体实例是低辛烷值汽油馏分的催化重整方法，其中汽油馏分和氢气流在重整条件下与减弱的超活性多金属催化复合材料接触。

公开(公告)号：US4246095A

公开(公告)日：1981-01-20

申请号：US45024

申请日：1979-06-04

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： C10G35/09 ,  C10G35/08

CPC分类号： C10G35/09

摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a novel sulfided superactive multimetallic catalytic composite comprising a sulfided combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component, which is maintained in the elemental metallic state during the incorporation and pyrolysis of the rhenium carbonyl component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, sulfur component, and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, 0.001 to about 0.2 wt. % sulfur, and about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of a platinum group component maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligands used in the rhenium reagent. A specific example of the type of hydrocarbon conversion process disclosed herein is a process for the catalytic reforming of a low octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the subject sulfided superactive multimetallic catalytic composite at reforming conditions.

摘要翻译： 碳氢化合物通过在烃转化条件下与新型硫化超活性多金属催化复合材料接触而转化，所述催化复合材料包含催化有效量的热解铼羰基组分的硫化组合和多孔载体材料，所述多孔载体材料含有催化有效量的铂组分 组分，其在羰基铼组分的引入和热解期间保持在元素金属状态。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 铂组分，热解的铼羰基组分，硫组分和任选的卤素组分优选以基于元素计算的量存在于多金属催化复合物中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％铼，0.001至约0.2wt。 ％硫和约0.1至约3.5wt。 ％卤素。 与本发明催化复合材料的制备相关的主要特征是羰基铑合金与保持元素状态的铂族组分的均匀分散体的多孔载体材料的反应，由此铼部分与铂族的相互作用 部分由于铼试剂中使用的一氧化碳配体的铂嗜性（即铂寻求）倾向而最大化。 本文公开的烃转化方法的具体实例是低辛烷值汽油馏分的催化重整方法，其中汽油馏分和氢气流在重整条件下与目标硫化超活性多金属催化复合物接触。

公开(公告)号：US4238363A

公开(公告)日：1980-12-09

申请号：US48958

申请日：1979-06-15

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J27/08 ,  C10G35/09 ,  B01J27/04

CPC分类号： C10G35/09 ,  B01J27/08

摘要： A sulfided and attenuated superactive multimetallic catalytic composite especially useful for the conversion of hydrocarbons comprises a sulfided combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component, which is maintained in the elemental metallic state during the incorporation and pyrolysis of the rhenium carbonyl component, and of a zinc component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, zinc component, sulfur component, and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, about 0.01 to about 5 wt. % zinc, 0.001 to about 0.2 wt. % sulfur, and about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of a zinc component and of a plantinum group metal maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligand used in the rhenium reagent.

摘要翻译： 特别可用于烃转化的硫化和减弱的超活性多金属催化复合物包括催化有效量的热解铼羰基组分与含有催化有效量的铂族组分的均匀分散体的多孔载体材料的硫化组合，其中 在羰基铼组分和锌组分的引入和热解过程中保持元素金属状态。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 铂族组分，热解的铼羰基组分，锌组分，硫组分和任选的卤素组分优选以基于元素计算的量存在于多金属催化复合材料中，对应于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％铼，约0.01至约5wt。 ％锌，0.001至约0.2wt。 ％硫和约0.1至约3.5wt。 ％卤素。 与制备本发明的催化复合材料相关的主要特征是羰基钌合物与含有均匀分散的锌组分和保持在元素状态的植物组合金属的多孔载体材料的反应，由此铼的相互作用 由于在铼试剂中使用的一氧化碳配体的铂嗜性（即铂寻求）倾向，铂基团部分被最大化。

公开(公告)号：US4235705A

公开(公告)日：1980-11-25

申请号：US970049

申请日：1978-12-15

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/644 ,  B01J23/656 ,  C10G35/09 ,  C10G35/08

CPC分类号： B01J23/6567 ,  C10G35/09 ,  B01J23/6447

摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a novel attenuated superactive multimetallic catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of a catalytically effective amount of a platinum group component, which is maintained in the elemental metallic state during the incorporation of the rhenium carbonyl component, and of a bismuth component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, bismuth component and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, about 0.01 to about 5% bismuth and about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of a bismuth component and of a platinum group metal maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligands associated with the rhenium reagent. A specific example of the type of hydrocarbon conversion process disclosed herein is a process for the catalytic reforming of a low octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the subject attenuated superactive multimetallic catalytic composite at reforming conditions.

摘要翻译： 通过在碳氢化合物转化条件下使它们与新型减弱的超活性多金属催化复合材料接触来转化碳氢化合物，该催化复合材料包含催化有效量的热解的铼羰基组分与含有催化有效量的铂的均匀分散体的多孔载体材料的组合 组分，其在并入铼羰基组分期间保持在元素金属状态和铋组分。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 铂族组分，热解铼羰基组分，铋组分和任选的卤素组分优选以基于元素计算的量存在于多金属催化复合物中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％铼，约0.01至约5％的铋和约0.1至约3.5wt。 ％卤素。 与本发明催化复合材料的制备相关联的关键特征是羰基钌合物与含有均匀分散的铋组分和维持在元素态的铂族金属的多孔载体材料的反应，由此铼的相互作用 与铂族部分的部分由于与铼试剂相关的一氧化碳配体的铂嗜性（即铂寻求）倾向而最大化。 本文公开的烃转化方法的具体实例是低辛烷值汽油馏分的催化重整的方法，其中汽油馏分和氢气流在重整条件下与主体减弱的超多活性多金属催化复合材料接触。

公开(公告)号：US4231897A

公开(公告)日：1980-11-04

申请号：US36120

申请日：1979-05-04

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/656 ,  C10G35/09 ,  B01J27/08 ,  B01J23/36 ,  B01J27/10

CPC分类号： C10G35/09 ,  B01J23/6567

摘要： A novel attenuated superactive multimetallic catalytic composite especially useful for converting hydrocarbons comprises a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of catalytically effective amounts of a platinum group component, which is maintained in the elemental metallic state during the incorporation of the rhenium carbonyl component, and of a cadmium component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, cadmium component and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, about 0.01 to about 5 wt. % cadmium and about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of a cadmium component and of a platinum group metal maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligands associated with the rhenium reagent.

摘要翻译： 特别适用于转化烃类的新型减毒超活性多金属催化复合物包括催化有效量的热解铼羰基组分与含有催化有效量的铂族组分的均匀分散体的多孔载体材料的组合，其保持在 在引入羰基铼组分期间的元素金属状态和镉组分。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 铂族组分，热解的铼羰基组分，镉组分和任选的卤素组分优选以基于元素计算的量存在于多金属催化复合物中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％铼，约0.01至约5wt。 ％镉和约0.1至约3.5wt。 ％卤素。 与本发明催化复合材料的制备相关的主要特征是羰基铑合金与含有均匀分散的镉组分和保持在元素状态的铂族金属的多孔载体材料的反应，由此铼的相互作用 与铂族部分的部分由于与铼试剂相关的一氧化碳配体的铂嗜性（即铂寻求）倾向而最大化。

公开(公告)号：US4212727A

公开(公告)日：1980-07-15

申请号：US850

申请日：1979-01-02

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： C10G35/09 ,  C10G47/18 ,  C07C9/12 ,  B01J29/12 ,  C10G13/10 ,  C10G35/06

CPC分类号： C10G35/09 ,  C10G2400/02 ,  Y10S208/02

摘要： A process for the simultaneous production of high octane motor fuel and isobutane. The process is effected with a physical mixture of compatible reforming catalyst and hydrocracking catalyst.

摘要翻译： 同时生产高辛烷值汽油和异丁烷的方法。 该方法用相容的重整催化剂和加氢裂化催化剂的物理混合物进行。

公开(公告)号：US4210523A

公开(公告)日：1980-07-01

申请号：US13491

申请日：1979-02-21

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/656 ,  C10G35/09 ,  C10G35/08

CPC分类号： C10G35/09 ,  B01J23/6567

摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a novel superactive multimetallic catalytic composite comprising a reduced combination of a catalytically effective amount of an adsorbed rhenium-oxygen complex with a porous carrier material containing a catalytically effective amount of a conventional rhenium component and a uniform dispersion of a catalytically effective amount of a platinum group component which is maintained in the elemental metallic state during the adsorption and reduction of the rhenium-oxygen complex. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium-oxygen complex with a porous carrier material containing a conventional rhenium component and a uniform dispersion of a platinum group component maintained in the elemental state, whereby the interaction of the rhenium-oxygen complex with the platinum group metal moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the oxygen ligands used in the rhenium reagent. A specific example of the type of hydrocarbon conversion process disclosed herein is a process for the catalytic reforming of a low octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the subject superactive multimetallic catalytic composite at reforming conditions.

摘要翻译： 碳氢化合物通过在烃转化条件下与新型超多活性多金属催化复合物接触而转化，所述催化复合材料包含催化有效量的吸附的铼 - 氧络合物与含有催化有效量的常规铼组分的多孔载体材料的组合和 催化有效量的铂族组分的均匀分散，其在铼 - 氧络合物的吸附和还原期间保持在元素金属状态。 与本发明催化复合材料的制备相关的关键特征是铼 - 氧络合物与含有常规铼组分的多孔载体材料和维持在元素状态的铂族组分的均匀分散体的反应，由此， 与铂族金属部分的铼 - 氧络合物由于铼试剂中使用的氧配体的铂（即铂寻求）倾向而最大化。 本文公开的烃转化方法的具体实例是低辛烷值汽油馏分的催化重整方法，其中汽油馏分和氢气流在重整条件下与目标超活性多金属催化复合物接触。

公开(公告)号：US4206040A

公开(公告)日：1980-06-03

申请号：US954684

申请日：1978-10-25

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/656 ,  C10G35/09 ,  C10G35/08

CPC分类号： B01J23/6567 ,  C10G35/09

摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a novel attenuated superactive multimetallic catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of a catalytically effective amount of a platinum group component, which is maintained in the elemental metallic state, and of a silver component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. A specific example of the type of hydrocarbon conversion process disclosed herein is a process for the catalytic reforming of a low octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with this attenuated superactive multimetallic catalytic composite at reforming conditions.

摘要翻译： 通过在碳氢化合物转化条件下使它们与新型减弱的超活性多金属催化复合材料接触来转化碳氢化合物，该催化复合材料包含催化有效量的热解的铼羰基组分与含有催化有效量的铂的均匀分散体的多孔载体材料的组合 保持在元素金属状态的组分和银组分。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 本文公开的烃转化方法的具体实例是用于催化重整低辛烷值汽油馏分的方法，其中汽油馏分和氢气流在重整条件下与该减弱的超活性多金属催化复合材料接触。

公开(公告)号：US4193863A

公开(公告)日：1980-03-18

申请号：US947906

申请日：1978-10-02

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/656 ,  C10G35/09 ,  C10G35/08

CPC分类号： C10G35/09 ,  B01J23/6567

摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a novel attenuated superactive multimetallic catalytic composite comprising a combination of a catalytically effective amount of a pyrolyzed rhenium carbonyl component with a porous carrier material containing a uniform dispersion of a catalytically effective amount of a platinum group component, which is maintained in the elemental metallic state, and of a cadmium component. In a highly preferred embodiment, this novel catalytic composite also contains a catalytically effective amount of a halogen component. The platinum group component, pyrolyzed rhenium carbonyl component, cadmium component and optional halogen component are preferably present in the multimetallic catalytic composite in amounts, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % rhenium, about 0.01 to about 5% cadmium and about 0.1 to about 3.5 wt. % halogen. A key feature associated with the preparation of the subject catalytic composite is reaction of a rhenium carbonyl complex with a porous carrier material containing a uniform dispersion of a cadmium component and of a platinum group metal maintained in the elemental state, whereby the interaction of the rhenium moiety with the platinum group moiety is maximized due to the platinophilic (i.e. platinum-seeking) propensities of the carbon monoxide ligands associated with the rhenium reagent. A specific example of the type of hydrocarbon conversion process disclosed herein is a process for the catalytic reforming of a low octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the subject superactive multimetallic catalytic composite at reforming conditions.

摘要翻译： 通过在碳氢化合物转化条件下使它们与新型减弱的超活性多金属催化复合材料接触来转化碳氢化合物，该催化复合材料包含催化有效量的热解的铼羰基组分与含有催化有效量的铂的均匀分散体的多孔载体材料的组合 维持在元素金属状态的组分和镉组分。 在一个非常优选的实施方案中，该新型催化复合材料还含有催化有效量的卤素组分。 铂族组分，热解的铼羰基组分，镉组分和任选的卤素组分优选以基于元素计算的量存在于多金属催化复合物中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％铼，约0.01至约5％的镉和约0.1至约3.5wt。 ％卤素。 与本发明催化复合材料的制备相关的主要特征是羰基铑合金与含有均匀分散的镉组分和保持在元素状态的铂族金属的多孔载体材料的反应，由此铼的相互作用 与铂族部分的部分由于与铼试剂相关的一氧化碳配体的铂嗜性（即铂寻求）倾向而最大化。 本文公开的烃转化方法的具体实例是低辛烷值汽油馏分的催化重整方法，其中汽油馏分和氢气流在重整条件下与目标超活性多金属催化复合物接触。

公开(公告)号：US4172853A

公开(公告)日：1979-10-30

申请号：US918208

申请日：1978-06-22

申请人： George J. Antos

发明人： George J. Antos

IPC分类号： B01J23/62 ,  B01J23/63 ,  C07C5/32 ,  C07C5/333 ,  C07C5/367 ,  C10G35/09 ,  C07C5/36

CPC分类号： C10G35/09 ,  B01J23/622 ,  B01J23/63 ,  C07C5/325 ,  C07C5/3337 ,  C07C5/367 ,  C07C2521/04 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/62 ,  Y02P20/52

摘要： Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions including a hydrogen-rich and substantially water-free environment, with a catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a Group IVA metallic component, and a lanthanide series component with a porous carrier material. A specific example of the catalyst used in the disclosed hydrocarbon dehydrogenation method in a nonacidic catalytic composite comprising a combination of a platinum group component, a Group IVA metallic component, a lanthanide series component, and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % Group IVA metal, about 0.1 to about 5 wt. % alkali metal or alkaline earth metal, and having an atomic ratio of lanthanide series metal to platinum group metal of about 0.1:1 to 1.25:1. A preferred modifying component for the disclosed catalytic composites in a sulfiding reagent.

摘要翻译： 可脱氢烃在脱氢条件（包括富氢和基本无水环境）下与它们接触脱氢，催化复合物包含催化有效量的铂族组分，IVA族金属组分和镧系元素组合 组分与多孔载体材料。 在公开的烃脱氢方法中用于非酸催化复合材料中的催化剂的具体实例包括铂族组分，IVA族金属组分，镧系元素组分和碱金属或碱土金属组分与多孔载体材料的组合 其量足以导致含有约0.01至约2wt。 ％铂族金属，约0.01至约5wt。 ％IVA族金属，约0.1至约5wt。 ％碱金属或碱土金属，并且镧系金属与铂族金属的原子比为约0.1:1至1.25:1。 在硫化试剂中所公开的催化复合材料的优选改性组分。