公开(公告)号：US11711968B2

公开(公告)日：2023-07-25

申请号：US17221044

申请日：2021-04-02

Applicant: Universal Display Corporation

Inventor： Jui-Yi Tsai ,  Alexey Borisovich Dyatkin ,  Walter Yeager ,  Chuanjun Xia

IPC: H01L51/50 ,  H10K85/30 ,  C07F15/00 ,  C09K11/02 ,  C09K11/06 ,  H10K50/11 ,  H10K50/15 ,  H10K50/18 ,  H10K50/165 ,  H10K50/17 ,  H10K101/10

CPC classification number: H10K85/342 ,  C07F15/0033 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1033 ,  C09K2211/185 ,  H10K50/11 ,  H10K50/15 ,  H10K50/165 ,  H10K50/171 ,  H10K50/18 ,  H10K2101/10

Abstract: A compound having the formula Ir(LA)n(LB)3-n, having the structure




of Formula I is provided. In the structure of Formula I, each of A1 through A8 is independently carbon or nitrogen; at least one of A1 through A8 is nitrogen; ring B is bonded to ring A through a C—C bond; the iridium is bonded to ring A through an Ir—C bond; X is O, S, or Se; each of R1 through R5 are independently selected from a variety of substituents, which may be linked for form a ring; n is an integer from 1 to 3; and at least one R2 adjacent to ring C is not hydrogen. Formulations and devices, such as OLEDs, that include the first compound are also provided.

公开(公告)号：US20230225205A1

公开(公告)日：2023-07-13

申请号：US18178087

申请日：2023-03-03

Applicant: Universal Display Corporation

Inventor： Tyler FLEETHAM ,  Jerald FELDMAN

IPC: H01L51/00 ,  C07F5/02 ,  C09K11/02 ,  C09K11/06

CPC classification number: H10K85/6572 ,  C07F5/027 ,  C09K11/02 ,  C09K11/06 ,  H10K50/121 ,  C09K2211/1007 ,  H10K50/11 ,  H10K2101/10 ,  C09K2211/1018

Abstract: Provided is a new composition of matter for boron containing organic molecules which can be used as hosts or emitters in OLED devices. The compound can have a structure of Formula I

公开(公告)号：US11696492B2

公开(公告)日：2023-07-04

申请号：US16807898

申请日：2020-03-03

Applicant: Universal Display Corporation

Inventor： Hsiao-Fan Chen ,  Daniel W. Silverstein ,  Peter Wolohan ,  Tyler Fleetham ,  Jason Brooks ,  Charles J. Stanton, III ,  Olexandr Tretyak ,  Raghupathi Neelarapu ,  Katarina Rohlfing ,  Douglas Williams

IPC: H01L51/54 ,  H01L51/00 ,  C07F15/00 ,  C09K11/06 ,  H01L51/50

CPC classification number: H01L51/0087 ,  C07F15/0086 ,  C09K11/06 ,  C09K2211/1074 ,  C09K2211/185 ,  H01L51/5012 ,  H01L51/5016

Abstract: A novel compound having a benzimidazole based structure is disclosed that is selected from one of the following structures:




The compound is useful in improving photophysical performance of OLEDs.

公开(公告)号：US20230203076A1

公开(公告)日：2023-06-29

申请号：US18178189

申请日：2023-03-03

Applicant: Universal Display Corporation

Inventor： Scott BEERS ,  Woo-Young SO ,  Hsiao-Fan CHEN

IPC: C07F15/00 ,  H10K59/12 ,  H10K85/40 ,  H10K85/30 ,  H10K85/60

CPC classification number: C07F15/006 ,  C07F15/0086 ,  C07F15/0033 ,  H10K59/12 ,  H10K85/40 ,  H10K85/342 ,  H10K85/346 ,  H10K85/622 ,  H10K85/654 ,  H10K85/6572 ,  H10K85/6576 ,  H10K50/11

Abstract: A compound comprising a first ligand LA of Formula I or Formula II:






wherein A1 and A2 are each independently C or Si;
wherein each RA, and RB independently represents mono to the maximum allowable substitution, or no substitution;
wherein each X1, X2, and X3 is independently C or N;
wherein each R, R1, R2, R3, R4 and RA is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein LA is complexed to a metal M;
wherein M is optionally coordinated to one or more other ligands;
wherein the ligand LA is optionally linked with the one or more other ligands to form a tridentate, tetradentate, pentadentate, or hexadentate ligand; and
wherein any two substituents are optionally joined or fused together to form a ring.

公开(公告)号：US11690285B2

公开(公告)日：2023-06-27

申请号：US17328403

申请日：2021-05-24

Applicant: Universal Display Corporation

Inventor： Nicholas J. Thompson ,  Chun Lin ,  Hsiao-Fan Chen

IPC: H01L51/00 ,  C07F5/02 ,  C09K11/06 ,  C07D403/14 ,  C07F7/08 ,  C07F15/00 ,  H01L51/50

CPC classification number: H01L51/0087 ,  C07D403/14 ,  C07F5/027 ,  C07F7/0812 ,  C07F15/0086 ,  C09K11/06 ,  H01L51/008 ,  H01L51/0067 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0094 ,  C07B2200/05 ,  C09K2211/1018 ,  C09K2211/1048 ,  C09K2211/185 ,  H01L51/5016 ,  H01L2251/5384 ,  H01L2251/552

Abstract: Disclosed is an OLED configuration that although comprises an exciplex that has an emission spectrum that is redder than the emission spectrum of the emitter, the emission from the exciplex is suppressed so that the overall OLED emission spectrum is still dominated by the emission of the emitter.

公开(公告)号：US20230192665A1

公开(公告)日：2023-06-22

申请号：US18062110

申请日：2022-12-06

Applicant: UNIVERSAL DISPLAY CORPORATION

Inventor： Tyler FLEETHAM ,  Peter WOLOHAN ,  Hsiao-Fan CHEN ,  Nicholas J. THOMPSON ,  Jerald FELDMAN ,  Geza SZIGETHY

IPC: C07D403/14 ,  H10K85/60 ,  C07D487/06 ,  C07D487/16 ,  C07F5/02 ,  C07D493/10 ,  C07D495/10 ,  C07D519/00 ,  H10K85/40 ,  C07F7/08 ,  H10K50/00

CPC classification number: C07D403/14 ,  H01L51/0072 ,  H01L51/0067 ,  H01L51/0055 ,  C07D487/06 ,  C07D487/16 ,  C07F5/027 ,  H01L51/0071 ,  H01L51/0073 ,  C07D493/10 ,  H01L51/0074 ,  C07D495/10 ,  C07D519/00 ,  H01L51/0094 ,  C07F7/0812 ,  H01L51/50 ,  C07B2200/05

Abstract: Provided are compounds comprising a first moiety and a second moiety, wherein the first moiety comprises an azabenzene joined to a trivalent nitrogen atom that is part of an at least three-cyclic heteroaromatic ring system. Also provided are formulations comprising these compounds. Further provided are organic light emitting devices (OLEDs) and related consumer products that utilize these compounds.

公开(公告)号：US11678567B2

公开(公告)日：2023-06-13

申请号：US16801549

申请日：2020-02-26

Applicant: Universal Display Corporation

Inventor： Bin Ma ,  Chun Lin

IPC: H10K85/60 ,  C09K11/06 ,  H10K50/11 ,  H10K50/18 ,  H10K50/15 ,  H10K85/30 ,  H01L51/00 ,  C07D209/86 ,  C09K11/02 ,  H01L51/50

CPC classification number: H01L51/0056 ,  C07D209/86 ,  C09K11/025 ,  C09K11/06 ,  H01L51/0067 ,  H01L51/0071 ,  H01L51/0072 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0059 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5056 ,  H01L51/5096

Abstract: This invention discloses a novel two dimensional material having propellane core for organic light emitting diodes. These compounds can be used as hosts, charging transporting materials, or blocking materials for PHOLEDs. The devices comprising these compounds have better performance due to the honeycomb pi-extended structure in the propellane molecules.

公开(公告)号：US11678565B2

公开(公告)日：2023-06-13

申请号：US16000134

申请日：2018-06-05

Applicant: Universal Display Corporation

Inventor： Tongxiang (Aaron) Lu ,  George Fitzgerald ,  Morgan C. MacInnis ,  Paul M. Lahti

IPC: H10K85/30 ,  C07F15/00 ,  H10K50/12 ,  C07F13/00 ,  H10K50/11 ,  H10K50/18 ,  H10K50/81 ,  H10K50/82 ,  H10K50/15 ,  H10K50/16 ,  H10K85/60 ,  H10K101/10

CPC classification number: H10K85/346 ,  C07F13/00 ,  C07F15/006 ,  C07F15/0033 ,  C07F15/0086 ,  C07F15/0093 ,  H10K50/12 ,  H10K50/18 ,  H10K50/81 ,  H10K50/82 ,  H10K50/11 ,  H10K50/15 ,  H10K50/16 ,  H10K85/6572 ,  H10K2101/10

Abstract: The present invention includes novel heterocyclic materials for use as blue phosphorescent materials in OLED devices. The materials are based on carbene and heterocyclic 5-membered ring linked ligands, which may be complexed to a transition metal via a metal-carbon (carbene) bond and a metal-nitrogen covalent bond. In one aspect, the present invention provides compounds comprising a ligand LA having the structure of Formula I:

公开(公告)号：US20230180594A1

公开(公告)日：2023-06-08

申请号：US17980014

申请日：2022-11-03

Applicant: Universal Display Corporation

Inventor： Jui-Yi TSAI ,  Geza SZIGETHY ,  Tongxiang LU ,  Alexey Borisovich DYATKIN ,  Llorenç BENAVENT ,  Miguel A. ESTERUELAS ,  Ana M. LOPEZ ,  Enrique OÑATE

IPC: H01L51/00 ,  C07F15/00 ,  C09K11/06

CPC classification number: H01L51/0085 ,  C07F15/0033 ,  C09K11/06 ,  H01L51/5012

Abstract: A compound including a first ligand LA of Formula I,




is provided. In Formula I, rings A, B, C, and D are each a 5-membered or 6-membered ring; L1 is selected from CR, SiR, GeR, N, or B; L2 is selected from CRR′, SiRR′, GeRR′, NR, O, S, Se, or C═X; X is CRR′, O, or S; each of Z1, Z2, Z3, Z4, Z5, Z6, Z7, Z8, and Z9 is independently C or N; each R, R′, RA, RB, RC, and RD is independently hydrogen or a General Substituent; LA is coordinated to a metal M through the indicated dashed lines; metal M may be coordinated to other ligands; and any two adjacent R, R′, RA, RB, RC, and RD may be joined or fused to form a ring. Formulations, OLEDs, and consumer products including the compound are also provided.

公开(公告)号：US11672175B2

公开(公告)日：2023-06-06

申请号：US16867696

申请日：2020-05-06

Applicant: Universal Display Corporation

Inventor： Zhiqiang Ji ,  Lichang Zeng ,  Alexey Borisovich Dyatkin ,  Chuanjun Xia

IPC: H01L51/50 ,  H01L51/00 ,  C09K11/06 ,  C09K11/02 ,  C07D487/04 ,  C07D405/14

CPC classification number: H01L51/0072 ,  C07D405/14 ,  C07D487/04 ,  C09K11/025 ,  C09K11/06 ,  H01L51/0052 ,  H01L51/0067 ,  H01L51/0073 ,  H01L51/0074 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/185 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5072 ,  H01L2251/5384

Abstract: Indolocarbazole materials with substitution attached at specific positions and methods to synthesize the same are disclosed. The materials are used as hosts for improving performance of organic electroluminescence devices.