摘要:
This invention relates to an organopentasiloxane with the following formula ##STR1## wherein A is the hydrogen atom or an aliphatically unsaturated monovalent hydrocarbon group, R is the same or different monovalent hydrocarbon group, and n is an integer with a value of 2 to 4, which carries silicon-bonded hydrogen or a silicon-bonded, aliphatically unsaturated monovalent hydrocarbon group at one molecular chain terminal and silicon-bonded organoxy group(s) at the other terminal.
摘要:
A method for the preparation of an organopolysiloxane which contains in each molecule at least one phenyl group and at least one silicon-bonded hydrogen atom is disclosed, said method comprising reacting (I) an organopolysiloxane having a molecular weight not exceeding 100,000 and containing in each molecule at least one phenyl group and at least one alkoxy group with (II) 1,1,3,3-tetramethyldisiloxane, wherein the reaction is carried out in the presence of an aqueous hydrochloric acid solution, this aqueous solution preferably further comprising an alcohol.
摘要:
The present invention relates to a method for the production of liquid-crystalline organopolysiloxane which provides for the facile introduction of a mesogenic group without the use of a hydrosilylation reaction.
摘要:
There is disclosed a novel phthalic acid ester-modified organopolysiloxane having the general formula ##STR1## where in R.sup.1 is a monovalent hydrocarbon group, R.sup.2 is a group R.sup.1 or a group with the formula ##STR2## with the proviso that at least one of the groups R.sup.2 in each molecule is the group with the formula ##STR3## in which R.sup.3 is an alkyl group, R.sup.4 is an alkylene group, and m is a positive integer.The organosiloxane is useful as a co-reactant in the preparation of organic resins such as polyesters, polyamides and polyimides.
摘要:
Polymerizing cyclic trisiloxanes using as the polymerization initiator an alkali metal salt of an organosilane or organopolysiloxane having a terminal alkenyl group, followed by termination of the reaction, produces an organopolysiloxane having an alkenyl group on one end. These organopolysiloxanes are useful for making copolymers and as additives to siloxane elastomers.
摘要:
Polydiorganosiloxanes which have a pendant alkenyl radical in the middle of the molecular chain are prepared by a nonequilibrium, living polymerization of cyclic trisiloxanes using an organopolysiloxane alkali metal salt of the formula ##STR1## where M is lithium, sodium, or potassium, which takes place under substantially anhydrous conditions, and the polymerization is terminated with an end-capping reaction to produce a polydiorganosiloxane of the formula ##STR2## where R.sup.1 is an alkenyl radical. These polymers can be used to make graft copolymers and can be made more functional when the ends are capped with functional groups.
摘要:
A current source inverter having a converter for changing alternating current into direct current, an inverter for changing the d.c. output of the converter into alternating current, and a reactor interposed between the converter and the inverter comprises power failure detecting means for detecting the power failure of the a.c. input of the converter. The power failure detecting means is constructed of square wave generator circuits which generate square waves when voltages in respective polarities of respective phases of the a.c. input exist, an adder which adds the outputs of said square wave generator circuits, and a comparator which compares an output of said adder with a predetermined value and which provides an output when the adder output is below the predetermined value. Both terminals of the reactor of the current source inverter are substantially short-circuited by the output of said power failure detecting means, thereby to prevent occurrence of an overvoltage at the time of the power failure of the a.c. input of the converter.
摘要:
Cemented carbide material consists essentially of 70 to 90% by weight of tungsten carbide or of a mixture of tungsten and carbide at least one transition metal carbide, the transition metal being one other than tungsten selected from Groups IV to VI of the Periodic Table and 10 to 30% by weight of a binder. The binder contains 20 to 90% by weight of nickel, 10 to 80% by weight of cobalt and 5 to 25% by weight of chromium as the base ingredients thereof. The cemented carbide material has improved resistance to oxidation, to wear and especially to thermal cracking and is therefore suitable for rolls, guide rollers and dies for plastic hot working.