Amphiphilic molecular sieve containing hydrophilic group on the outside and lipophilic group on the inside and production method threof

    公开(公告)号:US10759667B2

    公开(公告)日:2020-09-01

    申请号:US16029215

    申请日:2018-07-06

    Abstract: The present invention provides an amphiphilic molecular sieve containing a hydrophilic group on the outside and a lipophilic group on the inside and a production method thereof. The production method comprises: dispersing the ZSM-5 spherical nano-molecular sieve into toluene, adding thereto an organosilane containing a hydrophilic group and reacting at 40-80° C. for 2-16 h, to obtain a molecular sieve containing a hydrophilic group; placing the molecular sieve containing a hydrophilic group in an aqueous solution of sodium hydroxide and reacting at 50-90° C. for 10-50 min, to obtain a molecular sieve containing a hydrophilic group on the outside; dispersing the molecular sieve containing a hydrophilic group on the outside into toluene, adding thereto an organosilane containing a lipophilic group and reacting at 40-80° C. for 2-12 h, to obtain the amphiphilic molecular sieve containing a hydrophilic group on the outside and a lipophilic group on the inside. The present invention also provides an amphiphilic molecular sieve obtained by the above production method, which contains a hydrophilic group on the outside and a lipophilic group on the inside.

    PREDICTION METHOD FOR SHALE OIL AND GAS SWEET SPOT REGION, COMPUTER DEVICE AND COMPUTER READABLE STORAGE MEDIUM

    公开(公告)号:US20200211126A1

    公开(公告)日:2020-07-02

    申请号:US16572600

    申请日:2019-09-17

    Abstract: The invention provides a prediction method for a shale oil and gas sweet spot region, a computer device and a computer readable storage medium, wherein the method comprises: acquiring an oil and gas content influencing parameter value, an oil and gas fluidity influencing parameter value and a compressibility influencing parameter value, and production cost data; determining a final produced oil equivalent corresponding to each influencing parameter value according to a pre-established final produced oil equivalent prediction model; determining an economic lower limit value of the final produced oil equivalent according to the production cost data; determining whether or not the shale oil and gas region to be predicted is a shale oil and gas sweet spot region. The above technical solution realizes quantitative prediction of a shale oil and gas sweet spot region, improves prediction accuracy, and provides scientific guidance for shale oil and gas exploration and development.

    Amphiphilic molecular sieve containing lipophilic group on the outside and hydrophilic group on the inside and production method thereof

    公开(公告)号:US10647586B2

    公开(公告)日:2020-05-12

    申请号:US16029170

    申请日:2018-07-06

    Abstract: The present invention provides an amphiphilic molecular sieve containing a lipophilic group on the outside and a hydrophilic group on the inside and a production method thereof. The production method comprises: dispersing the nano-ZSM-5 molecular sieve into toluene, adding an organosilane containing a lipophilic group and reacting at 60-100° C. for 4-16 h, to obtain a molecular sieve containing a lipophilic group; placing the molecular sieve containing a lipophilic group in a mixed solution of sodium hydroxide solution and ethanol and reacting at 60-95° C. for 20-60 min, to obtain a molecular sieve containing a lipophilic group on the outside; dispersing the molecular sieve containing a lipophilic group on the outside into toluene, adding an organosilane containing a hydrophilic group and reacting at 60-100° C. for 4-16 h, to obtain the amphiphilic molecular sieve containing a lipophilic group on the outside and a hydrophilic group on the inside. The present invention also provides a molecular sieve obtained by the above production method, which does not destroy the characteristics of the original molecular sieve and has hydrophilic and lipophilic amphiphilic properties.

    LINEAR HIERARCHICAL STRUCTURE LITHIUM TITANATE MATERIAL, PREPARATION AND APPLICATION THEREOF

    公开(公告)号:US20200083528A1

    公开(公告)日:2020-03-12

    申请号:US16562418

    申请日:2019-09-05

    Abstract: A linear hierarchical structure lithium titanate material, preparation and application thereof. The crystal phase of the lithium titanate material is a spinel-type crystal phase or a monoclinic crystal phase or a composite crystal phase thereof; the lithium titanate material is mainly composed of a linear hierarchical structure; the linear hierarchical structure has an aspect ratio larger than 10; and the surface components of the linear hierarchical structure are nanosheets. The long-axis of the linear structure facilitates the effective migration of electrons, and the sheet-like hierarchical structure facilitates the rapid intercalation and deintercalation process of lithium ions, sodium ions or potassium ions, and a large specific surface area facilitates the contact area between the electrolyte solution and the electrodes and reduces the current density, thus is excellent in a rapid charge-discharge performance of the battery.

    PROCESS FOR PREPARING TITANIC ACID SALT, TITANIC ACID, AND TITANIUM OXIDE HAVING CONTROLLABLE PARTICLE SIZE AND HIERARCHICAL STRUCTURE

    公开(公告)号:US20200071185A1

    公开(公告)日:2020-03-05

    申请号:US16556211

    申请日:2019-08-29

    Abstract: A process for preparing a titanic acid salt, titanic acid, and titanium oxide having a controllable particle size and a hierarchical structure, wherein the process includes the steps of: preparing a titanium-containing peroxo-complex solution; adding a basic metal compound to the titanium-containing peroxo-complex solution to form a mixture solution; adding one of polyvinyl alcohol, hydroxypropyl methyl cellulose, and polyethylene glycol to the mixture solution to form a precursor dispersion; and subjecting the precursor dispersion to a solvothermal reaction to obtain the titanic acid salt having a hierarchical structure. The process for preparing a titanic acid salt, titanic acid, and titanium oxide having a controllable particle size and a hierarchical structure, can not only realize the regulation of morphology and particle diameter of constituent units in the hierarchical structure, but also can achieve the regulation of particle size in the hierarchical structure.

    ULTRASONIC MICROBUBBLE GENERATION METHOD, APPARATUS AND SYSTEM

    公开(公告)号:US20200070067A1

    公开(公告)日:2020-03-05

    申请号:US16546588

    申请日:2019-08-21

    Abstract: The embodiments of the present disclosure disclose an ultrasonic microbubble generation method, apparatus and system. The apparatus comprises a horn-shaped conductor including an upper horn-shaped body and a lower cylindrical body; the horn-shaped body is provided with a cavity having an upper opening, an upper end of the cavity is fixedly connected with a micropore vibration thin sheet, a micropore array of the micropore vibration thin sheet is corresponding to the upper opening of the cavity, and a side wall of the cavity is provided with a through hole for external gas to enter the cavity; the cylindrical body is provided with a transducing ring and an electrode sheet, an outer side of the cylindrical body is insulated and sealed, and a connection wire of the electrode sheet is led out by a steel pipe and connected with an external ultrasonic oscillation controller.

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