Catalytic hydrogenation process utilizing multi-stage ebullated bed reactors
    141.
    发明授权
    Catalytic hydrogenation process utilizing multi-stage ebullated bed reactors 失效
    使用多级沸腾床反应器的催化氢化方法

    公开(公告)号:US06270654B1

    公开(公告)日:2001-08-07

    申请号:US09087181

    申请日:1998-05-29

    IPC分类号: C10G4500

    摘要: A process for catalytic multi-stage hydrogenation of heavy carbonaceous feedstocks using catalytic ebullated bed reactors is operated at selected flow and operating conditions so as to provide improved reactor operations and produce increased yield of lower boiling hydrocarbon liquid and gas products. The disclosed process advantageously takes advantage of an external gas/liquid separation unit associated with the first stage reactor to allow for a more efficient and effective catalytic hydrocracking process. The more efficient process is primarily a result of the increased catalyst loading and lower gas hold-up in the ebullated reactors.

    摘要翻译: 使用催化沸腾床反应器的重碳质原料催化多级氢化的方法在所选择的流动和操作条件下操作,以提供改进的反应器操作并产生较低沸点烃液体和气体产物的产率。 所公开的方法有利地利用与第一级反应器相关联的外部气/液分离单元以允许更有效和有效的催化加氢裂化方法。 更有效的方法主要是催化剂负载增加和沸腾反应器中较低气体滞留的结果。

    Low pressure process for the hydroconversion of heavy hydrocarbons
    142.
    发明授权
    Low pressure process for the hydroconversion of heavy hydrocarbons 失效
    重烃加氢转化的低压工艺

    公开(公告)号:US6136179A

    公开(公告)日:2000-10-24

    申请号:US91610

    申请日:1998-06-19

    CPC分类号: C10G47/26 C10G47/02

    摘要: This invention relates to a process of catalytic hydroconversion of a heavy hydrocarbon oil containing a substantial portion of components having an atmospheric boiling point above 565.degree. C. to give a product hydrocarbon oil containing components having a boiling point below about 565.degree. C. The process includes steps of mixing a heavy hydrocarbon oil with an oil soluble molybdenum compound, introducing the resulting mixture into a hydroconversion zone, introducing a reactor feed gas into the hydroconversion zone, and recovering the product hydrocarbon oil from the hydroconversion zone.

    摘要翻译: PCT No.PCT / US97 / 02409 Sec。 371日期:1998年6月19日 102(e)1998年6月19日PCT 1997年2月14日提交PCT公布。 第WO97 / 29841号公报 日期:1997年8月21日本发明涉及含有大部分沸点高于565℃的组分的重质烃油的催化加氢转化方法,得到含有沸点低于约565℃的组分的产物烃油 该方法包括将重质烃油与油溶性钼化合物混合的步骤,将所得混合物引入加氢转化区,将反应器进料气体引入加氢转化区,并从加氢转化区回收产物烃油。

    Catalytic process for treating heavy oils
    144.
    发明授权
    Catalytic process for treating heavy oils 失效
    用于处理重油的催化工艺

    公开(公告)号:US5178749A

    公开(公告)日:1993-01-12

    申请号:US586622

    申请日:1990-09-21

    摘要: The hydroprocessing of heavy oils is improved by the use of a high activity slurry catalyst prepared by sulfiding an aqueous Group VIB metal compound with a gas containing hydrogen sulfide to a dosage greater than 8 SCF of hydrogen sulfide per pound of Group VIB metal. After introducing the slurry catalyst into the heavy oil, and subjecting the mixture to elevated temperatures and partial pressures of hydrogen, the mixture is treated in a fixed or ebullated bed of hydrodesulfurization/hydrodemetalation catalyst under hydroprocessing conditions.

    摘要翻译: 通过使用通过将含有硫化氢的气体的VIB族金属化合物硫化为每磅VIB族金属的大于8SCF的硫化氢而制备的高活性浆料催化剂来改善重油的加氢处理。 在将浆料催化剂引入重油中,并将混合物经受高温和氢气分压后,在加氢脱硫/加氢脱矿催化剂的固定或沸腾床中在加氢处理条件下处理该混合物。

    Method for controlling sedimentation in an ebullated bed process
    146.
    发明授权
    Method for controlling sedimentation in an ebullated bed process 失效
    控制沸腾床处理沉淀的方法

    公开(公告)号:US4898663A

    公开(公告)日:1990-02-06

    申请号:US275831

    申请日:1988-11-25

    IPC分类号: C10G47/26

    CPC分类号: C10G47/26

    摘要: In an ebullated bed process, it has been found that in switching from one sediment yielding feedstock to a second sediment yielding feedstock that the transient sediment concentration is 5 to 8 times the steady state concentration. Such transients have caused unit shutdowns with lost production time.A method has been found which avoids these high transient sediment concentrations. Second feedstock is added incrementally (1 vol % to 2 vol % of the final rate) over the period of a week or more and sediment in the product analyzed. After full second feedstock rate is achieved, first feedstock is reduced incrementally with sediment analysis. Higher unit utilization is achieved with the corresponding increased yearly production.

    Additive for the hydroconversion of a heavy hydrocarbon oil
    147.
    发明授权
    Additive for the hydroconversion of a heavy hydrocarbon oil 失效
    加氢转化重质烃油的添加剂

    公开(公告)号:US4863887A

    公开(公告)日:1989-09-05

    申请号:US131437

    申请日:1987-12-11

    CPC分类号: C10G47/26 C10G49/00

    摘要: There is provided an additive for the hydroconversion of a heavy hydrocarbon oil, which is obtained by suspending a fine powder of a carbonaceous substance and a solution of a heteropolymolybdic acid and/or transition metal salts thereof in a hydrocarbon oil. By the use of the additive of the present invention, the hydroconversion of a heavy hydrocarbon oil can be effectively performed at high conversion without occurrence of coking.

    摘要翻译: 提供了通过将碳质物质的细粉末和杂多钼酸和/或其过渡金属盐的溶液悬浮在烃油中而获得的重质烃油的加氢转化的添加剂。 通过使用本发明的添加剂,可以以高转化率有效地进行重质烃油的加氢转化而不发生焦化。

    Hydrovisbreaking of oils
    149.
    发明授权
    Hydrovisbreaking of oils 失效
    油的水力断裂

    公开(公告)号:US4708784A

    公开(公告)日:1987-11-24

    申请号:US18690

    申请日:1987-02-25

    IPC分类号: C10G47/26 C10G45/04

    CPC分类号: C10G47/26

    摘要: A hydrotreating (hydrovisbreaking) process comprises the step of contacting under suitable reaction conditions (A) a substantially liquid hydrocarbon-containing feed stream which contains more than 0.1 weight-% Ramsbottom carbon residue, (B) a free hydrogen-containing gas and (C) a catalyst composition comprising alkyl molybdate and/or molybdenum sulfonate.

    摘要翻译: 加氢处理(加氢脱硫)方法包括在合适的反应条件(A)下接触的步骤(A)基本上液体含烃的进料流,其含有大于0.1重量%的Ramsbottom碳残余物,(B)游离含氢气体和(C )包含钼酸烷基酯和/或磺酸钼的催化剂组合物。

    Hydrocracking of heavy feeds with dispersed dual function catalyst
    150.
    发明授权
    Hydrocracking of heavy feeds with dispersed dual function catalyst 失效
    用分散双功能催化剂加氢裂解重质进料

    公开(公告)号:US4604189A

    公开(公告)日:1986-08-05

    申请号:US685589

    申请日:1984-12-24

    IPC分类号: C10G47/26 C10G47/20

    CPC分类号: C10G47/26

    摘要: Catalytic hydroconversion of a relatively heavy hydrocarbon residual fraction is effected by adding a thermally decomposable metal compound to the oil, along with an acidic catalyst solid to the oil, and passing the mixture to a hydroconversion zone containing hydrogen at an elevated temperature. Preferred metals are cobalt and molybdenum. Preferred solids are large pore zeolites, silica/alumina, clays and surface activated metal oxides.

    摘要翻译: 相对重的烃残余馏分的催化加氢转化通过向油中加入可热分解的金属化合物以及酸性催化剂固体加入到油中,并在升高的温度下将混合物送入含氢的加氢转化区来进行。 优选的金属是钴和钼。 优选的固体是大孔沸石,二氧化硅/氧化铝,粘土和表面活化的金属氧化物。