公开(公告)号：US09975112B2

公开(公告)日：2018-05-22

申请号：US14969747

申请日：2015-12-15

Applicant: ENI S.p.A.

Inventor： Giuseppe Bellussi ,  Angela Carati ,  Maria Federica Gagliardi ,  Stefano Zanardi ,  Marcello Marella ,  Roberto Scattolin ,  Michele Tomaselli

IPC: B01J31/00 ,  B01J23/00 ,  B01J27/051 ,  B01J27/049 ,  B01J35/10 ,  B01J37/03 ,  B01J37/20 ,  C10G45/08 ,  B01J23/883 ,  B01J23/888 ,  B01J21/00 ,  B01J25/00

CPC classification number: B01J27/0515 ,  B01J23/002 ,  B01J23/883 ,  B01J23/8885 ,  B01J27/049 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/033 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G2300/1044 ,  C10G2300/1062 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2400/04 ,  C10G2400/06 ,  B01J2523/31 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/41

Abstract: New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.pC  (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, O is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH  (I) wherein the groups RIRIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N  (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b)/c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d=(2a+6b+Hc)/2 wherein H=4 when Z=Si H=3 when Z=Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.

公开(公告)号：US09849446B2

公开(公告)日：2017-12-26

申请号：US15241185

申请日：2016-08-19

Applicant: ExxonMobil Research and Engineering Company

Inventor： John P. Greeley ,  Paul Podsiadlo ,  William Ernest Lewis ,  Roby Bearden, Jr. ,  Amitava Sarkar ,  Mainak Ghosh ,  Ramanathan Sundararaman ,  Thomas F. Degnan, Jr. ,  Manuel A. Francisco

IPC: C10G45/04 ,  B01J27/051 ,  B01J37/20 ,  B01J23/881 ,  C10G47/06 ,  B01J37/18

CPC classification number: B01J27/0515 ,  B01J23/881 ,  B01J27/049 ,  B01J35/0006 ,  B01J37/04 ,  B01J37/18 ,  B01J37/20 ,  C10G45/04 ,  C10G47/06

Abstract: Systems and methods are provided for slurry hydroconversion of a heavy oil feedstock, such as an atmospheric or vacuum resid, in the presence of an enhanced or promoted slurry hydroconversion catalyst system. The slurry hydroconversion catalyst system can be formed from a) a Group VIII non-noble metal catalyst precursor/concentrate (such as an iron-based catalyst precursor/concentrate) and b) a Group VI metal catalyst precursor/concentrate (such as a molybdenum-based catalyst precursor/concentrate) and/or a Group VI metal sulfided catalyst.

公开(公告)号：US09731283B2

公开(公告)日：2017-08-15

申请号：US15243007

申请日：2016-08-22

Applicant: ExxonMobil Research and Engineering Company

Inventor： Majosefina Cunningham ,  Jason M. Golias ,  Chuansheng Bai

IPC: B01J31/02 ,  B01J31/34 ,  B01J31/06 ,  B01J35/10 ,  C10G45/08 ,  B01J37/08 ,  B01J23/882 ,  B01J23/883 ,  B01J31/04 ,  B01J31/12

CPC classification number: B01J31/34 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J27/049 ,  B01J27/0515 ,  B01J31/04 ,  B01J31/069 ,  B01J31/124 ,  B01J35/002 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/0018 ,  B01J37/084 ,  B01J37/086 ,  B01J37/20 ,  C10G45/08

Abstract: Bulk metallic catalyst precursor compositions are provided that include a Group VIB metal, a Group VIII metal, an organic-compound based component, and an organo-metalloxane polymer or gel. The catalyst precursor compositions can further include a binder. Amorphous sulfided catalysts formed from the catalyst precursor compositions are also provided. The catalyst precursor compositions can have a surface area of about 20 m2/g or less.

公开(公告)号：US20170080410A1

公开(公告)日：2017-03-23

申请号：US15243007

申请日：2016-08-22

Applicant: ExxonMobil Research and Engineering Company

Inventor： Majosefina CUNNINGHAM ,  Jason M. GOLIAS ,  Chuansheng BAI

IPC: B01J31/34 ,  B01J35/10 ,  C10G45/08 ,  B01J31/06

CPC classification number: B01J31/34 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J27/049 ,  B01J27/0515 ,  B01J31/04 ,  B01J31/069 ,  B01J31/124 ,  B01J35/002 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/0018 ,  B01J37/084 ,  B01J37/086 ,  B01J37/20 ,  C10G45/08

Abstract: Bulk metallic catalyst precursor compositions are provided that include a Group VIB metal, a Group VIII metal, an organic-compound based component, and an organo-metalloxane polymer or gel. The catalyst precursor compositions can further include a binder. Amorphous sulfided catalysts formed from the catalyst precursor compositions are also provided. The catalyst precursor compositions can have a surface area of about 20 m2/g or less.

公开(公告)号：US09327274B2

公开(公告)日：2016-05-03

申请号：US14019319

申请日：2013-09-05

Applicant: Jinyi Han ,  Alexander E. Kuperman

Inventor： Jinyi Han ,  Alexander E. Kuperman

IPC: B01J27/051 ,  B01J27/049 ,  B01J27/043 ,  B01J27/047 ,  B01J35/00 ,  B01J35/10

CPC classification number: B01J27/0515 ,  B01J27/043 ,  B01J27/047 ,  B01J27/049 ,  B01J27/051 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1038 ,  C10G45/08

Abstract: The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The self-supported MMS catalyst contains Ni:W in a mole ratio of 1:3 to 4:1, on a transition metal basis. The self supported MMS catalyst is characterized as having an HYD reaction rate constant of at least 15% higher than that of a catalyst comprising nickel sulfide alone or a catalyst comprising tungsten sulfide alone, when compared on same metal molar basis in hydrotreating of benzene as a feedstock at identical process conditions.

Abstract translation: 本发明涉及一种用于加氢处理烃原料的自支撑混合金属硫化物（MMS）催化剂及其制备方法。 自支撑的MMS催化剂以过渡金属为基础，含有摩尔比为1:3至4:1的Ni:W。 自支撑的MMS催化剂的特征在于，与单独的硫化镍或仅含硫化钨的催化剂相比，HYD反应速率常数比单独的硫化镍催化剂高至少15％，当与 原料在相同的工艺条件下。

公开(公告)号：US09242231B2

公开(公告)日：2016-01-26

申请号：US13855258

申请日：2013-04-02

Applicant: Yeda Research and Development Co. Ltd. ,  NDSU Research Foundation

Inventor： Reshef Tenne ,  Yulia Tsverin ,  Uwe Burghaus ,  Mallikharjuna Rao Komarneni

IPC: B01J27/049 ,  B01J27/02 ,  B01J35/00 ,  B01J35/06 ,  C10G45/04 ,  B01D53/86 ,  B01J37/16 ,  B01J37/02

CPC classification number: B01J27/049 ,  B01D53/8687 ,  B01D2255/20776 ,  B01D2255/802 ,  B01D2257/70 ,  B01J27/02 ,  B01J35/0013 ,  B01J35/004 ,  B01J35/006 ,  B01J35/06 ,  B01J37/0217 ,  B01J37/16 ,  C02F2305/08 ,  C02F2305/10 ,  C10G45/04 ,  C10G2300/202 ,  C10G2300/70 ,  C10G2300/703 ,  Y02W10/37

Abstract: This invention relates to a hybrid component comprising at least one nanoparticle of inorganic layered compound (in the form of fullerene-like structure or nanotube), and at least one metal nanoparticle, uses thereof as a catalyst, (e.g. photocatalysis) and processes for its preparation.

Abstract translation: 本发明涉及包含至少一种无机层状化合物纳米颗粒（呈富勒烯结构或纳米管形式）的纳米颗粒和至少一种金属纳米颗粒，其用途作为催化剂（例如光催化剂）及其工艺 制备。

公开(公告)号：US08956585B2

公开(公告)日：2015-02-17

申请号：US13010885

申请日：2011-01-21

Applicant: Michael Anthony Reynolds

Inventor： Michael Anthony Reynolds

IPC: C01B17/00 ,  C01B25/14 ,  C01D5/08 ,  C01G39/06 ,  B01J27/04 ,  B01J27/047 ,  B01J27/049 ,  B01J27/051 ,  B01J35/02 ,  B01J35/10 ,  B01J37/03 ,  C01B17/20 ,  C01B19/00 ,  C01G39/00 ,  C01G41/00 ,  C01G49/00 ,  C01G51/00 ,  C01G53/00 ,  C10G47/02 ,  B82Y30/00

CPC classification number: C01G39/06 ,  B01J27/04 ,  B01J27/047 ,  B01J27/049 ,  B01J27/051 ,  B01J27/0515 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/031 ,  B82Y30/00 ,  C01B17/20 ,  C01B19/002 ,  C01B19/007 ,  C01G39/006 ,  C01G41/006 ,  C01G49/009 ,  C01G51/006 ,  C01G53/006 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/40 ,  C10G47/02

Abstract: A method for producing a thiometallate or selenometallate material is provided in which a first salt containing an anionic component selected from the group consisting of MoS42−, MoSe42−, WS42−, WSe42−, VS43−, and VSe43− and a second salt containing a cationic component comprising a metal in any non-zero oxidation state selected from the group consisting of Cu, Fe, Ag, Co, Mn, Re, Ru, Rh, Pd, Ir, Pt, B, Al, Ce, La, Pr, Sm, Eu, Yb, Lu, Dy, Ni, Zn, Bi, Sn are mixed under anaerobic conditions in an aqueous mixture at a temperature of from 50° C. to 150° C.

Abstract translation: 提供一种生产硫属金属或硒金属酸盐材料的方法，其中含有选自MoS42-，MoSe42-，WS42-，WSe42-，VS43-和VSe43-的阴离子组分的第一盐和含有 阳离子组分，其包含选自Cu，Fe，Ag，Co，Mn，Re，Ru，Rh，Pd，Ir，Pt，B，Al，Ce，La，Pr中的任何非零氧化态的金属， 将Sm，Eu，Yb，Lu，Dy，Ni，Zn，Bi，Sn在厌氧条件下在50〜150℃的温度下在含水混合物中混合。

公开(公告)号：US08940268B2

公开(公告)日：2015-01-27

申请号：US13010883

申请日：2011-01-21

Applicant: Michael Anthony Reynolds

Inventor： Michael Anthony Reynolds

IPC: C01B17/00 ,  C01B25/14 ,  C01D5/08 ,  C01G39/00 ,  B01J27/04 ,  B01J27/047 ,  B01J27/049 ,  B01J27/051 ,  B01J35/10 ,  B01J37/03 ,  C01B17/20 ,  C01B19/00 ,  C01G39/06 ,  C01G41/00 ,  C01G49/00 ,  C01G51/00 ,  C01G53/00 ,  C01G55/00 ,  C10G47/02 ,  B82Y30/00

CPC classification number: C01G39/006 ,  B01J27/04 ,  B01J27/047 ,  B01J27/049 ,  B01J27/051 ,  B01J27/0515 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/031 ,  B82Y30/00 ,  C01B17/20 ,  C01B19/002 ,  C01B19/007 ,  C01G39/06 ,  C01G41/006 ,  C01G49/009 ,  C01G51/006 ,  C01G53/006 ,  C01G55/002 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/40 ,  C10G47/02

Abstract: A method for producing a thiometallate or selenometallate material is provided in which a first salt containing an anionic component selected from the group consisting of MoS42−, MoSe42−, WS42−, WSe42−, VS43−, and VSe43−, and a second salt containing a cationic component comprising a metal in any non-zero oxidation state selected from the group consisting of Fe, Ag, Co, Mn, Re, Ru, Rh, Pd, Ir, Pt, B, Al, Ce, La, Pr, Sm, Eu, Yb, Lu, Dy, Ni, Zn, Bi, Sn, Pb, Cd, Sb, Ge, Ga, In, Au, Hg are mixed under anaerobic conditions in an aqueous mixture at a temperature of from 15° C. to 150° C.

Abstract translation: 提供了一种生产硫代金属或硒金属酸盐材料的方法，其中含有选自MoS42-，MoSe42-，WS42-，WSe42-，VS43-和VSe43-的阴离子组分的第一盐和含 包含选自Fe，Ag，Co，Mn，Re，Ru，Rh，Pd，Ir，Pt，B，Al，Ce，La，Pr，Sm中的任何非零氧化态的金属的阳离子组分 ，Eu，Yb，Lu，Dy，Ni，Zn，Bi，Sn，Pb，Cd，Sb，Ge，Ga，In，Au，Hg在厌氧条件下在15℃的温度下在含水混合物中混合。 至150℃

公开(公告)号：US08834706B2

公开(公告)日：2014-09-16

申请号：US13701528

申请日：2011-06-03

Applicant: Kyung Seok Noh ,  Jae Wook Ryu ,  Do Hyoun Kim ,  Gyung Rok Kim ,  Seung Woo Lee ,  Do Woan Kim ,  Sun Choi ,  Seung Hoon Oh ,  Byung Won Yoon ,  Bum Suk Chun

Inventor： Kyung Seok Noh ,  Jae Wook Ryu ,  Do Hyoun Kim ,  Gyung Rok Kim ,  Seung Woo Lee ,  Do Woan Kim ,  Sun Choi ,  Seung Hoon Oh ,  Byung Won Yoon ,  Bum Suk Chun

IPC: C10G67/02 ,  B01J29/12 ,  C10G67/04 ,  B01J27/045 ,  B01J27/049 ,  B01J29/74 ,  B01J35/00 ,  B01J29/85 ,  C10M177/00 ,  C10G45/58 ,  C10G65/04 ,  B01J29/70 ,  B01J29/44 ,  B01J29/22 ,  B01J27/051 ,  C10G59/06

CPC classification number: C10G67/0454 ,  B01J27/045 ,  B01J27/049 ,  B01J27/051 ,  B01J29/12 ,  B01J29/22 ,  B01J29/44 ,  B01J29/7084 ,  B01J29/7415 ,  B01J29/7461 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/85 ,  B01J35/0006 ,  B01J35/0093 ,  C10G45/58 ,  C10G59/06 ,  C10G65/043 ,  C10G67/02 ,  C10G67/0463 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/206 ,  C10G2300/302 ,  C10G2300/4018 ,  C10G2400/10 ,  C10M101/02 ,  C10M177/00 ,  C10M2203/1006 ,  C10N2270/00

Abstract: The present invention relates to a method for preparing lubricating base oils by using vacuum distilled deasphalted oil, and more specifically, to a method for preparing various kinds of lubricating base oils by distilling a distillate obtained from a solvent deasphalting (SDA) process under reduced pressure to obtain heavy deasphalted oil (H-DAO) and light deasphalted (Lt-DAO) and then treating the H-DAO and the Lt-DAO by catalytic reactions, respectively. According to the present invention, it is possible to obtain heavy lubricating base oil (150BS) of a high viscosity grade which can not be obtained by a known catalytic reaction and a lubricating base oil of group III by hydrogenation, in a high yield, and thus economical efficiency is excellent.

Abstract translation: 本发明涉及一种使用真空蒸馏的脱沥青油制备润滑基础油的方法，更具体地说，涉及通过在减压下蒸馏由溶剂脱沥青（SDA）方法获得的馏出物制备各种润滑基础油的方法 得到重质脱沥青油（H-DAO）和轻质脱沥青（Lt-DAO），然后分别通过催化反应处理H-DAO和Lt-DAO。 根据本发明，可以通过氢化得到高粘度等级的重质润滑基础油（150BS），其通过已知的催化反应和润滑基础油以高收率得到，并且 从而经济效益极佳。

公开(公告)号：US20140179967A1

公开(公告)日：2014-06-26

申请号：US14234529

申请日：2012-07-25

Applicant: Sang Il Lee ,  Do Woan Kim ,  Hyuck Jae Lee ,  Sang Hun Oh ,  Jae Hyun Koh ,  Sun Choi ,  Seung Hoon Oh ,  Byeung Soo Lim ,  Yong Seung Kim ,  Gyung Rok Kim ,  Young Moo Park ,  Jong Su Lee

Inventor： Sang Il Lee ,  Do Woan Kim ,  Hyuck Jae Lee ,  Sang Hun Oh ,  Jae Hyun Koh ,  Sun Choi ,  Seung Hoon Oh ,  Byeung Soo Lim ,  Yong Seung Kim ,  Gyung Rok Kim ,  Young Moo Park ,  Jong Su Lee

IPC: C07C1/207

CPC classification number: C07C1/2078 ,  B01J21/16 ,  B01J21/18 ,  B01J23/28 ,  B01J23/30 ,  B01J23/462 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/882 ,  B01J23/883 ,  B01J23/885 ,  B01J23/888 ,  B01J27/045 ,  B01J27/047 ,  B01J27/049 ,  B01J27/051 ,  B01J27/1853 ,  B01J27/188 ,  B01J27/19 ,  B01J29/076 ,  B01J37/0201 ,  B01J37/18 ,  B01J37/20 ,  B01J2229/186 ,  C07C1/20 ,  C07C7/04 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2521/16 ,  C07C2523/20 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/72 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/882 ,  C07C2523/883 ,  C07C2523/885 ,  C07C2523/888 ,  C07C2527/02 ,  C07C2527/043 ,  C07C2527/045 ,  C07C2527/167 ,  C07C2527/185 ,  C07C2527/188 ,  C07C2527/19 ,  C07C2529/70 ,  C10G3/42 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/48 ,  C10G3/49 ,  C10G3/50 ,  C10G2400/30 ,  Y02P20/52 ,  Y02P20/582 ,  C07C15/04 ,  C07C15/06 ,  C07C15/08

Abstract: This invention relates to a method of producing an aromatic hydrocarbon compound from byproducts of aromatic carboxylic acid and/or aromatic carboxylic acid alkylester preparation processes using hydroprocessing under conditions of high temperature and high hydrogen pressure in the presence of a catalyst, and to a hydroprocessing catalyst used therein.

Abstract translation: 本发明涉及一种在催化剂存在下，在高温高氢气条件下使用加氢处理的芳香族羧酸和/或芳香族羧酸烷基酯制备方法的副产物的芳香族烃化合物的制造方法，以及加氢处理催化剂 在其中使用。