Abstract:
A vapor phase process for producing a fluorinated alcohol, such as 2,2,2-trifluoroethanol via oxidation of an hydrofluorocarbon, such as 1,1,1-trifluoroethane, with an oxidizing agent and elemental fluorine.
Abstract:
The invention relates to a cost effective and convenient process for the manufacture of fluorinated olefins of the formula RCF.sub.2 CH=CH.sub.2 where R is C.sub.x Cl.sub.y F.sub.z and y+z=2.times.+1. The invention is also directed to a lo practical process for converting these olefins to hydrofluorocarbons via the catalyzed fluorination with hydrogen fluoride. Hydrofluorocarbons produced via this process have application as solvents among other uses.
Abstract translation:本发明涉及用于制造式RCF 2 CH = CH 2的氟化烯烃的成本有效和方便的方法,其中R是C x Cly F z且y + z = 2x + 1。 本发明还涉及通过氟化氢的催化氟化将这些烯烃转化为氢氟烃的实际方法。 通过该方法生产的氢氟烃可用作其他用途的溶剂。
Abstract:
The preparation of halosilanes having mixed-halogen substituents is described comprising providing an aryl-halo-silane having one more first halogens and one or more aryl groups, and substituting one or more of said aryl groups of said aryl-halo-silane with a second halogen having an atomic number greater than that of said first halogen.
Abstract:
A process for producing a fluorinated organic compound comprising: (a) reacting an organic starting material with hydrogen fluoride in the presence of a fluorination catalyst and an HFC reaction solvent to produce a product stream containing the fluorinated organic compound wherein the reaction solvent has a boiling point higher than that of the fluorinated organic compound; and (b) recovering the fluorinated organic compound from the product stream.
Abstract:
The invention relates to novel azeotrope-like compositions of 1-bromopropane, 4-methoxy-1,1,1,2,2,3,3,4,4-nonafluorobutane (HFE-7100) and at least one organic solvent selected from the group consisting of methanol, ethanol, 2-propanol, 2-methyl-2-propanol, tetrahydrofuran, nitromethane, and methylene chloride and more particularly to azeotrope-like compositions based on these compounds which are useful as solvents in refrigeration flushing, oxygen system cleaning and vapor degreasing applications.
Abstract:
A process for the catalytic fluorination of hydrochlorocarbons and hydrochlorofluorocarbons in the liquid phase. The process is useful for fluorinating hydrochloropropanes, hydrochlorofluoropropanes, hydrochloropropenes and hydrochlorofluoropropenes and most particularly useful for fluorinating 1,1,1,3,3-pentachloropropane to 1,1,1,3,3-pentafloropropane. Suitable catalysts include (i) a pentavalent molybdenum halide; (ii) a tetravalent tin halide; (iii) a tetravalent titanium halide; (iv) a mixture of a pentavalent tantalum halide with a tetravalent tin halide; (v) a mixture of a pentavalent tantalum halide with a tetravalent titanium halide; (vi) a mixture of a pentavalent niobium halide with a tetravalent tin halide; (vii) a mixture of a pentavalent niobium halide with a tetravalent titanium halide; (viii) a mixture of a pentavalent antimony halide with a tetravalent tin halide; (ix) a mixture of a pentavalent antimony halide with a tetravalent titanium halide; (x) a mixture of a pentavalent molybdenum halide with a tetravalent tin halide; (xi) a mixture of a pentavalent molybdenum halide with a tetravalent titanium halide and (xii) a mixture of a pentavalent antimony halide with a trivalent antimony halide. Products of this process are useful in a variety of applications including solvents, blowing agents, and refrigerants.
Abstract:
A process for preparing 1,1,1,3,3-pentafluoropropane from a hydrochlorocarbon of the formula C.sub.3 H.sub.y Cl.sub.x, wherein x is an integer from 3 to 5, y is an integer from 1 to 3, x+y=4, 6, or 8, and x-y=2 is provided.
Abstract translation:一种从式C 3 H y Cl x的氢氯烃制备1,1,1,3,3-五氟丙烷的方法,其中x为3至5的整数,y为1至3的整数,x + y = 4,6, 或8,并且xy = 2。
Abstract:
A process for producing a fluorinated olefin having the formula: CH.sub.3-a F.sub.a CH.dbd.CHCl where a=1,2 or 3, said process comprising catalytically reacting a chlorinated organic compound with a fluorination agent under conditions sufficient to form said hydrofluorocarbon compound, said chlorinated organic compound having the formula: CH.sub.b Cl.sub.c F.sub.d CH.sub.e CHCl.sub.e where b=0, 1 or 2; c=0, 1, 2, or 3; d=0, 1, 2 or 3; and e=1 or 2 with the provisos that b+c+d=3, c+e>1 and b+e
Abstract translation:一种制备具有下式的CH3-aFaCH = CHCl的氟化烯烃的方法,其中a = 1,2或3,所述方法包括在足以形成所述氢氟烃化合物的条件下将氯化有机化合物与氟化剂催化反应,所述氯化有机物 具有下式的化合物:CHbClcFdCHeCHCle其中b = 0,1或2; c = 0,1,2或3; d = 0,1,2或3; e = 1或2,条件是b + c + d = 3,c + e> 1,b + e <4。
Abstract:
A process for the preparation of a fluorinated acid such as trifluoroacetic acid, including admixing an hydrofluorocarbon, such as 1,1,1-trifluoroethane, with chlorine, an oxidizing agent and an additive to prevent or minimize decomposition; and irradiating the reaction mixture with a light source having a wavelength ranging from 2000 .ANG. to 14000 .ANG..
Abstract:
The invention relates to a cost effective and convenient process for the manufacture of fluorinated olefins of the formula RCF.sub.2 CH.dbd.CH.sub.2 where R is C.sub.x Cl.sub.y F.sub.z and y+z=2x+1. The invention is also directed to a practical process for converting these olefins to hydrofluorocarbons via the catalyzed fluorination with hydrogen fluoride. Hydrofluorocarbons produced via this process have application as solvents among other uses.