Method of producing fluorinated organic compounds
    14.
    发明授权
    Method of producing fluorinated organic compounds 失效
    氟化有机化合物的制备方法

    公开(公告)号:US6080899A

    公开(公告)日:2000-06-27

    申请号:US236880

    申请日:1999-01-25

    CPC classification number: C07C17/206

    Abstract: A process for producing a fluorinated organic compound comprising: (a) reacting an organic starting material with hydrogen fluoride in the presence of a fluorination catalyst and an HFC reaction solvent to produce a product stream containing the fluorinated organic compound wherein the reaction solvent has a boiling point higher than that of the fluorinated organic compound; and (b) recovering the fluorinated organic compound from the product stream.

    Abstract translation: 一种氟化有机化合物的制造方法,其特征在于,包括:(a)在氟化催化剂和HFC反应溶剂的存在下,使有机原料与氟化氢反应,制造含有氟化有机化合物的产物流,其中,反应溶剂为沸点 高于氟化有机化合物; 和(b)从产物流中回收氟化有机化合物。

    Liquid phase catalytic fluorination of hydrochlorocarbon and
hydrochlorofluorocarbon
    16.
    发明授权
    Liquid phase catalytic fluorination of hydrochlorocarbon and hydrochlorofluorocarbon 失效
    液相催化氟化氟氯烃和氢氯氟烃

    公开(公告)号:US6023004A

    公开(公告)日:2000-02-08

    申请号:US744157

    申请日:1996-11-12

    Abstract: A process for the catalytic fluorination of hydrochlorocarbons and hydrochlorofluorocarbons in the liquid phase. The process is useful for fluorinating hydrochloropropanes, hydrochlorofluoropropanes, hydrochloropropenes and hydrochlorofluoropropenes and most particularly useful for fluorinating 1,1,1,3,3-pentachloropropane to 1,1,1,3,3-pentafloropropane. Suitable catalysts include (i) a pentavalent molybdenum halide; (ii) a tetravalent tin halide; (iii) a tetravalent titanium halide; (iv) a mixture of a pentavalent tantalum halide with a tetravalent tin halide; (v) a mixture of a pentavalent tantalum halide with a tetravalent titanium halide; (vi) a mixture of a pentavalent niobium halide with a tetravalent tin halide; (vii) a mixture of a pentavalent niobium halide with a tetravalent titanium halide; (viii) a mixture of a pentavalent antimony halide with a tetravalent tin halide; (ix) a mixture of a pentavalent antimony halide with a tetravalent titanium halide; (x) a mixture of a pentavalent molybdenum halide with a tetravalent tin halide; (xi) a mixture of a pentavalent molybdenum halide with a tetravalent titanium halide and (xii) a mixture of a pentavalent antimony halide with a trivalent antimony halide. Products of this process are useful in a variety of applications including solvents, blowing agents, and refrigerants.

    Abstract translation: 在液相中氢氯碳氢化合物和氢氯氟烃的催化氟化的方法。 该方法可用于氟化氢氯丙烷,氢氯氟丙烷,氢氯丙烯和氢氯氟丙烯,最特别用于将1,1,1,3,3-五氯丙烷氟化为1,1,1,3,3-五氟丙烷。 合适的催化剂包括(i)五价钼卤化物; (ii)四价卤化锡; (iii)四价钛卤化物; (iv)五价卤化钽与四价卤化锡的混合物; (v)五价钽卤化物与四价钛卤化物的混合物; (vi)五价铌卤化物与四价卤化锡的混合物; (vii)五价铌卤化物与四价钛卤化物的混合物; (viii)五价锑卤化物与四价卤化锡的混合物; (ix)五价锑卤化物与四价钛卤化物的混合物; (x)五价钼卤化物与四价卤化锡的混合物; (xi)五价钼卤化物与四价卤化钛的混合物,(xii)五价锑卤化物与三价卤化锑的混合物。 该方法的产品可用于各种应用,包括溶剂,发泡剂和制冷剂。

    Preparation of fluoroalkyl compounds and their derivatives
    18.
    发明授权
    Preparation of fluoroalkyl compounds and their derivatives 失效
    氟烷基化合物及其衍生物的制备

    公开(公告)号:US5777184A

    公开(公告)日:1998-07-07

    申请号:US882061

    申请日:1997-06-25

    CPC classification number: C07C45/54 C07C17/00 C07C29/149 C07C67/11

    Abstract: A process for producing a fluorinated olefin having the formula: CH.sub.3-a F.sub.a CH.dbd.CHCl where a=1,2 or 3, said process comprising catalytically reacting a chlorinated organic compound with a fluorination agent under conditions sufficient to form said hydrofluorocarbon compound, said chlorinated organic compound having the formula: CH.sub.b Cl.sub.c F.sub.d CH.sub.e CHCl.sub.e where b=0, 1 or 2; c=0, 1, 2, or 3; d=0, 1, 2 or 3; and e=1 or 2 with the provisos that b+c+d=3, c+e>1 and b+e

    Abstract translation: 一种制备具有下式的CH3-aFaCH = CHCl的氟化烯烃的方法,其中a = 1,2或3,所述方法包括在足以形成所述氢氟烃化合物的条件下将氯化有机化合物与氟化剂催化反应,所述氯化有机物 具有下式的化合物:CHbClcFdCHeCHCle其中b = 0,1或2; c = 0,1,2或3; d = 0,1,2或3; e = 1或2,条件是b + c + d = 3,c + e> 1,b + e <4。

    Process for the preparation of a fluorinated acid
    19.
    发明授权
    Process for the preparation of a fluorinated acid 失效
    制备氟化酸的方法

    公开(公告)号:US5736012A

    公开(公告)日:1998-04-07

    申请号:US711774

    申请日:1996-09-10

    CPC classification number: C07C51/215

    Abstract: A process for the preparation of a fluorinated acid such as trifluoroacetic acid, including admixing an hydrofluorocarbon, such as 1,1,1-trifluoroethane, with chlorine, an oxidizing agent and an additive to prevent or minimize decomposition; and irradiating the reaction mixture with a light source having a wavelength ranging from 2000 .ANG. to 14000 .ANG..

    Abstract translation: 一种制备氟化酸如三氟乙酸的方法,包括将氢氟烃如1,1,1-三氟乙烷与氯,氧化剂和添加剂混合以防止或最小化分解; 并用波长范围从2000安格到14000埃的光源照射反应混合物。

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