公开(公告)号：US08652244B2

公开(公告)日：2014-02-18

申请号：US13078152

申请日：2011-04-01

申请人： David Nalewajek ,  Andrew Joseph Poss ,  Rajiv Ratna Singh ,  Cheryl Cantlon

发明人： David Nalewajek ,  Andrew Joseph Poss ,  Rajiv Ratna Singh ,  Cheryl Cantlon

IPC分类号： C09D13/00 ,  A61B5/103 ,  A61B5/117 ,  C09D11/00

CPC分类号： G03C1/73 ,  A61B5/117 ,  G06K2009/00946

摘要： Developing compositions are provided herein for use in producing a visibly detectable image of a latent physiological biometric. The developing compositions include a carrier solvent that includes at least one C3-C4 hydrofluorocarbon olefin or at least one hydrochlorofluorocarbon olefin.

摘要翻译： 本文提供显影组合物用于产生潜在生理学的可见可检测图像。 显影组合物包括载体溶剂，其包含至少一种C 3 -C 4氢氟烃烯烃或至少一种氢氯氟烃烯烃。

公开(公告)号：US08524955B2

公开(公告)日：2013-09-03

申请号：US13110974

申请日：2011-05-19

申请人： Andrew Joseph Poss ,  David Nalewajek ,  Haridasan K. Nair ,  Michael Van Der Puy ,  Rajiv Ratna Singh

发明人： Andrew Joseph Poss ,  David Nalewajek ,  Haridasan K. Nair ,  Michael Van Der Puy ,  Rajiv Ratna Singh

IPC分类号： C07C17/093

CPC分类号： C07C17/354 ,  C07C17/23 ,  C07C17/37 ,  C07C21/22 ,  C07C21/18 ,  C07C21/09

摘要： Disclosed is a process for making hexafluoro-2-butyne comprising the steps of: (a) providing a composition comprising CF3CX═CXCF3, where X=halogen; and (b) treating CF3CX═CXCF3 with a dehalogenation catalyst in the presence of a halogen acceptor compound Y, where Y is not hydrogen. The halogen acceptor compound Y is a material capable of being halogenated, preferably a compound having a multiple bond, such as an alkyne, alkene, allene, or carbon monoxide. Another suitable material capable of being halogenated is a cyclopropane. A catalyst effectively transfers halogen from CF3CX═CXCF3 to the halogen acceptor compound. Since Y is not hydrogen, the formation of CF3CX═CHCF3 is greatly reduced or eliminated.

摘要翻译： 公开了制备六氟-2-丁炔的方法，包括以下步骤：（a）提供包含CF 3 C X = CXCF 3的组合物，其中X =卤素; 和（b）在卤素受体化合物Y的存在下用脱卤催化剂处理CF 3 C X = CXCF 3，其中Y不是氢。 卤素受体化合物Y是能够被卤化的物质，优选具有多重键的化合物，如炔烃，烯烃，烯烃或一氧化碳。 能够被卤化的另一种合适的材料是环丙烷。 催化剂有效地将卤素从CF 3 C X = CXCF 3转移到卤素受体化合物。 由于Y不是氢，CF3CX = CHCF3的形成大大降低或消除。

公开(公告)号：US20130038896A1

公开(公告)日：2013-02-14

申请号：US13205090

申请日：2011-08-08

申请人： Jonathan David Nalewajek

发明人： Jonathan David Nalewajek

IPC分类号： G06F3/12

CPC分类号： G06F3/1206 ,  G06F3/1204 ,  G06F3/122 ,  G06F3/1225 ,  G06F3/1247 ,  G06F3/1267 ,  G06F3/1284 ,  G06F3/1292

摘要： In accordance with aspects of the present disclosure, a method, product, apparatus and system is disclosed. The method includes coupling a print device to a printer, wherein the print device comprises a memory arranged to store information including a printer driver associated with the printer; coupling a mobile device to the print device; receiving a document stored on the mobile device; converting the document to a format suitable to be printed by the printer using the print driver; and transmitting, by a transmitter, the document to the printer.

摘要翻译： 根据本公开的方面，公开了一种方法，产品，装置和系统。 该方法包括将打印设备耦合到打印机，其中打印设备包括布置成存储包括与打印机相关联的打印机驱动程序的信息的存储器; 将移动设备耦合到所述打印设备; 接收存储在移动设备上的文档; 将文档转换成适合于打印机使用打印驱动程序打印的格式; 并且由发射机将文件发送到打印机。

公开(公告)号：US20090149681A1

公开(公告)日：2009-06-11

申请号：US12263848

申请日：2008-11-03

申请人： David E. Bradley ,  David Nalewajek ,  Robert L. Bell

发明人： David E. Bradley ,  David Nalewajek ,  Robert L. Bell

IPC分类号： C07C19/08

CPC分类号： C07C17/206 ,  C07C17/21 ,  C07C19/08

摘要： A process for the production of C2-C4 hydrofluorocarbon, such as 1,1,1,3,3-pentafluoropropane, by contacting a non-fluorinated hydrochlorocarbon with a fluorinating agent, such as hydrogen fluoride, in a liquid catalyst system preferably comprising fluorinated superacid catalyst prepared from SbF5, NbF5, TaF5 or TaF5/SnF4 and HF.

摘要翻译： 通过使非氟化氢氯烃与氟化氢如氟化氢接触，在液体催化剂体系中将C2-C4氢氟烃如1,1,1,3,3-五氟丙烷生产的方法优选包括含氟化合物 由SbF5，NbF5，TaF5或TaF5 / SnF4和HF制备的超强酸催化剂。

公开(公告)号：US07307137B2

公开(公告)日：2007-12-11

申请号：US10466651

申请日：2001-10-18

申请人： Kreisler Lau ,  Feng Quan Liu ,  Paul Apen ,  Boris Korolev ,  Emma Brouk ,  Ruslan Zherebin ,  David Nalewajek ,  Roger Leung

发明人： Kreisler Lau ,  Feng Quan Liu ,  Paul Apen ,  Boris Korolev ,  Emma Brouk ,  Ruslan Zherebin ,  David Nalewajek ,  Roger Leung

IPC分类号： C08G63/78

CPC分类号： C08G61/12 ,  C07C13/615 ,  C07C13/64 ,  C07C15/54 ,  C07C17/10 ,  C07C17/269 ,  C07C2603/74 ,  C07C2603/90 ,  C07F7/0805 ,  C08F238/00 ,  C08G61/02 ,  H01L2924/0002 ,  C07C23/46 ,  C07C25/22 ,  H01L2924/00

摘要： The present invention is directed to low dielectric polymers and to methods of producing these low dielectric constant polymers, dielectric materials and layers, and electronic components. In one aspect of the present invention, an isomeric mixture of thermosetting monomers, wherein the monomers have a core structure and a plurality of arms, is provided, and the isomeric mixture of thermosetting monomers is polymerized, wherein polymerization comprises a reaction of an ethynyl group that is located in at least one arm of a monomer. In yet another aspect of the inventive subject matter, spin-on low dielectric constant materials are formed having a first backbone with an aromatic moiety and a first reactive group, and a second backbone with an aromatic moiety and a second reactive group, wherein the first and second backbone are crosslinked via the first and second reactive groups in a crosslinking reaction preferably without an additional crosslinker, and wherein a cage structure having at least eight (8) atoms is covalently bound to at least one of the first and second backbone.

摘要翻译： 本发明涉及低介电聚合物以及生产这些低介电常数聚合物，介电材料和层以及电子元件的方法。 在本发明的一个方面，提供其中单体具有核心结构和多个臂的热固性单体的异构体混合物，并且热固性单体的异构体混合物聚合，其中聚合包括乙炔基 其位于单体的至少一个臂中。 在本发明主题的另一方面，形成旋涂低介电常数材料，其具有具有芳族部分和第一反应性基团的第一主链和具有芳族部分和第二反应性基团的第二主链，其中第一 并且第二主链在交联反应中通过第一和第二反应性基团交联，优选不含另外的交联剂，并且其中具有至少八个（8）原子的笼结构共价结合至第一和第二主链中的至少一个。

公开(公告)号：US20060122301A1

公开(公告)日：2006-06-08

申请号：US11006879

申请日：2004-12-08

申请人： Haridasan Nair ,  David Nalewajek

发明人： Haridasan Nair ,  David Nalewajek

IPC分类号： C08K3/26

CPC分类号： C08F216/125 ,  C07C41/06 ,  C07C43/17 ,  C07C43/172 ,  C07C2601/14

摘要： Fluorinated divinyl ethers having structures according to Formula I or II: RfCX═CY—O—Z—O—CH═CH2  (I) RfCX═CY—O—M—O—CY═CXRf  (II) wherein Rf is fluorine or a C1-C20 fluorinated alkyl; X and Y are independently hydrogen, a halogen, or a C1-C20 fluorinated alkylene; Z is a C1-C20 alkylene, C3-C10 cycloalkylene, four to ten ring member aromatic and non-aromatic heterocycloalkylene, C6-C15 arylene, or C7-C20 arylalkylene; and M is a C1-C20 alkylene, C3-C18 fluorinated alkylene provided that the chain does not terminate with -CHF- or -CF2-, or a C3-C18 diol having the formula —HO—CH2—(CF2)n—CH2—OH— wherein n is an integer from 1 to 16. Curable compositions, polymers, films, coatings, and optical devices comprising fluorinated divinyl ether compounds are also disclosed as well as processes for producing optical devices from the fluorinated divinyl ether compounds and processes for producing the fluorinated divinyl ethers.

摘要翻译： 具有根据式I或II的结构的氟化二乙烯基醚：<？in-line-formula description =“In-line Formulas”end =“lead”？> R CX-CY-OZO-CH -CH 2（I）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas” end =“lead”？> R CX-CY-OMO-CY-CXR （II）<？in-line-formula description =“In-Line Formulas “end =”tail“？>其中R 1是氟或C 1 -C 20氟代烷基; X和Y独立地是氢，卤素或C 1 -C 20氟代亚烷基; Z是C 1 -C 20亚烷基，C 3 -C 10亚环烷基，4至10个环成员 芳族和非芳族杂环亚烷基，C 6 -C 15亚芳基或C 7 -C 20芳基亚烷基; 并且M是C 1 -C 20亚烷基，C 3 -C 18氟化亚烷基，条件是链 不用-CHF-或-CF 2 - 或具有式-HO-CH 2的C 3 -C 18二醇终止， 其中n是1至16的整数。（2）其中n是1至16的整数。 还公开了包含氟化二乙烯基醚化合物的可固化组合物，聚合物，膜，涂料和光学装置，以及从氟化二乙烯基醚化合物生产光学器件的方法和用于生产氟化二乙烯基醚的方法。

公开(公告)号：US20050107246A1

公开(公告)日：2005-05-19

申请号：US10965576

申请日：2004-10-14

申请人： Raymond H. Thomas ,  Roy Robinson ,  David Nalewajek ,  Kane Cook

发明人： Raymond H. Thomas ,  Roy Robinson ,  David Nalewajek ,  Kane Cook

IPC分类号： C08F4/645 ,  B01J31/22 ,  B01J37/03 ,  C08F4/6592 ,  B01J31/00

CPC分类号： B01J31/14 ,  B01J21/04 ,  B01J21/08 ,  B01J31/146 ,  B01J31/1616 ,  B01J31/2295 ,  B01J37/031 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  B01J2531/842 ,  C08F4/025 ,  C08F4/65908 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  Y02P20/544 ,  C08F4/65916

摘要： Disclosed are methods of producing supported organic catalyst systems which find particular use in polymerization reactions. The methods comprise generally, the steps of (a) providing an organic catalyst solution comprising an organic catalyst dissolved in a solvent; (b) contacting the organic catalyst solution with a solid support material; and (c) removing the solvent from the support material by using one or more supercritical-like solvents.

公开(公告)号：US06743943B2

公开(公告)日：2004-06-01

申请号：US09854244

申请日：2001-05-11

申请人： Russell F. Anderson ,  David E. Bradley ,  David Nalewajek ,  Haridasan K. Nair ,  Mariola J. Proszowski ,  Eugene V. Sitzman ,  Ellen L. Swan

发明人： Russell F. Anderson ,  David E. Bradley ,  David Nalewajek ,  Haridasan K. Nair ,  Mariola J. Proszowski ,  Eugene V. Sitzman ,  Ellen L. Swan

IPC分类号： C07C6934

CPC分类号： C07C43/17 ,  C07C43/172 ,  C07C43/176 ,  C07C69/63 ,  C07C309/73 ,  C07C2601/14 ,  C08F8/18 ,  C08F16/26 ,  C09D11/101 ,  C09D129/10 ,  C09J4/00 ,  C09J129/10 ,  G02B6/1221 ,  G02B6/13 ,  G11B7/2531 ,  G11B7/2532 ,  G11B7/2533 ,  G11B7/2542 ,  G11B7/2545 ,  G11B7/256 ,  G11B7/2572 ,  C08F216/125

摘要： Vinyl ether compounds having the formula: R—O—X—O—CH═CH2 wherein R is a radical selected from R1—CnHm—, R1—CnHm—C(═O)—, R1—CnHm—CH[—O—X—O—CH═CH2—], R1—CnHm—CH[—O—X—O—CH═CH2—]C(═O)—, R1—CnHm—CH[—C(═O)—O—X—O—CH═CH2—], R1—CnHm—CH[—C(═O)—O—X—O—CH═CH2—]C(═O)—, R1—[CFCl—CF2—]pCH2— and HCFCl—CF2—, wherein R1 is hydrogen, an unsubstituted or substituted fluorinated aliphatic radical, an unsubstituted or substituted fluorinated cyclic aliphatic radical, an unsubstituted or substituted fluorinated aromatic radical, an unsubstituted or substituted fluorinated araliphatic radical, or an unsubstituted or substituted fluorinated heterocyclic radical; n is an integer between 1 and 6, inclusive; n≦m≦2n; p is an integer between 1 and 20, inclusive and X is an unsubstituted or substituted aliphatic radical, an unsubstituted or substituted cyclic aliphatic radical, an unsubstituted or substituted aromatic radical, an unsubstituted or substituted araliphatic radical, or an unsubstituted or substituted heterocyclic radical; provided that when R1 of R1—CnHm— is an otherwise unsubstituted fluorinated aliphatic group, X is not ethylene or propylene. Curable compositions containing the vinyl ether compounds are also disclosed, as well as polymers polymerized from the vinyl ether compounds.

摘要翻译： 具有下式的乙烯基醚化合物：其中R是选自R1-CnHm-，R1-CnHm-C（= O） - ，R1-CnHm-CH [-OXO-CH = CH2-]，R1-CnHm-CH [-OXO-CH = CH2-] C（= O） - ，R1-CnHm-CH [-C（= O）-OXO-CH = CH2-]，R1-CnHm-CH [-C（= O） OXO-CH = CH 2 - ] C（= O） - ，R 1 - [CFCl-CF 2 - ] pCH 2 - 和HCFCl-CF 2 - ，其中R 1是氢，未取代或取代的氟化脂族基，未取代或取代的氟代环状脂族 基团，未取代或取代的氟化芳族基团，未取代或取代的氟化芳脂族基团，或未取代或取代的氟化杂环基团; n是1和6之间的整数，包括1和6; n <= m <= 2n; p是1至20的整数，包括1和20，X是未取代或取代的脂族基团，未取代或取代的环状脂族基团，未取代或取代的芳族基团，未取代或取代的芳脂族基团，或未取代或取代的杂环基团; 条件是当R1-CnHm-的R1是另外未被取代的氟代脂族基团时，X不是乙烯或丙烯。 还公开了含有乙烯基醚化合物的可固化组合物，以及由乙烯基醚化合物聚合的聚合物。

公开(公告)号：US06486114B2

公开(公告)日：2002-11-26

申请号：US09167000

申请日：1998-09-28

申请人： David Nalewajek ,  Earl A. E. Lund ,  David P. Wilson

发明人： David Nalewajek ,  Earl A. E. Lund ,  David P. Wilson

IPC分类号： C09K504

CPC分类号： C09K5/045 ,  C08J9/14 ,  C09K2205/128 ,  C09K2205/132 ,  C09K2205/22 ,  C09K2205/32

摘要： Azeotrope-like compositions comprising pentafluoropropane and a perfluorocarbon having 5 to 7 carbon atoms or N-methylperfluoromorpholine OR N-ethylperfluoromorpholine are stable and have utility as refrigerants for heating and cooling, blowing agents, solvents and fire extinguishing agents.

摘要翻译： 包含五氟丙烷和5-7个碳原子的全氟化碳或N-甲基双氟吗啉或N-乙基双氟吗啉的类共沸组合物是稳定的，可用作加热和冷却的制冷剂，发泡剂，溶剂和灭火剂。

公开(公告)号：US06291704B1

公开(公告)日：2001-09-18

申请号：US09271650

申请日：1999-03-18

申请人： Russell F. Anderson ,  David E. Bradley ,  David Nalewajek ,  Haridasan K. Nair ,  Mariola J. Proszowski ,  Eugene V. Sitzman ,  Ellen L. Swan

发明人： Russell F. Anderson ,  David E. Bradley ,  David Nalewajek ,  Haridasan K. Nair ,  Mariola J. Proszowski ,  Eugene V. Sitzman ,  Ellen L. Swan

IPC分类号： C07C6963

CPC分类号： C07C43/17 ,  C07C43/172 ,  C07C43/176 ,  C07C69/63 ,  C07C309/73 ,  C07C2601/14 ,  C08F8/18 ,  C08F16/26 ,  C09D11/101 ,  C09D129/10 ,  C09J4/00 ,  C09J129/10 ,  G02B6/1221 ,  G02B6/13 ,  G11B7/2531 ,  G11B7/2532 ,  G11B7/2533 ,  G11B7/2542 ,  G11B7/2545 ,  G11B7/256 ,  G11B7/2572 ,  C08F216/125

摘要： Vinyl ether compounds having the formula: R—O—X—O—CH═CH2 wherein R is a radical selected from R1—CnHm—, R1—CnHm—C(═O)—, R1—CnHm—CH[—O—X—O—CH═CH2—], R1—CnHm—CH[—O—X—O—CH═CH2—]C(═O)—, R1—CnHm—CH[—C(═O)—O—X—O—CH═CH2—], R1—CnHm—CH[—C(═O)—O—X—0—CH═CH2—]C(═O)—, R1—[CFCl—CF2—]pCH2— and HCFCl—CF2—, wherein R1 is hydrogen, an unsubstituted or substituted fluorinated aliphatic radical, an unsubstituted or substituted fluorinated cyclic aliphatic radical, an unsubstituted or substituted fluorinated aromatic radical, an unsubstituted or substituted fluorinated araliphatic radical, or an unsubstituted or substituted fluorinated heterocyclic radical; n is an integer between 1 and 6, inclusive; n≦m≦2n; p is an integer between 1 and 20, inclusive and X is an unsubstituted or substituted aliphatic radical, an unsubstituted or substituted cyclic aliphatic radical, an unsubstituted or substituted aromatic radical, an unsubstituted or substituted araliphatic radical, or an unsubstituted or substituted heterocyclic radical; provided that when R1 of R1—CnHm— is an otherwise unsubstituted fluorinated aliphatic group, X is not ethylene or propylene. Curable compositions containing the vinyl ether compounds are also disclosed, as well as polymers polymerized from the vinyl ether compounds.

摘要翻译： 具有下式的乙烯基醚化合物：其中R是选自R1-CnHm-，R1-CnHm-C（= O） - ，R1-CnHm-CH [-OXO-CH = CH2-]，R1-CnHm-CH [-OXO-CH = CH2-] C（= O） - ，R1-CnHm-CH [-C（= O）-OXO-CH = CH2-]，R1-CnHm-CH [-C（= O） OX-0-CH = CH 2 - ] C（= O） - ，R 1 - [CFCl-CF 2 - ] pCH 2 - 和HCFCl-CF 2 - ，其中R 1是氢，未取代或取代的氟化脂族基团，未取代或取代的氟化 未取代或取代的氟化芳族基团，未取代或取代的氟化芳脂族基团，或未取代或取代的氟化杂环基团; n是1和6之间的整数，包括1和6; n <= m <= 2n; p是1至20的整数，包括1和20，X是未取代或取代的脂族基团，未取代或取代的环状脂族基团，未取代或取代的芳族基团，未取代或取代的芳脂族基团，或未取代或取代的杂环基团; 条件是当R1-CnHm-的R1是另外未被取代的氟代脂族基团时，X不是乙烯或丙烯。 还公开了含有乙烯基醚化合物的固化组合物以及由乙烯基醚化合物聚合的聚合物。