Abstract:
The present invention relates to a tire with a colored sidewall joined with a plurality of colored grooves in its tread. In particular, the present invention relates to a tire of a black-colored rubber composition having a non-black colored sidewall portion which is integral with a plurality of non-black colored grooves of a tread of lug and groove configuration. For said tread, at least a portion of the visible surface of a plurality of tread grooves, exclusive of the outer surface portion of said carbon black reinforced rubber lugs intended to be ground-contacting, is of a non-black colored, synthetic amorphous silica reinforced rubber composition exclusive of carbon black. For said colored sidewall and plurality of connecting tread groove combination, said tread groove and sidewall may be of the same or different non-black color(s). In one aspect, said non-black visible surface of said tread grooves and connecting sidewall contains an elastomeric brominated copolymer of isobutylene and p-methyl styrene in combination with an organo phosphite compound.
Abstract:
This invention relates to a pneumatic tire having a built-in sealant layer and its preparation. The sealant layer precursor is a layer of a butyl rubber based composition which contains an organoperoxide. The butyl rubber of said precursor is a copolymer of isobutylene and isoprene containing from about 0.5 to about 5, alternately less than 1, mole percent isoprene. The precursor composition contains carbon black and/or coal dust and may contain a dispersion of liquid conjugated diene polymer (e.g. liquid cis 1,4-polyisoprene polymer), short fibers and/or hollow glass microspheres. A layer of the sealant precursor is built into the tire between a sulfur vulcanized halobutyl rubber innerliner and conjugated diene-based rubber of the tire carcass. The butyl rubber of the sealant precursor is partially depolymerized by the organoperoxide during the elevated temperature vulcanization of the tire to form the built-in sealant layer. In one aspect of the invention, said uncured butyl rubber sealant precursor layer composition has a storage modulus G′ (80° C.) in a range of about 100 to about 400 kPa and said partially depolymerized butyl rubber sealant layer composition has a storage modulus G′ (80° C.) in range of about 5 to about 50 kPa.