公开(公告)号：US5103060A

公开(公告)日：1992-04-07

申请号：US571286

申请日：1990-08-23

Applicant: Wolfgang Brox ,  Dirk Funhoff ,  Ulrike Licht ,  Harald Fuchs ,  Wolfgang Schrepp

Inventor： Wolfgang Brox ,  Dirk Funhoff ,  Ulrike Licht ,  Harald Fuchs ,  Wolfgang Schrepp

IPC: G02F1/35 ,  C07C211/48 ,  C07C211/52 ,  C07C245/08 ,  C07C251/24 ,  C07C251/86 ,  C07C255/58 ,  C07C323/37 ,  C07D213/24 ,  C07D251/24 ,  C08F16/14 ,  C08F16/28 ,  C08F26/00 ,  C08F26/02 ,  C08F28/00 ,  C08F28/02 ,  G02F1/355 ,  G02F1/361

CPC classification number: C07C245/08 ,  C07C211/48 ,  C07C211/52 ,  C07C255/58 ,  G02F1/3611 ,  G02F1/3617 ,  C07C2101/10

Abstract: The novel compounds of the general formula I ##STR1## where X is straight-chain or branched alkanediyl having from 1 to 20 carbon atoms orX is straight-chain or branched alkanediyl having from 2 to 20 carbon atoms, whose carbon chain is interrupted by --O--, --S-- and/or --NR--,R is hydrogen, straight-chain or branched alkyl having from 1 to 6 carbon atoms or cycloalkyl, andY is a non-centrosymmetric radical containing an easily polarized conjugated .pi.-electron system and at least one terminal electron-acceptor group,having nonlinear optical properties, are highly suitable as nonlinear optical materials for nonlinear optical arrangements and for the preparation of polymers having nonlinear optical properties. In particular, they can be used to prepare organopolysiloxanes having nonlinear optical properties and containing side groups of the general formula Ia ##STR2## in which the variables are as defined above. These novel organopolysiloxanes having nonlinear optical properties are also highly suitable for the production of Langmuir-Blodgett layers.

Abstract translation: 其中X是具有1至20个碳原子的直链或支链烷二基或X是具有2至20个碳原子的直链或支链烷二基的通式I（I）的新化合物，其碳链 被-O - ， - S-和/或-NR-中断，R是氢，具有1至6个碳原子的直链或支链烷基或环烷基，Y是含有易极化共轭的非中心对称基团 具有非线性光学性质的π-电子系统和至少一个末端电子受体基团非常适用于非线性光学布置的非线性光学材料和用于制备具有非线性光学性质的聚合物。 特别地，它们可以用于制备具有非线性光学性质并且包含其中变量如上所定义的通式Ia（Ia）的侧基的有机聚硅氧烷。 这些具有非线性光学性质的新型有机聚硅氧烷也非常适合于生产Langmuir-Blodgett层。

公开(公告)号：US5049462A

公开(公告)日：1991-09-17

申请号：US481299

申请日：1990-02-20

Applicant: Dirk Funhoff ,  Harald Fuchs ,  Ulrike Licht ,  Wolfgang Schrepp ,  Werner Hickel ,  Wolfgang Knoll ,  Gerhard Wegner ,  Gisela Duda

Inventor： Dirk Funhoff ,  Harald Fuchs ,  Ulrike Licht ,  Wolfgang Schrepp ,  Werner Hickel ,  Wolfgang Knoll ,  Gerhard Wegner ,  Gisela Duda

IPC: G11B7/00 ,  G11B7/005 ,  G11B7/24 ,  G11B7/244 ,  G11B7/245 ,  G11B11/00

CPC classification number: G11B11/00 ,  G11B7/245 ,  Y10S430/146 ,  Y10T428/31504

Abstract: Information stored in a thin polymer layer is read out in a process wherein information introduced into a thin polymer layer on a metallic or semiconductor layer by electromagnetic or particle rays which produce a permanent change in the properties of the polymer layer in the irradiated areas is read out using surface plasmons.

Abstract translation: 读取存储在薄聚合物层中的信息，其中读取通过电磁或粒子射线在金属或半导体层上引入聚合物层中的聚合物薄层的信息，这些信号在照射区域中产生聚合物层性质的永久性变化 使用表面等离子体激元。

公开(公告)号：US5846689A

公开(公告)日：1998-12-08

申请号：US708818

申请日：1996-09-09

Applicant: Reinhold Schwalm ,  Dirk Funhoff ,  Horst Binder

Inventor： Reinhold Schwalm ,  Dirk Funhoff ,  Horst Binder

IPC: G03F7/004 ,  G03F7/039 ,  H01L21/027

CPC classification number: G03F7/039 ,  G03F7/0045 ,  Y10S430/106

Abstract: A positive-working radiation-sensitive mixture essentially consists of (a) at least one polymer which contains acid-labile groups and is insoluble in water but becomes soluble in aqueous alkaline solutions as a result of the action of acid, (b) at least one organic compound which produces an acid under the action of actinic radiation and (c) at least one further organic compound differing from (b), where the polymer (a) contains incorporated units of the formulae (I), (II) and (III) ##STR1## and the organic compound (b) is a sulfonium salt of the formula (IV) ##STR2## The radiation-sensitive mixture is suitable for the production of relief structures having improved contrast.

Abstract translation: 正面工作的辐射敏感混合物基本上由（a）至少一种含有酸不稳定基团并且不溶于水但由于酸的作用而变得可溶于碱性水溶液的聚合物，（b）至少 一种在光化辐射作用下产生酸的有机化合物和（c）至少一种与（b）不同的另外的有机化合物，其中聚合物（a）含有式（I），（II）和（ III）和有机化合物（b）是式（IV）的锍盐。（IV）辐射敏感性混合物适用于生产具有改善的对比度的浮雕结构。

公开(公告)号：US5783354A

公开(公告)日：1998-07-21

申请号：US711016

申请日：1996-09-09

Applicant: Reinhold Schwalm ,  Dirk Funhoff ,  Horst Binder

Inventor： Reinhold Schwalm ,  Dirk Funhoff ,  Horst Binder

IPC: G03F7/004 ,  G03F7/039 ,  H01L21/027

CPC classification number: G03F7/0045 ,  G03F7/039 ,  Y10S430/106 ,  Y10S430/111

Abstract: A positive-working radiation-sensitive mixture essentially consists of (a.sub.1) at least one water-insoluble, organic polymeric binder which contains acid-labile groups and becomes soluble in aqueous alkaline solutions as a result of the action of acid, or (a.sub.2.1) a polymeric binder which is insoluble in water and soluble in aqueous alkaline solutions and (a.sub.2.2) a low molecular weight organic compound whose solubility and aqueous alkaline developer is increased as a result of the action of acid, and (b) at least one organic compound which produces an acid under the action of actinic radiation, and, if required, (c) one or more further organic compounds which differ from (b), at least one of the components (a.sub.1), (a.sub.2.1), (a.sub.2.2), (b) and (c) containing a bonded group of the general formula (I) --O.sup..crclbar. N.sup..sym. R.sub.4, or component (c) being of the formula (II) ##STR1## The radiation-sensitive mixture is suitable for the production of relief structures.

Abstract translation: 正面工作的辐射敏感混合物基本上由（a1）至少一种含有酸不稳定基团的水不溶性有机聚合物粘合剂组成，并且由于酸的作用而变得可溶于碱性水溶液，或（a2）。 1）聚合物粘合剂，其不溶于水并且可溶于碱性水溶液，和（a2.2）由于酸的作用，其溶解度和含水碱性显影剂增加的低分子量有机化合物，和（b）在 至少一种在光化辐射的作用下产生酸的有机化合物，如果需要，（c）一种或多种与（b），至少一种组分（a1），（a2.1）不同的其它有机化合物 ）（a）-O（ - ）N（+）R 4，或（c）成分为式（II）的键合基团的化合物（a2.2），（b）和（c） （II）辐射敏感混合物适用于浮雕结构的生产。

公开(公告)号：US5563022A

公开(公告)日：1996-10-08

申请号：US968408

申请日：1992-10-29

Applicant: Horst Binder ,  Reinhold Schwalm ,  Dirk Funhoff

Inventor： Horst Binder ,  Reinhold Schwalm ,  Dirk Funhoff

IPC: G03F7/004 ,  G03F7/039 ,  H01L21/027 ,  G03C1/492 ,  G03F7/30 ,  G03F7/38

CPC classification number: G03F7/0045 ,  Y10S430/106 ,  Y10S430/111 ,  Y10S430/122

Abstract: A positive-working UV-sensitive mixture containing(a1) an organic binder containing acid-labile ether, ester or carbonate groups or(a2) a polymeric binder which is insoluble in water but soluble in aqueous alkaline solutions and(a2.1) an organic compound whose solubility in an aqueous alkaline developer is increased by the action of an acid, or(a2.2) an organic compound whose solubility in an aqueous alkaline developer is increased by the action of an acid and which contains one or more acid-cleavable groups and in addition a group which forms an acid under the action of radiation, or a mixture of the organic compounds (a2.1) and (a2.2) and(b) an arylsulfonic ester, is suitable for the production of relief patterns.

Abstract translation: 含有（a1）含酸不稳定醚，酯或碳酸酯基团的有机粘合剂或（a2）不溶于水但可溶于碱性水溶液的聚合物粘合剂的正性UV敏感性混合物，（a2.1） 在水性碱性显影剂中的溶解度由酸的作用而增加的有机化合物，或（a2.2）其在碱性显影液中的溶解度在酸的作用下增加并且含有一种或多种酸 - 可裂解基团，另外还有在辐射作用下形成酸的基团，或有机化合物（a2.1）和（a2.2）和（b）芳基磺酸酯的混合物，适于生产浮雕 模式。

公开(公告)号：US5204178A

公开(公告)日：1993-04-20

申请号：US784427

申请日：1991-11-12

Applicant: Ulrike Licht ,  Harald Fuchs ,  Dirk Funhoff ,  Wolfgang Schrepp ,  Hans Schupp

Inventor： Ulrike Licht ,  Harald Fuchs ,  Dirk Funhoff ,  Wolfgang Schrepp ,  Hans Schupp

IPC: C08F220/36 ,  B05D1/20 ,  C08F20/34 ,  C08F20/52 ,  C08F220/34 ,  C08F220/60 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361

CPC classification number: C08F220/34 ,  B05D1/202 ,  B82Y20/00 ,  B82Y30/00 ,  B82Y40/00 ,  G02F1/3618 ,  Y10T428/261 ,  Y10T428/31504

Abstract: Novel (meth)acrylate copolymers which contain, as polymerized units,A) one or more (meth)acrylates and/or (meth)acrylamides having second order nonlinear optical properties and of the general formula I ##STR1## where R is hydrogen or methyl, X is a flexible spacer, which may or may not be present, Y is a divalent group having electron donor activity and Z is a noncentrosymmetric radical containing an easily polarizable conjugated .pi.-electron system and one or more electron acceptor groups, andB) one or more (meth)acrylates of alkanols where the alkyl radical is of 10 to 30 carbon atomsin a molar ratio of (A) to (B) of from 1:0.5 to 1:5 are very suitable as nonlinear optical materials for nonlinear optical arrangements and for the production of Langmuir-Blodgett films. The novel (meth)acrylate copolymers which contain terminal nitro, trifluoromethyl, cyano or fulven-6-yl groups as electron acceptors and have molar ratios A to B differing from those mentioned above are also suitable for intended uses outside nonlinear optics.

Abstract translation: PCT No.PCT / EP90 / 00866 Sec。 371日期1991年11月12日 102（e）1991年11月12日日期PCT提交1990年5月30日PCT公布。 公开号WO90 / 15087 日期：1990年12月13日。新型（甲基）丙烯酸酯共聚物，其含有作为聚合单元的A）一种或多种具有二阶非线性光学性质的（甲基）丙烯酸酯和/或（甲基）丙烯酰胺和通式I （I）其中R是氢或甲基，X是可以存在或可以不存在的柔性间隔物，Y是具有电子给体活性的二价基团，Z是含有容易极化的共轭π电子体系的非中心对称基团， 一种或多种电子受体基团，和B）一种或多种（A）至（B）摩尔比为1：0.5至1：1的烷基的碳原子数为10〜30的烷醇的（甲基） 5非常适合用于非线性光学布置的非线性光学材料和用于生产Langmuir-Blodgett膜。 含有末端硝基，三氟甲基，氰基或富二烯-6-基作为电子受体并且具有与上述不同的摩尔比A至B的新型（甲基）丙烯酸酯共聚物也适用于非线性光学外部的预期用途。