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    Acidproof, hydrolysis-resistant optical and ophathalmic glass of low density
    13.
    发明授权
    Acidproof, hydrolysis-resistant optical and ophathalmic glass of low density 失效
    耐酸，耐水解的光学和光学玻璃的低密度

    公开(公告)号：US4400473A

    公开(公告)日：1983-08-23

    申请号：US384462

    申请日：1982-06-02

    Applicant: Karl Mennemann ,  Georg Gliemeroth ,  Volkmar Geiler

    Inventor： Karl Mennemann ,  Georg Gliemeroth ,  Volkmar Geiler

    IPC: C03C3/064 ,  C03C3/066 ,  C03C3/068 ,  C03C3/072 ,  C03C3/074 ,  C03C3/08 ,  C03C3/10

    CPC classification number: C03C3/074 ,  C03C3/064 ,  C03C3/066 ,  C03C3/068 ,  C03C3/072 ,  Y10S501/901 ,  Y10S501/903

    Abstract: An improved optical glass having an index of refraction of .gtoreq.1.69, an Abbe number of .gtoreq.38, and a density of .ltoreq.3.25 g/cm.sup.3, represents a further development of another optical glass recently provided by the same inventors. The new glass has improved suitability for continuous-tank manufacture and increased acidproofness and differs from the other glass in its content of 0.5-4.0% by weight of P.sub.2 O.sub.5 ; its sum total of SiO.sub.2 +B.sub.2 O.sub.3 +Al.sub.2 O.sub.3 +P.sub.2 O.sub.5 being 38.5-41.5% by weight; and its sum total of MgO+CaO being 13-17.5% by weight. The full glass composition, e.g. is in % by weight:______________________________________ SiO.sub.2 26.0-32.5 B.sub.2 O.sub.3 6.0-12.0 Al.sub.2 O.sub.3 0-3.0 P.sub.2 O.sub.5 0.5-4.0 SiO.sub.2 + B.sub.2 O.sub.3 + Al.sub.2 O.sub.3 + P.sub.2 O.sub.5 = 38.5-41.5 Li.sub.2 O 0-5 Na.sub.2 O 0-6 K.sub.2 O 0-8 Li.sub.2 O + Na.sub.2 O + K.sub.2 O = 4.5-12.0 MgO 0-8 CaO 9-16 MgO + CaO = 13-17.5 SrO 0-6 BaO 0-5 ZnO 0-7 PbO 0-4 SrO + BaO + ZnO + PbO = 0-7 MgO + CaO + SrO + BaO + ZnO + PbO = 17-24 La.sub.2 O.sub.3 6-11 ZrO.sub.2 5-8 La.sub.2 O.sub.3 + ZrO.sub.2 = 13.5-17.5 TiO.sub.2 5-9 Nb.sub.2 O.sub.5 6-11 WO.sub.3 0-4 TiO.sub.2 + Nb.sub.2 O.sub.5 + WO.sub.3 = 14-18 La.sub.2 O.sub.3 + ZrO.sub.2 + TiO.sub.2 + Nb.sub.2 O.sub.5 + WO.sub.3 = 28-33 ZrO.sub.2 + TiO.sub.2 + Nb.sub.2 O.sub.5 = 20-26 ______________________________________

    Abstract translation: 具有折射率> / = 1.69，阿贝数≥38，密度为3.25g / cm 3的改进的光学玻璃表示最近由同一发明人提供的另一种光学玻璃的进一步发展 。 新玻璃改善了连续罐制造的适用性和耐酸性，与其他玻璃不同，其含量为P2O5重量的0.5-4.0％ 其总计SiO 2 + B 2 O 3 + Al 2 O 3 + P 2 O 5为38.5-41.5％（重量）; MgO + CaO的总和为13〜17.5重量％。 全玻璃组合物，例如 为重量％：-SiO2 26.0-32.5 -B2O3 6.0-12.0 -Al2O3 0-3.0 -P2O5 0.5-4.0 -SiO2 + B2O3 + Al2O3 + P2O5 = 38.5-41.5 -Li2O 0-5 -Na2O 0-6-K2O 0-8 -Li2O + Na2O + K2O = 4.5-12.0 -MgO 0-8 -CaO 9-16 -MgO + CaO = 13-17.5 -SrO 0-6 -BaO 0-5 -ZnO 0-7 -PbO 0- 4 -SrO + BaO + ZnO + PbO = 0-7 -MgO + CaO + SrO + BaO + ZnO + PbO = 17-24 -a2O3 6-11-ZrO2 5-8 -La2O3 + ZrO2 = 13.5-17.5 -TiO2 5 -9 -Nb2O5 6-11 -WO3 0-4 -TiO2 + Nb2O5 + WO3 = 14-18 -La2O3 + ZrO2 + TiO2 + Nb2O5 + WO3 = 28-33-ZrO2 + TiO2 + Nb2O5 = 20-26 -

    Optical glass, optical elements made therefrom, method of making the optical elements from the glass, and optical components comprising one or more optical elements
    14.
    发明授权
    Optical glass, optical elements made therefrom, method of making the optical elements from the glass, and optical components comprising one or more optical elements 有权
    光学玻璃，由其制成的光学元件，从玻璃制造光学元件的方法以及包括一个或多个光学元件的光学部件

    公开(公告)号：US08404606B2

    公开(公告)日：2013-03-26

    申请号：US12711390

    申请日：2010-02-24

    Applicant: Silke Wolff ,  Karl Mennemann ,  Uwe Kolberg ,  Ute Woelfel ,  Thomas Lifka

    Inventor： Silke Wolff ,  Karl Mennemann ,  Uwe Kolberg ,  Ute Woelfel ,  Thomas Lifka

    IPC: C03C3/068 ,  C03C3/155 ,  C03B11/00

    CPC classification number: C03C3/068

    Abstract: The lead-free and arsenic-free optical glasses have a refractive index of 1.83≦nd≦1.95 and an Abbé number of 24≦νd≦35, good chemical resistance, excellent crystallization stability and a composition, in wt. % based on oxide content, of SiO2, 2-8; B2O3, 15-22; La2O3, 35-42; ZnO, 10-18; TiO2, 9-15; ZrO2, 3-10; Nb2O5, 4-10; and WO3, >0.5-3. Besides containing at most 5 wt. % of each of GeO2, Ag2O and BaO and conventional fining agents, they may also contain at most in total 5 wt. % of Al2O3, MgO, CaO, SrO, P2O5 and up to at most in total 5 wt. % of the components F, Ta2O5. The glasses are preferably free of alkali metal oxides, Bi2O3, Y2O3, Gd2O3 and/or Yb2O3. Optical elements made from the optical glass are also described.

    Abstract translation: 无铅和无砷的光学眼镜的折射率为1.83＆nlE; nd＆nlE; 1.95，Abbé数为24＆nlE;＆ngr; d＆nlE; 35，良好的耐化学性，优异的结晶稳定性和组成，以重量计。 基于氧化物含量％，SiO 2，2-8; B2O3，15-22; La2O3,35-42; ZnO，10-18; TiO2，9-15; ZrO2，3-10; Nb2O5,4-10; 和WO3，> 0.5-3。 除含有最多5wt。 GeO 2，Ag 2 O和BaO和常规澄清剂中的每一种的％，它们也可以最多含有5wt。 ％的Al 2 O 3，MgO，CaO，SrO，P 2 O 5，最多至多5重量％ ％的组分F，Ta2O5。 玻璃优选不含碱金属氧化物Bi 2 O 3，Y 2 O 3，Gd 2 O 3和/或Yb 2 O 3。 还描述了由光学玻璃制成的光学元件。

    High absorbance Pb-containing glass for cathode ray tube picture screen
    16.
    发明授权
    High absorbance Pb-containing glass for cathode ray tube picture screen 失效
    高吸收性含铅玻璃用于阴极射线管图像屏幕

    公开(公告)号：US4520115A

    公开(公告)日：1985-05-28

    申请号：US519650

    申请日：1983-08-02

    Applicant: Burkhard Speit ,  Karl Mennemann ,  Georg Gliemeroth

    Inventor： Burkhard Speit ,  Karl Mennemann ,  Georg Gliemeroth

    IPC: C03C3/066 ,  C03C3/07 ,  C03C3/072 ,  C03C3/074 ,  C03C3/102 ,  C03C3/108 ,  C03C3/11 ,  C03C4/08 ,  H01J29/86 ,  C03C3/10

    CPC classification number: H01J29/863 ,  C03C3/07 ,  C03C3/102 ,  C03C4/087

    Abstract: These objects have been attained by providing highly absorbent lead containing alkali metal silicate glasses for cathode ray tube image screens, having a linear absorption coefficient .mu. of >30 cm.sup.-1 (0.6 .ANG.) and with a high resistance to discoloration by X-ray and electron radiation, comprises, in weight percent:______________________________________ SiO.sub.2 20-65% P.sub.2 O.sub.5 + B.sub.2 O.sub.3 + Al.sub.2 O.sub.3 0-30% Li.sub.2 O 0-5% Na.sub.2 O 0-10% K.sub.2 O 0-15% MgO + CaO + ZnO 0-15% SrO 0-20% BaO 0-40% PbO 5-60% ZrO.sub.2 0-10% CeO.sub.2 0.1-5% Other Components 0-20%. ______________________________________

    Abstract translation: 这些目的已经通过为阴极射线管图像屏幕提供含有碱金属硅酸盐玻璃的高吸收性铅，其线性吸收系数μ> 30cm-1（0.6安格姆），并且通过X射线具有高抗变色性， 电子辐射以重量百分数计：-SiO2 20-65％-P2O5 + B2O3 + Al2O3 0-30％-Li2O 0-5％-Na2O 0-10％-K2O 0-15％-MgO + CaO + ZnO0 -15％-SrO 0-20％-BaO 0-40％-PbO 5-60％-ZrO 2 0-10％-CeO 2 0.1-5％ - 其它组分0-20％。 -

    Acidproof, hydrolysis-resistant optical and ophthalmic glass of low density
    18.
    发明授权
    Acidproof, hydrolysis-resistant optical and ophthalmic glass of low density 失效
    耐酸，耐水解的光学和眼镜玻璃密度低

    公开(公告)号：US4390638A

    公开(公告)日：1983-06-28

    申请号：US282787

    申请日：1981-07-13

    Applicant: Karl Mennemann ,  Georg Gliemeroth ,  Volkmar Geiler

    Inventor： Karl Mennemann ,  Georg Gliemeroth ,  Volkmar Geiler

    IPC: G02C7/02 ,  C03C3/064 ,  C03C3/066 ,  C03C3/068 ,  C03C3/072 ,  C03C3/074 ,  C03C4/20 ,  C03C13/04 ,  G02B1/00 ,  C03C3/08 ,  C03C3/10

    CPC classification number: C03C3/064 ,  C03C3/066 ,  C03C3/068 ,  Y10S501/901 ,  Y10S501/903

    Abstract: An optical and ophthalmic glass having an index of refraction of .gtoreq.1.69, an Abbe number of .gtoreq.37, and a density of .ltoreq.3.30 g/cm.sup.3, consists essentially of (in % by weight):______________________________________ SiO.sub.2 18-36 B.sub.2 O.sub.3 3-18 GeO.sub.2 0-8 Al.sub.2 O.sub.3 0-6, wherein SiO.sub.2 + B.sub.2 O.sub.3 + Al.sub.2 O.sub.3 + GeO.sub.2 25-39 P.sub.2 O.sub.5 0-14, wherein SiO.sub.2 + B.sub.2 O.sub.3 + Al.sub.2 O.sub.3 + GeO.sub.2 + P.sub.2 O.sub.5 = 30-44 Li.sub.2 O 0-12 Na.sub.2 O 0-14 K.sub.2 O 0-18 Li.sub.2 O + Na.sub.2 O + K.sub.2 O = 2-18 MgO 0-15 CaO 7-25 MgO + CaO 15-32 SrO 0-13 BaO 0-17 ZnO 0-15 PbO 0-10 SrO + BaO + ZnO + PbO 0-20 TiO.sub.2 3-14 Nb.sub.2 O.sub.5 0-13 WO.sub.3 0-10 TiO.sub.2 + Nb.sub.2 O.sub.5 + WO.sub.3 = 10-21 ZrO.sub.2 0-15, La.sub.2 O.sub.3 0-20 Y.sub.2 O.sub.3 0-16 Gd.sub.2 O.sub.3 0-16 Yb.sub.2 O.sub.3 0-10 La.sub.2 O.sub.3 + Y.sub.2 O.sub.3 + Gd.sub.2 O.sub.3 + Yb.sub.2 O.sub.3 = 0-20 Ta.sub.2 O.sub.5 0-13 HfO.sub.2 0-5 SnO.sub.2 0-6. ______________________________________

    Abstract translation: 具有折射率> / = 1.69，阿贝数≥37，密度为3.30g / cm 3的光学和眼镜玻璃基本上由（以重量％计）：-SiO 2 18 -36 -B2O3 3-18 -GeO2 0-8 -Al2O3 0-6，其中SiO2 + B2O3 + Al2O3 + GeO2 = 25-39 -P2O5 0-14，其中SiO2 + B2O3 + Al2O3 + GeO2 + P2O5 = 30 -44 -Li2O 0-12 -Na2O 0-14 -K2O 0-18 -Li2O + Na2O + K2O = 2-18 -MgO 0-15 -CaO 7-25 -MgO + CaO 15-32 -SrO 0-13 - BaO 0-17 -ZnO 0-15 -PbO 0-10 -SrO + BaO + ZnO + PbO 0-20 -TiO2 3-14 -Nb2O5 0-13 -WO3 0-10 -TiO2 + Nb2O5 + WO3 = 10-21 -ZrO2 0-15，-La2O3 0-20 -Y2O3 0-16 -Gd2O3 0-16 -Yb2O3 0-10 -La2O3 + Y2O3 + Gd2O3 + Yb2O3 = 0-20-Ta2O5 0-13 -HfO2 0-5 -SnO2 0-6。 -

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