摘要:
A novel silver halide emulsion containing a dispersing agent and silver halide grains is provided, characterized in that first tabular grains having a (100) plane as a main plane and an aspect ratio (diameter/thickness) of 1.5 or more whose shape on the main plane is a rectangular parallelogram having one to four corners non-equivalently missing account for 10% or more of all silver halide grains calculated in terms of projected area. In a preferred embodiment, 20% or more of the grains other than said first tabular grains calculated in terms of projected area is occupied by second tabular grains having a (100) plane as a main plane, an aspect ratio of 1.5 or more and the shape on the main plane of substantially a rectangular parallelogram.
摘要:
A silver halide emulsion is disclosed, comprising at least a dispersing medium and silver halide grains, wherein at least 60% of the total projected area of silver halide grains is occupied by tabular grains having a crystal defect for anisotropic growth which have a {100} face as a main plane and an aspect ratio (diameter/thickness ratio) of not less than 2.0, and the right-angled parallelogram enclosed with {100} faces at the edges of the tabular grains or a right-angled parallelogram formed by extending the {100} faces at the edges having a slenderness side ratio (a ratio of the length of the long side to that of the short side) of 1 to 6; and said silver halide emulsion is prepared in the presence of a compound A.sup.0 and/or a compound B.sup.0, wherein the compound A.sup.0 represents an organic compound having covalently bonded to an individual molecule thereof at least two molecules of an adsorbable agent which accelerates formation of a {100} face of silver bromide grains, and the compound B.sup.0 represents an organic compound except gelatin having at least four alcoholic groups per molecule, both the compounds A.sup.0 and B.sup.0 are organic compounds except gelatin and other proteins. The emulsion is excellent in sensitivity, image quality and preservability.
摘要:
A silver halide emulsion at least containing a dispersion medium and silver halide grains, in which the grains of 20% or more of the total projected areas of all the silver halide grains are substantially octahedral grains as derived from cubic grains by deleting substantially two diagonal apexes of the eight apices of the cubic grain, the outer surface of the deleted site is a {111} plane, and the main plane (the maximum flat plane of the outer surface of the grain) is a {100} plane. Since the sites of forming chemically-sensitized nuclei are defined in the emulsion grains, dispersion of latent images formed is inhibited. The emulsion has a high sensitivity and has excellent reciprocity law failure characteristics, developability and formed image quality.
摘要:
A process or the preparation of a silver halide photographic emulsion is provided which comprises the addition of at least one pendant type spectral sensitizing dye containing as a substituent a compound having the effect of inhibiting fog at any time after the formation of silver halide grains, but before the completion of the chemical ripening process. In a preferred embodiment, the addition of said pendant type spectral sensitizing dyes is effected at any time after the formation of silver halide grains, but before former one second of the total time of the chemical ripening process. The pendant type spectral sensitizing dyes are compounds represented by the general formula (III) or (IV): ##STR1## wherein SSD represents a sensitizing dye portion; AF represents a compound portion containing a saturated or unsaturated 5- to 7-membered ring containing at least one nitrogen atom; L.sup.1 represents a divalent connecting group containing at least one of C, N, S and O; L.sup.2 has the same meaning at L.sup.1 and does not connect SSD and AF; l.sup.1, l.sup.2 and l.sup.3 each represents an integer 1 to 3, l.sup.2 being equal to l.sup.1 or l.sup.3 ; l.sup.4 represents an integer 0 to 3; and l.sup.5 represents an integer 0 or 1, with the proviso that when there is a plurality of L.sup.1 's, L.sup.2 's, SSD's or AF's, they may be the same or different and that when none of L.sup.2 's adjacent to l.sup.5 connect SSD and AF, l.sup.5 represents 0.
摘要:
A silver halide photographic material is disclosed, comprising a support having thereon an emulsion layer comprising a dispersion medium, silver halide grains, and a pendant type sensitizing dye, wherein said pendant type sensitizing dye is a compound comprising a sensitizing dye and an antifoggant, each of which may have substituent groups and wherein said sensitizing dye and antifoggant are organochemically bonded.
摘要:
A silver halide photographic emulsion comprising silver halide grains is disclosed, wherein at least 60% of the total projected area of the silver halide grains is comprised of tabular silver halide grains having a central portion and an outer portion, of which the iodide content of the central portion is from 7 mol % to the solid solution limit, and which have two parallel twinned crystal planes.A method for the manufacture of the silver halide emulsion is also disclosed, which comprises the steps of nucleating the silver halide grains under conditions where the gelatin concentration in the reaction solution is set at from 0.1 to 20 wt %, the addition rates of the silver salt and the halide are set at from 6.times.10.sup.-4 to 2.9.times.10.sup.-1 mol/minute per liter of reaction solution, and the pBr value in the reaction solution is set at from 1.0 to 2.5, Ostwald ripening the nucleated grains, and then growing the thus ripened grains.
摘要:
The present invention can reduce the warping of the printed circuit board of a display device. This advantage can be obtained by providing a display device which includes a display element; a printed circuit board which is arranged in a state that the printed circuit board extends over a peripheral portion of the display element; and a plurality of flexible printed circuit boards which connect the display element and the printed circuit board, wherein the printed circuit board is connected with the plurality of flexible printed circuit boards using a plurality of connection terminal groups corresponding to the plurality of flexible printed circuit boards, dummy terminal groups are provided between the plurality of connection terminal groups, and the dummy terminal groups are arranged on a side close to the display element side and a side remote from the display element side in the direction orthogonal to the extension direction of the printed circuit board in a state that respective dummy terminal rates are made close to each other.
摘要:
A silver halide emulsion comprises at least a dispersion medium, water and a silver halide grain, wherein grains occupying from 40 to 100% of the total projected area of said gains have an AgI content of 85 to 100 mol %, a single kind of outer shape except for size and the equivalent-circle projected diameter of from 0.002 to 20 μm.
摘要:
There is disclosed a silver halide emulsion that comprises at least a dispersion medium and silver halide grains, wherein 60% or more of the total projected area of the silver halide grains is occupied by tabular grains having an epitaxial junction, which grains each have a {100} face as a main plane and an aspect ratio (diameter/thickness ratio) of from 2.0 to 100; and wherein a right-angled parallelogram enclosed with {100} side faces at the main plane edges on the portion of the tabular grains, which portion does not have the epitaxial junction, or if the tabular grains have at least one corner broken off, a right-angled parallelogram formed by extending the {100} side faces at the main plane edges, has a slenderness side ratio (a ratio of the length of the long side to that of the short side) of 1 to 6; and wherein the tabular grains have the epitaxial junction with a silver halide protrusion that has a higher solubility than the portion of the tabular grains, which portion does not have the epitaxial junction. There is also disclosed a silver halide emulsion the same to the above, except that (A) the tabular grains have no epitaxy but crystal defects for anisotropic growth and an aspect ratio of 2.0 or more, and (B) a six-coordinate dopant capable of forming a shallow electron trap is present in a crystal lattice. The silver halide emulsions are high in sensitivity and image quality, and they are excellent in suppression of dependency on a processing solution pH and in preservability of latent image, and they can be utilized in silver halide color photographic light-sensitive materials.
摘要:
A silver halide emulsion is described, which comprises at least a dispersion medium and silver halide grains, wherein from 40 to 100% of the total projected area of the entire silver halide grains are occupied by tabular grains having a thickness of from 0.01 to 0.50 .mu.m, an aspect ratio (diameter/thickness) of from 1.6 to 500, and main planes of {100} faces, and the aspect ratio of a right angled parallelogram surrounded by edge sides of {100} face of the tabular grains or a right angled parallelogram formed by extending the edge sides (long side length/short side length) is from 1 to 8, and the tabular grains are tabular grains formed by the adsorption of compound A.sup.0 represented by formula (Z.sup.1), (Z.sup.2), (Z.sup.3) or (Z.sup.4) onto silver halide grains:B.sup.1 --S--B.sup.2 (Z.sup.1)B.sup.1 --S(O)--B.sup.2 (Z.sup.2)B.sup.1 --S(O.sub.2)--B.sup.2 (Z.sup.3)B.sup.1 --S.sup.+ (R.sup.0)--B.sup.2 .multidot.Y.sub.0.sup.-(Z.sup.4)wherein B.sup.1 represents a residue having two or more repeating units of polyvinyl alcohol in B.sup.1 ; --S-- represents a thioether group; B.sup.2 represents a residue having two or more repeating units of polyacrylic acid or polyacrylamide; R.sup.0 represents an alkyl group having from 1 to 20 carbon atoms, an aryl group, or an amino group; and Y.sub.0.sup.- represents an anion.