公开(公告)号：US20090208741A1

公开(公告)日：2009-08-20

申请号：US12370967

申请日：2009-02-13

申请人： Yuusuke Toyama ,  Shinichi Inoue ,  Mizue Nagata ,  Toshitsugu Hosokawa

发明人： Yuusuke Toyama ,  Shinichi Inoue ,  Mizue Nagata ,  Toshitsugu Hosokawa

IPC分类号： B32B27/36 ,  C08F8/30

CPC分类号： C08G18/6229 ,  C08F8/00 ,  C08F2800/20 ,  C08G18/10 ,  C08G18/6254 ,  C08G18/73 ,  Y10T428/2891 ,  C08F220/12

摘要： There is provided a pressure-sensitive adhesive composition for optical films. The composition can form a pressure-sensitive adhesive layer that can prevent light leakage caused by stress associated with dimensional change of a component such as an optical film, which include the pressure-sensitive adhesive layer that has reworkability such that it can be easily peeled from a component, and that has satisfactory processability such that it can be processed without pressure-sensitive adhesive stain or dropout, after it is formed on an optical film. A pressure-sensitive adhesive optical film produced using the composition is also provided. The pressure-sensitive adhesive composition includes a (meth)acrylic polymer including (a) 34 to 94% by weight of an alkyl(meth)acrylate monomer unit, (b) 5 to 35% by weight of an aromatic ring-containing (meth)acrylate monomer unit, and (c) 0.01 to 0.5% by weight of an amino group-containing (meth)acrylate monomer unit and further including (d) 0.05 to 3% by weight of a carboxyl group-containing (meth)acrylate monomer unit and/or (e) 0.05 to 2% by weight of a hydroxyl group-containing (meth)acrylate monomer unit and having a weight average molecular weight of 1,600,000 to 3,000,000 as determined by gel permeation chromatography; crosslinking agents including 0.01 to 5 parts by weight of an isocyanate crosslinking agent and 0.01 to 2 parts by weight of a silane coupling agent based on 100 parts by weight of the (meth)acrylic polymer.

摘要翻译： 提供了一种用于光学膜的压敏粘合剂组合物。 该组合物可以形成一种压敏粘合剂层，其可以防止由与诸如光学膜的组分的尺寸变化相关的应力引起的光泄漏，其包括具有可再加工性的压敏粘合剂层，使得其可以容易地从 并且具有令人满意的加工性，使得其可以在形成在光学膜上之后可以被加工而没有压敏粘合剂污渍或脱落。 还提供了使用该组合物制备的压敏粘合剂光学膜。 压敏粘合剂组合物包括（甲基）丙烯酸类聚合物，其包含（a）34-94重量％的（甲基）丙烯酸烷基酯单体单元，（b）5-35重量％的含芳环的（甲基） ）丙烯酸酯单体单元，（c）0.01〜0.5重量％的含氨基（甲基）丙烯酸酯单体单元，进一步含有（d）0.05〜3重量％的含羧基的（甲基）丙烯酸酯单体 单元和/或（e）0.05〜2重量％的含羟基的（甲基）丙烯酸酯单体单元，通过凝胶渗透色谱法测定的重均分子量为1,600,000至3,000,000; 交联剂，其包含0.01至5重量份的异氰酸酯交联剂和基于100重量份的（甲基）丙烯酸类聚合物）的0.01至2重量份的硅烷偶联剂。

公开(公告)号：US20090162577A1

公开(公告)日：2009-06-25

申请号：US12338435

申请日：2008-12-18

申请人： Shinichi INOUE ,  Yuusuke TOYAMA ,  Mizue NAGATA ,  Toshitsugu HOSOKAWA ,  Yutaka MOROISHI ,  Fumiko NAKANO

发明人： Shinichi INOUE ,  Yuusuke TOYAMA ,  Mizue NAGATA ,  Toshitsugu HOSOKAWA ,  Yutaka MOROISHI ,  Fumiko NAKANO

IPC分类号： C09J131/02 ,  C09K19/00

CPC分类号： C09J133/08 ,  C09J133/14 ,  C09J2201/606 ,  Y10T428/1077 ,  Y10T428/2891

摘要： There is provided an optical film pressure-sensitive adhesive composition capable of forming a pressure-sensitive adhesive layer that has reworkability such that optical films therewith can be easily separated from liquid crystal panels with no adhesive residue and also has satisfactory processability such that it can be processed without causing adhesive stain or dropout after it is formed on an optical film. The optical film pressure-sensitive adhesive composition includes 100 parts by weight of a (meth)acrylic polymer including, as monomer units, (a) 50 to 99.79% by weight of an alkyl (meth)acrylate monomer, (b) 0.01 to 0.45% by weight of a tertiary amino group-containing monomer, and (c) 0.1 to 3% by weight of a hydroxyl group-containing monomer; and 0.01 to 2 parts by weight of a crosslinking agent that is at least one selected from the group consisting of hexamethylene diisocyanate, hydrogenated xylylene diisocyanate, and isophorone diisocyanate, or a polyisocyanate compound derived therefrom.

摘要翻译： 提供一种光学膜压敏粘合剂组合物，其能够形成具有再加工性的粘合剂层，使得其中的光学膜可以容易地与液晶面板分离而没有粘合残留物，并且还具有令人满意的加工性，使得其可以 在光学膜上形成之后不会引起粘合剂污渍或脱落。 光学膜压敏粘合剂组合物包括100重量份的（甲基）丙烯酸类聚合物，其包含作为单体单元的（a）50-99.79重量％的（甲基）丙烯酸烷基酯单体，（b）0.01至0.45 （c）0.1〜3重量％的含羟基单体;和（c）含有叔氨基的单体的重量％ 和0.01〜2重量份的选自六亚甲基二异氰酸酯，氢化亚二甲苯基二异氰酸酯和异佛尔酮二异氰酸酯中的至少一种的交联剂或由其衍生的多异氰酸酯化合物。

公开(公告)号：US20090116111A1

公开(公告)日：2009-05-07

申请号：US12262771

申请日：2008-10-31

申请人： Yuusuke TOYAMA ,  Shinichi INOUE ,  Mizue NAGATA ,  Toshitsugu HOSOKAWA

发明人： Yuusuke TOYAMA ,  Shinichi INOUE ,  Mizue NAGATA ,  Toshitsugu HOSOKAWA

IPC分类号： G02B1/10 ,  B32B33/00 ,  B32B38/00

CPC分类号： C09J7/0246 ,  C09J7/22 ,  C09J7/38 ,  C09J133/066 ,  C09J2433/00 ,  Y10T428/1225 ,  Y10T428/14 ,  Y10T428/2809 ,  Y10T428/31928

摘要： A pressure-sensitive adhesive optical film of the present invention comprises an optical film; and a pressure-sensitive adhesive layer laminated on at least one side of the optical film, wherein the pressure-sensitive adhesive layer is formed from an acrylic pressure-sensitive adhesive comprising a (meth)acrylic polymer comprising 30 to 99.99% by weight of an alkyl (meth)acrylate monomer unit and 0.01 to 15% by weight of a functional group-containing monomer unit, and the (meth)acrylic polymer in the acrylic pressure-sensitive adhesive is crosslinked by electron beam irradiation. The pressure-sensitive adhesive optical film has a high level of reworkability, durability and workability.

摘要翻译： 本发明的粘合型光学膜包括光学膜; 以及层叠在所述光学膜的至少一侧的压敏粘合剂层，其中，所述压敏粘合剂层由包含（甲基）丙烯酸类聚合物的丙烯酸类压敏粘合剂形成，所述（甲基）丙烯酸类聚合物包含30〜99.99重量％ （甲基）丙烯酸烷基酯单体单元和0.01〜15重量％的含官能团的单体单元，并且丙烯酸类压敏粘合剂中的（甲基）丙烯酸类聚合物通过电子束照射而交联。 压敏粘合剂光学膜具有高水平的再加工性，耐久性和可加工性。

公开(公告)号：US20080112047A1

公开(公告)日：2008-05-15

申请号：US11938968

申请日：2007-11-13

申请人： Hiroaki Mizushima ,  Megumi Katou ,  Mizue Nagata ,  Takaaki Ishii ,  Daisuke Ogomi

发明人： Hiroaki Mizushima ,  Megumi Katou ,  Mizue Nagata ,  Takaaki Ishii ,  Daisuke Ogomi

IPC分类号： B32B17/08 ,  G02B5/30

CPC分类号： B29D11/0073 ,  B29D11/00634 ,  G02B5/305 ,  G02B5/3083

摘要： A method for producing a polarizing plate of the invention comprises bonding a transparent protective film (A) and another transparent protective film (B) to one side of a polarizer and to another side of the polarizer, respectively, with an adhesive, wherein the polarizer has a moisture content of 15 to 30% by weight, the transparent protective film (A) is made of the same quality material as the transparent protective film (B), the transparent protective film (A) is thicker than the transparent protective film (B), and the transparent protective film (A) has a moisture content higher than that of the transparent protective film (B). The polarizing plate obtained by the production method can suppress curling.

摘要翻译： 本发明的偏振片的制造方法包括：将透明保护膜（A）和另一透明保护膜（B）分别粘合到偏振片的一面和偏振片的另一侧，其中所述偏振片 水分含量为15〜30重量％，透明保护膜（A）由与透明保护膜（B）相同质量的材料制成，透明保护膜（A）比透明保护膜（A）厚 B），并且透明保护膜（A）的水分含量高于透明保护膜（B）的水分含量。 通过该制造方法得到的偏光板可以抑制卷曲。

公开(公告)号：US08709597B2

公开(公告)日：2014-04-29

申请号：US12916959

申请日：2010-11-01

申请人： Yuusuke Toyama ,  Shinichi Inoue ,  Mizue Nagata ,  Toshitsugu Hosokawa

发明人： Yuusuke Toyama ,  Shinichi Inoue ,  Mizue Nagata ,  Toshitsugu Hosokawa

IPC分类号： B32B15/04

CPC分类号： C08G18/6229 ,  C08F8/00 ,  C08F2800/20 ,  C08G18/10 ,  C08G18/6254 ,  C08G18/73 ,  Y10T428/2891 ,  C08F220/12

摘要： There is provided a pressure-sensitive adhesive composition for optical films. The composition can form a pressure-sensitive adhesive layer that can prevent light leakage caused by stress associated with dimensional change of a component such as an optical film, which include the pressure-sensitive adhesive layer that has reworkability such that it can be easily peeled from a component, and that has satisfactory processability such that it can be processed without pressure-sensitive adhesive stain or dropout, after it is formed on an optical film. A pressure-sensitive adhesive optical film produced using the composition is also provided. The pressure-sensitive adhesive composition includes a (meth)acrylic polymer including (a) 34 to 94% by weight of an alkyl (meth)acrylate monomer unit, (b) 5 to 35% by weight of an aromatic ring-containing (meth)acrylate monomer unit, and (c) 0.01 to 0.5% by weight of an amino group-containing (meth)acrylate monomer unit and further including (d) 0.05 to 3% by weight of a carboxyl group-containing (meth)acrylate monomer unit and/or (e) 0.05 to 2% by weight of a hydroxyl group-containing (meth)acrylate monomer unit and having a weight average molecular weight of 1,600,000 to 3,000,000 as determined by gel permeation chromatography; crosslinking agents including 0.01 to 5 parts by weight of an isocyanate crosslinking agent and 0.01 to 2 parts by weight of a silane coupling agent based on 100 parts by weight of the (meth)acrylic polymer.

摘要翻译： 提供了一种用于光学膜的压敏粘合剂组合物。 该组合物可以形成一种压敏粘合剂层，其可以防止由与诸如光学膜的组分的尺寸变化相关的应力引起的光泄漏，其包括具有可再加工性的压敏粘合剂层，使得其可以容易地从 并且具有令人满意的加工性，使得其可以在形成在光学膜上之后可以被加工而没有压敏粘合剂污渍或脱落。 还提供了使用该组合物制备的压敏粘合剂光学膜。 压敏粘合剂组合物包括（甲基）丙烯酸类聚合物，其包含（a）34-94重量％的（甲基）丙烯酸烷基酯单体单元，（b）5-35重量％的含芳环的（甲基） ）丙烯酸酯单体单元，（c）0.01〜0.5重量％的含氨基（甲基）丙烯酸酯单体单元，进一步含有（d）0.05〜3重量％的含羧基的（甲基）丙烯酸酯单体 单元和/或（e）0.05〜2重量％的含羟基的（甲基）丙烯酸酯单体单元，通过凝胶渗透色谱法测定的重均分子量为1,600,000至3,000,000; 交联剂，其包含0.01至5重量份的异氰酸酯交联剂和基于100重量份的（甲基）丙烯酸类聚合物）的0.01至2重量份的硅烷偶联剂。

公开(公告)号：US07846542B2

公开(公告)日：2010-12-07

申请号：US12370967

申请日：2009-02-13

申请人： Yuusuke Toyama ,  Shinichi Inoue ,  Mizue Nagata ,  Toshisugu Hosokawa

发明人： Yuusuke Toyama ,  Shinichi Inoue ,  Mizue Nagata ,  Toshisugu Hosokawa

IPC分类号： C08F8/30 ,  C08F8/00

CPC分类号： C08G18/6229 ,  C08F8/00 ,  C08F2800/20 ,  C08G18/10 ,  C08G18/6254 ,  C08G18/73 ,  Y10T428/2891 ,  C08F220/12

摘要： There is provided a pressure-sensitive adhesive composition for optical films. The composition can form a pressure-sensitive adhesive layer that can prevent light leakage caused by stress associated with dimensional change of a component such as an optical film, which include the pressure-sensitive adhesive layer that has reworkability such that it can be easily peeled from a component, and that has satisfactory processability such that it can be processed without pressure-sensitive adhesive stain or dropout, after it is formed on an optical film. A pressure-sensitive adhesive optical film produced using the composition is also provided. The pressure-sensitive adhesive composition includes a (meth)acrylic polymer including (a) 34 to 94% by weight of an alkyl(meth)acrylate monomer unit, (b) 5 to 35% by weight of an aromatic ring-containing (meth)acrylate monomer unit, and (c) 0.01 to 0.5% by weight of an amino group-containing (meth)acrylate monomer unit and further including (d) 0.05 to 3% by weight of a carboxyl group-containing (meth)acrylate monomer unit and/or (e) 0.05 to 2% by weight of a hydroxyl group-containing (meth)acrylate monomer unit and having a weight average molecular weight of 1,600,000 to 3,000,000 as determined by gel permeation chromatography; crosslinking agents including 0.01 to 5 parts by weight of an isocyanate crosslinking agent and 0.01 to 2 parts by weight of a silane coupling agent based on 100 parts by weight of the (meth)acrylic polymer.

摘要翻译： 提供了一种用于光学膜的压敏粘合剂组合物。 该组合物可以形成一种压敏粘合剂层，其可以防止由与诸如光学膜的组分的尺寸变化相关的应力引起的光泄漏，其包括具有可再加工性的压敏粘合剂层，使得其可以容易地从 并且具有令人满意的加工性，使得其可以在形成在光学膜上之后可以被加工而没有压敏粘合剂污渍或脱落。 还提供了使用该组合物制备的压敏粘合剂光学膜。 压敏粘合剂组合物包括（甲基）丙烯酸类聚合物，其包含（a）34-94重量％的（甲基）丙烯酸烷基酯单体单元，（b）5-35重量％的含芳环的（甲基） ）丙烯酸酯单体单元，（c）0.01〜0.5重量％的含氨基（甲基）丙烯酸酯单体单元，进一步含有（d）0.05〜3重量％的含羧基的（甲基）丙烯酸酯单体 单元和/或（e）0.05〜2重量％的含羟基的（甲基）丙烯酸酯单体单元，通过凝胶渗透色谱法测定的重均分子量为1,600,000至3,000,000; 交联剂，其包含0.01至5重量份的异氰酸酯交联剂和基于100重量份的（甲基）丙烯酸类聚合物）的0.01至2重量份的硅烷偶联剂。

公开(公告)号：US07576913B2

公开(公告)日：2009-08-18

申请号：US11938968

申请日：2007-11-13

申请人： Hiroaki Mizushima ,  Megumi Katou ,  Mizue Nagata ,  Takaaki Ishii ,  Daisuke Ogomi

发明人： Hiroaki Mizushima ,  Megumi Katou ,  Mizue Nagata ,  Takaaki Ishii ,  Daisuke Ogomi

IPC分类号： G02B5/30

CPC分类号： B29D11/0073 ,  B29D11/00634 ,  G02B5/305 ,  G02B5/3083

摘要： A method for producing a polarizing plate of the invention comprises bonding a transparent protective film (A) and another transparent protective film (B) to one side of a polarizer and to another side of the polarizer, respectively, with an adhesive, wherein the polarizer has a moisture content of 15 to 30% by weight, the transparent protective film (A) is made of the same quality material as the transparent protective film (B), the transparent protective film (A) is thicker than the transparent protective film (B), and the transparent protective film (A) has a moisture content higher than that of the transparent protective film (B). The polarizing plate obtained by the production method can suppress curling.

摘要翻译： 本发明的偏振片的制造方法包括：将透明保护膜（A）和另一透明保护膜（B）分别粘合到偏振片的一面和偏振片的另一侧，其中所述偏振片 水分含量为15〜30重量％，透明保护膜（A）由与透明保护膜（B）相同质量的材料制成，透明保护膜（A）比透明保护膜（A）厚 B），并且透明保护膜（A）的水分含量高于透明保护膜（B）的水分含量。 通过该制造方法得到的偏光板可以抑制卷曲。

公开(公告)号：US20090110924A1

公开(公告)日：2009-04-30

申请号：US12260210

申请日：2008-10-29

申请人： Shinichi INOUE ,  Yuusuke TOYAMA ,  Mizue NAGATA ,  Toshitsugu HOSOKAWA

发明人： Shinichi INOUE ,  Yuusuke TOYAMA ,  Mizue NAGATA ,  Toshitsugu HOSOKAWA

IPC分类号： B32B33/00 ,  B32B38/00 ,  C08F20/10 ,  C08G16/00 ,  C08F20/28 ,  C08F26/02

CPC分类号： C09J133/066 ,  C09J7/22 ,  C09J7/38 ,  C09J2433/00 ,  Y10T428/2809

摘要： A pressure-sensitive adhesive for an optical film of the present invention comprises a (meth)acrylic polymer comprising 50 to 99.99% by weight of alkyl (meth)acrylate monomer unit and 0.01 to 30% by weight of a photocrosslinkable monomer unit having an unsaturated double bond-containing polymerizable functional group and a photocrosslinkable moiety different from the functional group. A pressure-sensitive adhesive layer is formed from the pressure-sensitive adhesive on at least one side of an optical film, wherein the photocrosslinkable moiety of the (meth)acrylic polymer in the pressure-sensitive adhesive is crosslinked by active energy ray irradiation. The pressure-sensitive adhesive can form the pressure-sensitive adhesive layer with a high level of durability and preferable workability.

摘要翻译： 本发明的光学薄膜用粘合剂包含（甲基）丙烯酸系聚合物，其含有50〜99.99重量％的（甲基）丙烯酸烷基酯单体单元和0.01〜30重量％的具有不饱和键的光可交联单体单元 含有双键的可聚合官能团和与该官能团不同的光可交联部分。 在光学膜的至少一侧上由压敏粘合剂形成压敏粘合剂层，其中压敏粘合剂中的（甲基）丙烯酸类聚合物的光致交联部分通过活性能量射线照射而交联。 压敏粘合剂可以形成具有高水平的耐久性和优选的可加工性的压敏粘合剂层。