公开(公告)号：US20060189953A1

公开(公告)日：2006-08-24

申请号：US10552152

申请日：2004-04-07

申请人： Takayasu Taniguchi ,  Masayoshi Handa ,  Yasuhiro Nawata

发明人： Takayasu Taniguchi ,  Masayoshi Handa ,  Yasuhiro Nawata

IPC分类号： A61F13/20

CPC分类号： C08L101/14 ,  A61F13/8405 ,  A61L15/425 ,  A61L15/46 ,  A61L15/60 ,  A61L2300/102 ,  A61L2300/21 ,  A61L2300/404 ,  A61L2300/45 ,  B32B27/18

摘要： The object of the present invention is to provide a water-absorbing resin compound, wherein the water-absorbing resin compound can retain antibacterial properties of an antibacterial metal to suppress the emission of unpleasant odors even when an organic material exists in a system in the case of using an eluting-type antibacterial agent. Thus, the present invention relates to a water-absorbing resin compound, which comprises a water-absorbing resin, an antibacterial agent having a porous material incorporating an antibacterial metal, and a metal chelating agent. Further, the present invention also relates to an absorbing material, which comprises a water-absorbing resin compound of the present invention, and a hydrophilic fiber as well as an absorbing product, which comprises a liquid-permeable sheet and a liquid-non-permeable sheet, and an absorbing material comprising a water-absorbing resin compound of the present invention, and a hydrophilic fiber between the liquid-permeable sheet and the liquid-non-permeable sheet.

摘要翻译： 本发明的目的是提供一种吸水性树脂化合物，其中吸水性树脂化合物可以保持抗菌金属的抗菌性能，以抑制令人不快的气味的排放，即使当在该情况下的系统中存在有机材料时 使用洗脱型抗菌剂。 因此，本发明涉及一种吸水性树脂化合物，其包含吸水性树脂，具有包含抗菌金属的多孔材料的抗菌剂和金属螯合剂。 此外，本发明还涉及一种吸收材料，其包含本发明的吸水性树脂化合物和亲水性纤维以及吸收产品，其包含透液性片和不透液性的片 片材，以及包含本发明的吸水性树脂化合物的吸收材料和透液性片材与不透液性片材之间的亲水性纤维。

公开(公告)号：US08981176B2

公开(公告)日：2015-03-17

申请号：US12956563

申请日：2010-11-30

申请人： Takayasu Taniguchi ,  Masayoshi Handa ,  Yasuhiro Nawata

发明人： Takayasu Taniguchi ,  Masayoshi Handa ,  Yasuhiro Nawata

IPC分类号： A61F13/15 ,  A61L9/01 ,  C08L101/14 ,  A61F13/84 ,  A61L15/42 ,  A61L15/46 ,  A61L15/60 ,  B32B27/18

CPC分类号： C08L101/14 ,  A61F13/8405 ,  A61L15/425 ,  A61L15/46 ,  A61L15/60 ,  A61L2300/102 ,  A61L2300/21 ,  A61L2300/404 ,  A61L2300/45 ,  B32B27/18

摘要： The object of the present invention is to provide a water-absorbing resin compound, wherein the water-absorbing resin compound can retain antibacterial properties of an antibacterial metal to suppress the emission of unpleasant odors even when an organic material exists in a system in the case of using an eluting-type antibacterial agent. Thus, the present invention relates to a water-absorbing resin compound, which comprises a water-absorbing resin, an antibacterial agent having a porous material incorporating an antibacterial metal, and a metal chelating agent. Further, the present invention also relates to an absorbing material, which comprises a water-absorbing resin compound of the present invention, and a hydrophilic fiber as well as an absorbing product, which comprises a liquid-permeable sheet and a liquid-non-permeable sheet, and an absorbing material comprising a water-absorbing resin compound of the present invention, and a hydrophilic fiber between the liquid-permeable sheet and the liquid-non-permeable sheet.

摘要翻译： 本发明的目的是提供一种吸水性树脂化合物，其中吸水性树脂化合物可以保持抗菌金属的抗菌性能，以抑制令人不快的气味的排放，即使当在该情况下的系统中存在有机材料时 使用洗脱型抗菌剂。 因此，本发明涉及一种吸水性树脂化合物，其包含吸水性树脂，具有包含抗菌金属的多孔材料的抗菌剂和金属螯合剂。 此外，本发明还涉及一种吸收材料，其包含本发明的吸水性树脂化合物和亲水性纤维以及吸收产品，其包含透液性片和不透液性的片 片材，以及包含本发明的吸水性树脂化合物的吸收材料和透液性片材与不透液性片材之间的亲水性纤维。

公开(公告)号：US08378033B2

公开(公告)日：2013-02-19

申请号：US12297057

申请日：2007-04-20

申请人： Masayoshi Handa ,  Yasuhiro Nawata

发明人： Masayoshi Handa ,  Yasuhiro Nawata

IPC分类号： B01J20/26 ,  C08F2/18 ,  C08F20/06

CPC分类号： C08F2/32 ,  B01J20/267 ,  C08F220/06 ,  C08F222/385 ,  Y10T428/2982

摘要： The present invention relates to a method of producing water-absorbent resin particles in which a median particle size of primary particles (d) and a median particle size of secondary particles (D) satisfy the relationship of the formula, 5d/3+150

摘要翻译： 本发明涉及一次吸附树脂颗粒的制造方法，其中一次颗粒（d）的中值粒径和二次颗粒（D）的中值粒径满足式5d / 3 + D <5d + 150，包括以下步骤：（1）在石油烃溶剂中，在分散稳定剂存在下，使水溶性烯属不饱和单体进行第一步反相悬浮聚合反应，得到球形 中值粒径（d）为30〜130μm的一次粒子; （2）冷却聚合反应溶液，使分散稳定剂沉淀; 和（3）通过向聚合反应溶液中加入用于第二步的水溶性烯属不饱和单体进行第二步反相悬浮聚合反应，使初级颗粒附聚，得到具有中值粒径（D ）为200〜500μm。

公开(公告)号：US20110068300A1

公开(公告)日：2011-03-24

申请号：US12956563

申请日：2010-11-30

申请人： Takayasu Taniguchi ,  Masayoshi Handa ,  Yasuhiro Nawata

发明人： Takayasu Taniguchi ,  Masayoshi Handa ,  Yasuhiro Nawata

IPC分类号： C09K3/00

CPC分类号： C08L101/14 ,  A61F13/8405 ,  A61L15/425 ,  A61L15/46 ,  A61L15/60 ,  A61L2300/102 ,  A61L2300/21 ,  A61L2300/404 ,  A61L2300/45 ,  B32B27/18

摘要： The object of the present invention is to provide a water-absorbing resin compound, wherein the water-absorbing resin compound can retain antibacterial properties of an antibacterial metal to suppress the emission of unpleasant odors even when an organic material exists in a system in the case of using an eluting-type antibacterial agent. Thus, the present invention relates to a water-absorbing resin compound, which comprises a water-absorbing resin, an antibacterial agent having a porous material incorporating an antibacterial metal, and a metal chelating agent. Further, the present invention also relates to an absorbing material, which comprises a water-absorbing resin compound of the present invention, and a hydrophilic fiber as well as an absorbing product, which comprises a liquid-permeable sheet and a liquid-non-permeable sheet, and an absorbing material comprising a water-absorbing resin compound of the present invention, and a hydrophilic fiber between the liquid-permeable sheet and the liquid-non-permeable sheet.

摘要翻译： 本发明的目的是提供一种吸水性树脂化合物，其中吸水性树脂化合物可以保持抗菌金属的抗菌性能，以抑制令人不快的气味的排放，即使当在该情况下的系统中存在有机材料时 使用洗脱型抗菌剂。 因此，本发明涉及一种吸水性树脂化合物，其包含吸水性树脂，具有包含抗菌金属的多孔材料的抗菌剂和金属螯合剂。 此外，本发明还涉及一种吸收材料，其包含本发明的吸水性树脂化合物和亲水性纤维以及吸收产品，其包含透液性片和不透液性的片 片材，以及包含本发明的吸水性树脂化合物的吸收材料和透液性片材与不透液性片材之间的亲水性纤维。

公开(公告)号：US07713623B2

公开(公告)日：2010-05-11

申请号：US10548595

申请日：2004-03-12

申请人： Kenya Matsuda ,  Yuji Kinpara ,  Tomoki Kawakita ,  Yasuhiro Nawata

发明人： Kenya Matsuda ,  Yuji Kinpara ,  Tomoki Kawakita ,  Yasuhiro Nawata

IPC分类号： B32B5/66

CPC分类号： C08J3/24 ,  C08F2/14 ,  C08F2/32 ,  C08J2300/14 ,  Y10T428/2982 ,  Y10T428/2991 ,  Y10T428/2998

摘要： A process for producing a water-absorbent resin particle comprising subjecting a water-soluble ethylenically unsaturated monomer to a reverse phase suspension polymerization, characterized in that the process for producing a water-absorbent resin particle comprises the steps of (A) subjecting the water-soluble ethylenically unsaturated monomer to a first-step reverse phase suspension polymerization in a hydrocarbon-based solvent using a water-soluble radical polymerization initiator in the presence of a surfactant and/or a polymeric protective colloid, and optionally an internal crosslinking agent; (B) carrying out at least one step of the procedures of adding an aqueous solution of a water-soluble ethylenically unsaturated monomer containing a water-soluble radical polymerization initiator and optionally an internal crosslinking agent to a reaction mixture after the termination of the first-step reverse phase suspension polymerization in a state that the surfactant and/or the polymeric protective colloid is dissolved in the hydrocarbon-based solvent, and subsequently subjecting the mixture to a reverse phase suspension polymerization; and (C) post-crosslinking the resulting water-absorbent resin.

摘要翻译： 1.一种吸水性树脂粒子的制造方法，其特征在于，使水溶性烯属不饱和单体进行反相悬浮聚合，其特征在于，所述吸水性树脂粒子的制造方法包括以下工序：（A） 在表面活性剂和/或聚合物保护胶体和任选的内部交联剂存在下，使用水溶性自由基聚合引发剂在烃基溶剂中进行第一步反相悬浮聚合; （B）进行至少一个步骤，在第一阶段结束后，向反应混合物中加入含有水溶性自由基聚合引发剂和任选的内部交联剂的水溶性烯属不饱和单体的水溶液， 在表面活性剂和/或聚合物保护胶体溶解在烃系溶剂中，然后使混合物进行反相悬浮聚合的状态下进行步骤反相悬浮聚合; 和（C）使得到的吸水性树脂进行后交联。

公开(公告)号：US20080119808A1

公开(公告)日：2008-05-22

申请号：US11666665

申请日：2005-11-11

申请人： Masayoshi Handa ,  Yasuhiro Nawata

发明人： Masayoshi Handa ,  Yasuhiro Nawata

IPC分类号： C08F20/06

CPC分类号： C08F220/06 ,  A61L15/60 ,  B01J2220/68

摘要： Water-absorbent resin particles, characterized in that the water-absorbent resin particles have a water-retention capacity of physiological saline (X) of from 30 to 70 g/g, that the water-retention capacity of physiological saline (X) and a water absorption index under pressure (Y) satisfy the relationship of the formula: [Water absorption index under pressure (Y)]≧150 −2[Water-retention capacity of physiological saline (X)], and that the water-absorbent resin particles have a liquid-suction rate from pulp of 20 g/g/5 minutes or more; and an absorbent material and an absorbent article, each in which the water-absorbent resin particles are used. The absorbent material in which the water-absorbent resin particles are used can be suitably used, for example, in absorbent articles such as disposable diapers and sanitary napkins.

摘要翻译： 吸水性树脂颗粒的特征在于，吸水性树脂颗粒的生理盐水（X）的保水能力为30〜70g / g，生理盐水（X）和 压力下的吸水指数（Y）满足下式的关系：[压力下的吸水指数（Y）]> = 150〜2 [生理盐水（X）的保水量）]，吸水性树脂 颗粒具有20g / g / 5分钟以上的纸浆的液体抽吸速率; 和吸收性材料和吸收性物品，其中使用吸水性树脂颗粒。 使用吸水性树脂颗粒的吸收材料可以适用于例如一次性尿布和卫生巾等吸收性物品。

公开(公告)号：US20070179261A1

公开(公告)日：2007-08-02

申请号：US10583564

申请日：2004-12-20

申请人： Shinichi Uda ,  Tomoki Kawakita ,  Yasuhiro Nawata

发明人： Shinichi Uda ,  Tomoki Kawakita ,  Yasuhiro Nawata

IPC分类号： C08F4/00

CPC分类号： A61L15/60 ,  C08F2/32

摘要： A process for preparing a water-absorbent resin comprising carrying out a reversed phase suspension polymerization in multi-steps of at least two steps when the water-absorbent resin is prepared by subjecting a water-soluble ethylenically unsaturated monomer to the reversed phase suspension polymerization, said process for preparing a water-absorbent resin being characterized by adding a phosphorus-containing compound to at least one step in the second and subsequent steps, to carry out the polymerization reaction. The water-absorbent resin can be suitably used in hygienic materials such as disposable diaper, incontinence pad and sanitary napkin, especially in disposable diaper.

摘要翻译： 一种制备吸水性树脂的方法，包括当通过使水溶性烯键式不饱和单体进行反相悬浮聚合制备吸水性树脂时，以多步骤的至少两个步骤进行反相悬浮聚合， 所述制备吸水性树脂的方法的特征在于在第二和随后的步骤中向至少一个步骤中加入含磷化合物进行聚合反应。 吸水性树脂可以适用于一次性尿布，失禁垫和卫生巾等卫生材料，特别是一次性尿布。

公开(公告)号：US20070015887A1

公开(公告)日：2007-01-18

申请号：US10555217

申请日：2004-05-12

申请人： Kazuhiro Yoshino ,  Yasuhiro Nawata

发明人： Kazuhiro Yoshino ,  Yasuhiro Nawata

IPC分类号： C08F4/30

CPC分类号： C08F2/32

摘要： A process for preparing a water-absorbent resin comprising carrying out a reverse phase suspension polymerization in multi-steps of at least two steps when the water-absorbent resin is prepared by subjecting a water-soluble ethylenically unsaturated monomer to the reverse phase suspension polymerization in the presence of a crosslinking agent, the process for preparing a water-absorbent resin being characterized by adding a water-soluble chain transfer agent in an amount of 0.000012 to 0.01 mole per 1 mole of the water-soluble ethylenically unsaturated monomer used in a polymerization reaction to at least one step in the second and subsequent steps of the multi-steps, to carry out the polymerization reaction. The water-absorbent resin can be suitably used in hygienic materials such as disposable diaper and sanitary napkin.

摘要翻译： 一种制备吸水性树脂的方法，包括当通过使水溶性烯键式不饱和单体进行反相悬浮聚合制备吸水性树脂时，以多步骤的至少两个步骤进行反相悬浮聚合 交联剂的存在，吸水性树脂的制备方法的特征在于，相对于1摩尔聚合所用的水溶性烯属不饱和单体，加入水溶性链转移剂的量为0.000012〜0.01摩尔 与多步骤的第二步和后续步骤中的至少一个步骤反应，进行聚合反应。 吸水性树脂可以适用于一次性尿布和卫生巾等卫生材料。

公开(公告)号：US20060074160A1

公开(公告)日：2006-04-06

申请号：US10540832

申请日：2003-11-21

申请人： Masayoshi Handa ,  Yasuhiro Nawata

发明人： Masayoshi Handa ,  Yasuhiro Nawata

IPC分类号： C08K5/09

CPC分类号： C08K5/005 ,  A61F13/53 ,  C08K3/30

摘要： A water-absorbent resin composition comprising an oxygen-containing reducing inorganic salt and a water-absorbent resin, wherein the iron content in the resin composition is at most 1 ppm; an absorbent having the above-mentioned water-absorbent resin composition and a hydrophilic fiber; and an absorbent article comprising the above-mentioned absorbent interposed between a liquid-permeable sheet and a liquid-impermeable sheet.

摘要翻译： 包含含氧还原性无机盐和吸水性树脂的吸水性树脂组合物，其中所述树脂组合物中的铁含量为至多1ppm; 具有上述吸水性树脂组合物和亲水性纤维的吸收剂; 以及吸收性物品，其包含介于透液性片材和不透液性片材之间的上述吸收剂。

公开(公告)号：US20050085604A1

公开(公告)日：2005-04-21

申请号：US10501507

申请日：2002-12-27

申请人： Masayoshi Handa ,  Takayasu Taniguchi ,  Yasuhiro Nawata ,  Masato Fujikake

发明人： Masayoshi Handa ,  Takayasu Taniguchi ,  Yasuhiro Nawata ,  Masato Fujikake

IPC分类号： A61F13/53 ,  A61F5/44 ,  A61F13/15 ,  A61F13/49 ,  A61L15/18 ,  A61L15/20 ,  A61L15/60 ,  C08F2/44 ,  C08F6/00 ,  C08F20/04 ,  C08F20/06 ,  C08K3/18 ,  C08K3/30 ,  C08K3/32 ,  C08K5/16 ,  C08K5/17 ,  C08L33/02 ,  C08F4/28

CPC分类号： C08F6/006 ,  A61L15/18 ,  A61L15/20 ,  A61L15/60 ,  C08F6/00 ,  C08F6/008 ,  C08F20/04 ,  C08F20/06 ,  C08K5/16 ,  C08L33/02

摘要： A process for preparing a water-absorbent resin made from an α,β-unsaturated carboxylic acid as an essential monomer characterized in that the process comprises allowing a metal chelating agent to be present at any step in the process in an amount of 0.001 to 6 parts by weight, based on 100 parts by weight of the α,β-unsaturated carboxylic acid; and adding a reducing agent or an oxidizing agent thereto in an amount of 0.001 to 6 parts by weight, based on 100 parts by weight of the α,β-unsaturated carboxylic acid before initiation of drying and/or during drying of a gelated product containing a water-absorbent resin obtained by polymerization.

摘要翻译： 一种制备由α，β-不饱和羧酸作为必需单体制成的吸水性树脂的方法，其特征在于该方法包括使金属螯合剂以0.001至6的量存在于该方法中的任何步骤 重量份，基于100重量份的α，β-不饱和羧酸; 并以0.001至6重量份的量加入还原剂或氧化剂，基于100重量份的α，β-不饱和羧酸，然后开始干燥和/或在含有 通过聚合获得的吸水性树脂。