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公开(公告)号:US20220298272A1
公开(公告)日:2022-09-22
申请号:US17642460
申请日:2020-08-27
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: FABRIZIO PIEMONTESI , ALESSANDRO MIGNOGNA , DARIO LIGUORI , GIAMPIERO MORINI , TIZIANO DALL'OCCO , GIANNI VITALE
Abstract: A solid catalyst component for the polymerization of olefins made from or containing a magnesium halide, a titanium compound having at least a Ti-halogen bond, a first electron donor compound selected from 1,3 diethers (DE), and a second electron donor compound selected from dicarbamates (DC), wherein the first and second electron donor compounds are present in a molar ratio DE:DC ranging from 4.5:1 to 20:1.
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公开(公告)号:US20200231723A1
公开(公告)日:2020-07-23
申请号:US16632175
申请日:2018-07-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: PAOLA MASSARI , CAROLINE CATHELIN , CLAUDIO CAVALIERI , MARCO CIARAFONI , ROBERTO PANTALEONI , GIAMPIERO MORINI , GIANNI VITALE , FABRIZIO PIEMONTESI , GIANNI COLLINA , BENEDETTA GADDI
IPC: C08F210/06 , C08J5/18
Abstract: A propylene 1-hexene copolymer containing from 5.7 to 7.7% by weight of 1-hexene derived units, based upon the total weight of the propylene 1-hexene copolymer, having:a) a solubility in xylene at 25° C. ranging from 7.0 wt % to 15.0 wt %, based upon the total weight of the propylene 1-hexene copolymer; b) a melting temperature, measured by DSC ranging from 143.0° C. to 148.0° C.; c) a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230° C./2.16 kg) from 3.5 to 8.0 g/10 min.; and d) a content of 1-hexene derived units in the fraction soluble in xylene at 25° C. ranging from 13.5 wt % to 18.5 wt %, based upon the total weight of the soluble fraction.
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公开(公告)号:US20180223084A1
公开(公告)日:2018-08-09
申请号:US15750799
申请日:2016-07-19
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: PAOLA MASSARI , CAROLINE CATHELIN , CLAUDIO CAVALIERI , MARCO CIARAFONI , ANDREA FELISATI , ANGELO FERRARO , GIAMPIERO MORINI , FABRIZIO PIEMONTESI , GIANNI VITALE
CPC classification number: C08L23/142 , B32B27/08 , B32B27/32 , B32B2250/242 , B32B2250/40 , B32B2307/412 , B32B2307/414 , B32B2307/548 , B32B2307/732 , B32B2307/75 , C08L23/14 , C08L2201/10 , C08L2203/162 , C08L2205/025 , C08L2308/00 , C08F210/06 , C08F2/001 , C08F4/6492 , C08F4/6574
Abstract: A multilayer film made from or containing a skin layer made from or containing a polyolefin composition made from or containing:A) from 19 wt % to 50 wt % of a propylene ethylene copolymer having an ethylene derived units content ranging from 1.5 wt % to 6.0 wt % and B) from 50 wt % to 81 wt % of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from 1.5 wt % to 6.0 wt % and 1-butene derived units content of between 4.8 wt % to 12.4 wt %; the sum of the amount of component A) and B) being 100; the composition being characterized by the following features: molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; the creep and recovery curve measured on the polymer fuse at 200° C. shows a maximum value between 600 and 1200 seconds, lower than 53×10−5 1/Pa.
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公开(公告)号:US20170066855A1
公开(公告)日:2017-03-09
申请号:US15309138
申请日:2015-04-28
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: PAOLA MASSARI , FABRIZIO PIEMONTESI , GIANNI VITALE , CAROLINE CATHELIN , GIAMPIERO MORINI , MARCO CIARAFONI , CLAUDIO CAVALIERI , TIZIANA CAPUTO
IPC: C08F210/06 , C08J5/18
CPC classification number: C08F210/06 , C08F210/02 , C08F2800/20 , C08J5/18 , C08J2323/14 , C08F210/16 , C08F2500/04 , C08F2500/12 , C08F2500/26 , C08F10/00 , C08F4/6492 , C08F4/6574
Abstract: The present disclosure relates to a propylene ethylene copolymer comprising: an ethylene content of between 1.8 and 10.0% by weight; a molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; a content of xylene soluble fraction (XS) and ethylene content (C2) that fulfills the following relationship: XS
Abstract translation: 一种丙烯乙烯共聚物,其特征在于以下特征:乙烯含量在1.8至10.0重量%之间; 分子量分布(MWD),以Mw / Mn表示,大于4.0; 二甲苯可溶成分(XS)和乙烯含量(C2)的含量满足下列关系:XS <(C2x2.1)-2.4其中:XS =在25℃下可溶于二甲苯的馏分的重量% C2 =通过NMR确定的共聚物中乙烯单元的重量%。
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15.
公开(公告)号:US20160304642A1
公开(公告)日:2016-10-20
申请号:US15031913
申请日:2014-10-21
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: BENEDETTA GADDI , MARCO BOCCHINO , GIANNI COLLINA , OFELIA FUSCO , SIMONA GUIDOTTI , ANTONIO MAZZUCCO , ROBERTO PANTALEONI , FABRIZIO PIEMONTESI
IPC: C08F210/02 , C08J9/00
CPC classification number: C08F210/02 , C08F10/06 , C08J9/0052 , C08J9/0066 , C08F210/06 , C08F210/16 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F4/6492 , C08F4/651 , C08F2/001 , C08F4/6545
Abstract: The present disclosure relates to a process for the preparation of a porous propylene carried out in the presence of a catalyst system comprising (a) a Ziegler-Natta catalyst containing at least two electron donor compounds, one of which is present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates, and the other being selected from 1,3 diethers, (b) an aluminum alkyl and comprising the following steps: i) contacting the catalyst components (a) and (b) for a period of time ranging from 1 to 60 minutes, at a temperature ranging from 35 to 55° C.; optionally, ii) pre-polymerizing with one or more olefins of formula CH2═CHR, where R is H or a C1-C10 hydrocarbon group, up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); and iii) polymerizing propylene in the optional presence of minor amounts of ethylene and/or C4-C10 alpha olefins for producing the porous propylene (co)polymer.
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