公开(公告)号：US20210309676A1

公开(公告)日：2021-10-07

申请号：US17267601

申请日：2019-07-25

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： SIMONA GUIDOTTI ,  DARIO LIGUORI ,  GIAMPIERO MORINI ,  GIANNI VITALE

IPC: C07F7/28 ,  C08F210/06 ,  C07F3/02 ,  C07F9/94

Abstract: A solid catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, made from or containing Mg, Ti, Bi, halogen and an electron donor obtained from a process including the steps:
(a) dissolving a Mg(OR)2 compound wherein R groups, equal to or different from each other, are C1-C15 hydrocarbon groups optionally containing a heteroatom selected from O, N and halogen, in an organic liquid medium, thereby forming a first liquid mixture; (b) contacting the first liquid mixture (a) with TiCl4, thereby forming a second liquid mixture absent a solid phase, and (c) subjecting the second liquid mixture (b) to conditions, whereby solid catalyst particles are formed, wherein (i) a Bi compound and (ii) a bidentate electron donor compound are present in one or more of steps (a) to (c) and/or contacted with the solid catalyst particles obtained from (c).

公开(公告)号：US20190248930A1

公开(公告)日：2019-08-15

申请号：US16337779

申请日：2017-09-25

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： SIMONA GUIDOTTI ,  TIZIANO DALL'OCCO ,  DARIO LIGUORI ,  GIAMPIERO MORINI

IPC: C08F10/02

CPC classification number: C08F10/02 ,  C08F210/16 ,  C08F2410/01 ,  C08F210/08 ,  C08F2500/12 ,  C08F4/651 ,  C08F4/6494 ,  C08F4/6567

Abstract: A process for the preparation of a solid catalyst component for the homo or copolymerization of olefins, wherein the solid catalyst component is made from or contains Mg, Ti, halogen and an electron donor selected from cycloalkyl ethers, wherein the process includes the steps of (a) dissolving a Mg based compound and a TiCl3 based compound in a liquid medium further made from or containing a cycloalkyl ether and a compound of formula R2OH where R2 is a C1-C20 hydrocarbon group, in which the Ti/Mg molar ratio ranges from 0.1 to 0.5, the cycloalkyl ether/Mg ratio ranges from 1 to 4 and the ROH/Mg molar ratio ranges from 1 to 4; and (b) adding, to the solution coming from step (a), SiCl4 in an amount such that the R2OH/SiCl4 molar ratio ranges from 0.5 to 1.5 and maintaining the temperature in the range 50-150° C. thereby precipitating the solid catalyst component particles.

公开(公告)号：US20230002516A1

公开(公告)日：2023-01-05

申请号：US17780177

申请日：2020-11-28

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： SIMONA GUIDOTTI ,  DARIO LIGUORI ,  GIAMPIERO MORINI

IPC: C08F4/654 ,  C08F4/651 ,  C08F4/649

Abstract: A catalyst for the polymerization of olefins made from or containing (a) a solid catalyst component containing Mg, Ti and optionally an internal electron donor compound (ID), (b) an aluminum alky compound, and (c) an external electron donor (ED) selected from non-aromatic diazo compounds.

公开(公告)号：US20210087307A1

公开(公告)日：2021-03-25

申请号：US16613655

申请日：2018-05-09

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： DIEGO BRITA ,  SIMONA GUIDOTTI

IPC: C08F10/06 ,  C08F4/16 ,  C08F4/02

Abstract: A catalyst mixture made from or containing (a) particles of a solid catalyst component comprising Ti, Mg, Cl, and (b) from 0.5 to 5.0% by weight, based upon the total weight of the mixture, of particles of a solid compound having particle size ranging from 0.1 μm to 1 mm containing more than 50% by weight of SiO2 units.

公开(公告)号：US20190284316A1

公开(公告)日：2019-09-19

申请号：US16317676

申请日：2017-07-07

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： TIZIANO DALL'OCCO ,  SIMONA GUIDOTTI ,  DARIO LIGUORI ,  GIAMPIERO MORINI

IPC: C08F210/16

Abstract: A catalyst component for the polymerization of olefins, comprising Ti, Mg, halogen, an electron donor (ID) selected from the group consisting of aliphatic cyclic ethers and alkyl esters of aliphatic monocarboxylic acids and a compound of a metal selected from the group consisting of Zn and Cu, wherein the catalyst component is devoid of Zn—C or Cu—C bonds and the Mg/Ti molar ratio ranges from 4.0 to 50.0.

公开(公告)号：US20210170380A1

公开(公告)日：2021-06-10

申请号：US16771845

申请日：2018-12-12

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： SIMONA GUIDOTTI ,  DARIO LIGUORI ,  GIAMPIERO MORINI

IPC: B01J31/12 ,  C08F4/654

Abstract: A Mg compound based catalyst precursor made from or containing up to 50% by mols, with respect to Mg, of a compound of formula K(OR1) wherein R1 is H or a C1-C10 hydrocarbon group. When treated with transition metal compounds, the precursor is converted into catalyst with high activity in olefin polymerization.

公开(公告)号：US20170073444A1

公开(公告)日：2017-03-16

申请号：US15309042

申请日：2015-05-06

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： FABRIZIO PIEMONTESI ,  CAROLINE CATHELIN ,  SIMONA GUIDOTTI ,  DARIO LIGUORI ,  GIAMPIERO MORINI ,  DAVIDE TARTARI ,  GIANNI VITALE

IPC: C08F210/06

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/26 ,  C08F4/6574

Abstract: The present disclosure relates to propylene-ethylene copolymers comprising an ethylene content of 0.1-10% by weight, a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 3.0 and a xylene soluble (XS) fraction content defined by values that fall below the line given by the equation XS=1.0296·e0.435C2. The propylene-ethylene copolymers advantageously exhibit high transparency and low melting temperatures.

Abstract translation: 本公开内容涉及丙烯 - 乙烯共聚物，其包含乙烯含量为0.1-10重量％，分子量分布（MWD），以Mw / Mn表示，大于3.0，二甲苯可溶（XS）部分含量 由低于由公式XS = 1.0296·e0.435C2给出的线的值定义。 丙烯 - 乙烯共聚物有利地表现出高透明度和低熔融温度。

公开(公告)号：US20210269564A1

公开(公告)日：2021-09-02

申请号：US16967587

申请日：2019-01-25

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： SIMONA GUIDOTTI ,  DARIO LIGUORI ,  GIAMPIERO MORINI ,  GIANNI VITALE

IPC: C08F110/06 ,  C08F4/02 ,  C08F4/20 ,  C08F4/646 ,  C08F4/657

Abstract: A solid catalyst component for the polymerization of olefins CH2═CHR, wherein R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, made from or containing Mg, Ti, Bi, a halogen and an electron donor.

公开(公告)号：US20160304642A1

公开(公告)日：2016-10-20

申请号：US15031913

申请日：2014-10-21

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： BENEDETTA GADDI ,  MARCO BOCCHINO ,  GIANNI COLLINA ,  OFELIA FUSCO ,  SIMONA GUIDOTTI ,  ANTONIO MAZZUCCO ,  ROBERTO PANTALEONI ,  FABRIZIO PIEMONTESI

IPC: C08F210/02 ,  C08J9/00

CPC classification number: C08F210/02 ,  C08F10/06 ,  C08J9/0052 ,  C08J9/0066 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/001 ,  C08F4/6545

Abstract: The present disclosure relates to a process for the preparation of a porous propylene carried out in the presence of a catalyst system comprising (a) a Ziegler-Natta catalyst containing at least two electron donor compounds, one of which is present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates, and the other being selected from 1,3 diethers, (b) an aluminum alkyl and comprising the following steps: i) contacting the catalyst components (a) and (b) for a period of time ranging from 1 to 60 minutes, at a temperature ranging from 35 to 55° C.; optionally, ii) pre-polymerizing with one or more olefins of formula CH2═CHR, where R is H or a C1-C10 hydrocarbon group, up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); and iii) polymerizing propylene in the optional presence of minor amounts of ethylene and/or C4-C10 alpha olefins for producing the porous propylene (co)polymer.

公开(公告)号：US20230028786A1

公开(公告)日：2023-01-26

申请号：US17781952

申请日：2020-11-30

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： SIMONA GUIDOTTI ,  DARIO LIGUORI ,  GIAMPIERO MORINI

IPC: C08F110/02 ,  C08F210/16

Abstract: A solid catalyst component for the homopolymerization or copolymerization of olefins, made from or containing Ti, Mg, halogen, and at least one non-aromatic diazo compounds.