公开(公告)号：US20210309676A1

公开(公告)日：2021-10-07

申请号：US17267601

申请日：2019-07-25

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： SIMONA GUIDOTTI ,  DARIO LIGUORI ,  GIAMPIERO MORINI ,  GIANNI VITALE

IPC: C07F7/28 ,  C08F210/06 ,  C07F3/02 ,  C07F9/94

Abstract: A solid catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, made from or containing Mg, Ti, Bi, halogen and an electron donor obtained from a process including the steps:
(a) dissolving a Mg(OR)2 compound wherein R groups, equal to or different from each other, are C1-C15 hydrocarbon groups optionally containing a heteroatom selected from O, N and halogen, in an organic liquid medium, thereby forming a first liquid mixture; (b) contacting the first liquid mixture (a) with TiCl4, thereby forming a second liquid mixture absent a solid phase, and (c) subjecting the second liquid mixture (b) to conditions, whereby solid catalyst particles are formed, wherein (i) a Bi compound and (ii) a bidentate electron donor compound are present in one or more of steps (a) to (c) and/or contacted with the solid catalyst particles obtained from (c).

公开(公告)号：US20220235212A1

公开(公告)日：2022-07-28

申请号：US17617771

申请日：2020-05-26

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： CLAUDIO CAVALIERI ,  PAOLA MASSARI ,  ISABELLA MARIA VITTORIA CAMURATI ,  ROBERTO PANTALEONI ,  GIANNI COLLINA ,  GIANNI VITALE ,  MARCO CIARAFONI ,  BENEDETTA GADDI

IPC: C08L23/16 ,  C08J5/18

Abstract: A propylene polymer composition made from or containing:
a) from 15 wt % to 35 wt % of a propylene 1-hexene copolymer containing from 6.2 to 8.5% by weight, of 1-hexene derived units and having a Melt Flow Rate from 3.5 to 8.5 g/10 min; b) from 15 wt % to 35 wt % of a propylene 1-hexene copolymer containing from 10.4 wt % to 14.5 wt %, of 1-hexene derived units and having a Melt Flow Rate from 3.5 to 8.5 g/10 min; and c) from 38 wt % to 68 wt % of a propylene ethylene copolymer containing from 3.4 wt % to 5.7 wt % of ethylene derived units and having a Melt Flow Rate from 3.5 to 12.0 g/10 min, wherein the sum of the amount of a), b) and c) being 100.

公开(公告)号：US20200308381A1

公开(公告)日：2020-10-01

申请号：US16617403

申请日：2018-05-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： GIANNI VITALE ,  FABRIZIO PIEMONTESI ,  BENEDETTA GADDI ,  GIANNI COLLINA ,  GIAMPIERO MORINI ,  CAROLINE CATHELIN ,  MARCO CIARAFONI ,  GIANPIERO FERRARO ,  CLAUDIO CAVALIERI ,  PAOLA MASSARI ,  MICHELE GRAZZI

IPC: C08L23/12 ,  C08F210/02 ,  C08F210/06 ,  C08F2/00 ,  C08F4/646 ,  C08F4/649 ,  C08F4/657

Abstract: A polypropylene composition made from or containing: A) from 50 wt % to 90 wt %, based upon the total weight of the polypropylene composition, of a propylene homopolymer; and B) from 10 wt % to 50 wt %, based upon the total weight of the polypropylene composition, of a copolymer of propylene and ethylene having from 30.0 wt % to 70.0 wt %, based upon the total weight of the copolymer, of ethylene derived units; the polypropylene composition having: i) an intrinsic viscosity of the fraction soluble in xylene at 25° C. between 2.2 and 4.0 dl/g; ii) a MFR L from 0.5 to 100 g/10 min; and iii) a xylene soluble fraction ranging from 10 wt % to 50 wt %, based upon the total weight of the polypropylene composition.

公开(公告)号：US20170066856A1

公开(公告)日：2017-03-09

申请号：US15309155

申请日：2015-04-28

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： PAOLA MASSARI ,  FABRIZIO PIEMONTESI ,  GIANNI VITALE ,  CAROLINE CATHELIN ,  GIAMPIERO MORINI ,  MARCO CIARAFONI ,  CLAUDIO CAVALIERI ,  ANDREA ISATI

IPC: C08F210/06

CPC classification number: C08F210/06 ,  C08L23/12 ,  C08L23/142 ,  C08L2203/16 ,  C08L2203/162 ,  C08F10/06 ,  C08F4/6574 ,  C08F4/6465 ,  C08F4/6492 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/26

Abstract: The present disclosure relates to a multilayer film characterized by one or more skin layers comprising propylene/ethylene copolymers characterized by the following features: an ethylene derived units content of between 1.0 wt % and 15.0% wt %; and a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 4.0;a content of xylene soluble fraction (XS) and an ethylene derived units content (C2) that fulfills the following relationship: XS

Abstract translation: 其中XS是在25℃下可溶于二甲苯的馏分的重量百分比，C2是通过NMR确定的共聚物中乙烯单元的重量百分比。

公开(公告)号：US20190055333A1

公开(公告)日：2019-02-21

申请号：US15768875

申请日：2016-10-22

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： PAOLA MASSARI ,  CAROLINE CATHELIN ,  GIAMPIERO MORINI ,  FABRIZIO PIEMONTESI ,  GIANNI VITALE ,  MARCO CIARAFONI ,  CLAUDIO CAVALIERI ,  ROBERTO PANTALEONI ,  MICHELE GRAZZI

IPC: C08F210/06 ,  C08L23/16 ,  C08L23/12 ,  C08F4/657 ,  C08F4/659 ,  C08F2/00

Abstract: A polypropylene composition made from or containing: A) from 50 wt % to 90 wt %; of a propylene homopolymer; B) from 10 wt % to 50 wt %; of a copolymer of propylene having from 30.0 wt % to 70.0 wt %, of ethylene derived units, based upon the total weight of the copolymer; the sum of the amount of component A) and B) being 100; the polypropylene composition having: i) an intrinsic viscosity of the fraction soluble in xylene at 25° C. between 2.2 to 4.0 dl/g; ii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, at 230° C. and 2.16 kg load) from 0.5 to 100 g/10 min; iii) a xylene soluble fraction ranging from 20 wt % to 50 wt %, based upon the total weight of the polypropylene composition; wherein the polypropylene composition being obtained by a polymerization process wherein the catalyst system contains bismuth.

公开(公告)号：US20180237564A1

公开(公告)日：2018-08-23

申请号：US15750123

申请日：2016-07-19

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： PAOLA MASSARI ,  FABRIZIO PIEMONTESI ,  GIANNI VITALE ,  CAROLINE CATHELIN ,  GIAMPIERO MORINI ,  CLAUDIO CAVALIERI ,  MARCO CIARAFONI ,  ROBERTO PANTALEONI

IPC: C08F210/06 ,  C08J5/18

Abstract: A polyolefin composition made from or containing:A) from about 19 wt % to about 50 wt % of a propylene ethylene copolymer having an ethylene derived units content ranging from about 1.5 wt % to about 6.0 wt %B) from about 50 wt % to about 81 wt % of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from about 1.5 wt % to about 6.0 wt % and 1-butene derived units content between about 4.8 wt % and about 12.4 wt %;the sum of the amount of component A) and B) being 100;the polyolefin composition being characterized by the following features: molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than about 4.0; the creep and recovery curve measured on the polymer fuse at 200° C. shows a maximum value between 600 and 1200 seconds, lower than about 53×10−4 l/Pa.

公开(公告)号：US20170073444A1

公开(公告)日：2017-03-16

申请号：US15309042

申请日：2015-05-06

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： FABRIZIO PIEMONTESI ,  CAROLINE CATHELIN ,  SIMONA GUIDOTTI ,  DARIO LIGUORI ,  GIAMPIERO MORINI ,  DAVIDE TARTARI ,  GIANNI VITALE

IPC: C08F210/06

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/26 ,  C08F4/6574

Abstract: The present disclosure relates to propylene-ethylene copolymers comprising an ethylene content of 0.1-10% by weight, a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 3.0 and a xylene soluble (XS) fraction content defined by values that fall below the line given by the equation XS=1.0296·e0.435C2. The propylene-ethylene copolymers advantageously exhibit high transparency and low melting temperatures.

Abstract translation: 本公开内容涉及丙烯 - 乙烯共聚物，其包含乙烯含量为0.1-10重量％，分子量分布（MWD），以Mw / Mn表示，大于3.0，二甲苯可溶（XS）部分含量 由低于由公式XS = 1.0296·e0.435C2给出的线的值定义。 丙烯 - 乙烯共聚物有利地表现出高透明度和低熔融温度。

公开(公告)号：US20220033539A1

公开(公告)日：2022-02-03

申请号：US17312264

申请日：2019-12-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： ALESSANDRO MIGNOGA ,  DARIO LIGUORI ,  GIAMPIERO MORINI ,  GIANNI VITALE

IPC: C08F4/651 ,  C08F10/06 ,  C08F4/659

Abstract: A solid catalyst component for the polymerization of olefins made from or containing Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from diphenol derivatives.

公开(公告)号：US20210179751A1

公开(公告)日：2021-06-17

申请号：US17268653

申请日：2019-08-12

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： GIANPIERO FERRARO ,  GIANNI VITALE ,  FABRIZIO PIEMONTESI ,  BENEDETTA GADDI ,  GIANNI COLLINA ,  GIAMPIERO MORINI ,  CAROLINE CATHELIN ,  MARCO CIARAFONI ,  CLAUDIO CAVALIERI

IPC: C08F210/06

Abstract: A propylene ethylene copolymer having the following features: an ethylene content of between 1.0 and 4.0% by weight; a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 4.0; a content of xylene soluble fraction (XS) and ethylene content (C2) that fulfills the following relationship: (C2×1.1)+1.25

公开(公告)号：US20190055330A1

公开(公告)日：2019-02-21

申请号：US15759143

申请日：2016-08-30

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： FABRIZIO PIEMONTESI ,  GIANNI VITALE ,  DARIO LIGUORI ,  GIAMPIERO MORINI

IPC: C08F10/06

Abstract: A catalyst for the homopolymerization or copolymerization of CH2═CHR olefins, made from or containing the product obtained by contacting: (i) a solid catalyst component made from or containing Ti, Mg, Cl, and an internal electron donor compound, wherein the solid catalyst component contains from about 0.1 to about 50 wt % of Bi, based upon the total weight of the solid catalyst component; (ii) an alkyl aluminum compound and, (iii) an external electron donor compound having the formula: (R1)aSi(OR2)b wherein R1 and R2 are independently selected from the group consisting of alkyl radicals with 1-8 carbon atoms and a is 0 or 1 and a+b=4.