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公开(公告)号：US20240417629A1
公开(公告)日：2024-12-19
申请号：US18700328
申请日：2022-10-04
Applicant: BASF SE
Inventor： Gisela HIEBER , Fulvio Giacomo BRUNETTI , Armin LANGE DE OLIVEIRA , Daniel KOEPKE , Christian MUELLER , Monica HAAG , Michael SCHREIBER , Oliver PILARSKI , Lisa LOEBNITZ , Julian MEYER-KIRSCHNER , Ralf BOEHLING
Abstract: A process for purifying a pyrolysis oil originating from pyrolysis of plastic waste is provided, wherein the process comprises a dehalogenation of the pyrolysis oil, wherein the dehalogenation comprises contacting the pyrolysis oil with one or more adsorption materials and/or subjecting the pyrolysis oil to a temperature of about 280° C. or more, wherein a halogen content of a resulting purified pyrolysis oil is about 55% or more lower compared to the halogen content of the untreated pyrolysis oil.
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公开(公告)号：US20240409822A1
公开(公告)日：2024-12-12
申请号：US18704575
申请日：2022-10-17
Applicant: BASF SE
Inventor： Gisela HIEBER , Dagmar Pascale KUNSMANN-KEITEL , Artem D. VITYUK , Elise M. MOPHETT , Armin LANGE DE OLIVEIRA , Daniel KOEPKE , Christian MUELLER , Monica HAAG , Michael SCHREIBER , Oliver PILARSKI , Lisa LOEBNITZ , Julian MEYER-KIRSCHNER
Abstract: A process for purifying a pyrolysis product. for example a pyrolysis oil and/or a pyrolysis gas. originating from pyrolysis of plastic waste is provided. wherein the process comprises contacting a vaporized pyrolysis oil with one or more adsorption materials and condensing the vaporized pyrolysis oil after it has been contacted with the one or more adsorption materials.
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公开(公告)号：US20240279059A1
公开(公告)日：2024-08-22
申请号：US18569631
申请日：2022-06-14
Applicant: BASF SE
Inventor： Armin LANGE DE OLIVEIRA , Sandra MAGNUS , Andreas KUSCHEL , Christiane KURETSCHKA , Marcelo Daniel KAUFMAN RECHULSKI
CPC classification number: C01B3/40 , B01J23/83 , C01B2203/0233 , C01B2203/0238 , C01B2203/1052 , C01B2203/1241
Abstract: A continuous process for reforming one or more hydrocarbons to a synthesis gas comprising hydrogen and carbon monoxide, the start-up phase of said process comprising (i) providing a reactor comprising a reaction zone which comprises a catalyst comprising a mixed oxide comprising cobalt and oxygen; (ii) continuously passing an inert gas stream through the reaction zone according to (i), said inert gas stream comprising one or more inert gases; (iii) continuously passing a reactant gas stream into the reaction zone obtained from (ii), wherein from 95 to 100 volume-% of the reactant gas stream passed into the reaction zone consist of the one or more hydrocarbons, carbon dioxide, and water; subjecting said reactant gas stream to reforming conditions in said reaction zone; and removing a product stream from said reaction zone, said product stream comprising hydrogen and carbon monoxide.
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公开(公告)号：US20210078925A1
公开(公告)日：2021-03-18
申请号：US16613307
申请日：2018-05-14
Applicant: BASF SE
Inventor： Stephan ZUEND , Rainer PAPP , Boris BREITSCHEIDEL , Armin LANGE DE OLIVEIRA
IPC: C07C29/149 , B01J23/72
Abstract: A process for preparing C4 to C10 monohydroxy compounds from a bottom fraction arising in the distillation of a crude mixture of C4 to C10 oxo-process aldehydes from cobalt-catalyzed or rhodium-catalyzed hydroformylation, or in the distillation of a crude mixture of C4 to C10 oxo-process alcohols, which comprises contacting the bottom fraction in the presence of hydrogen with a catalyst comprising copper oxide and aluminum oxide, at a temperature of 150° C. to 300° C. and a pressure of 20 bar to 300 bar and subjecting the resulting crude hydrogenation product to distillation, and the amount of C4 to C10 monohydroxy compounds present in the crude hydrogenation product after the hydrogenation being greater than the amount of C4 to C10 monohydroxy compounds given stoichiometrically from the hydrogenation of the ester and aldehyde compounds present in the bottom fraction, including the C4 to C10 monohydroxy compounds still present in the bottom fraction before the hydrogenation.
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