公开(公告)号：US09985306B2

公开(公告)日：2018-05-29

申请号：US14958806

申请日：2015-12-03

申请人： Intelligent Energy Limited

发明人： Alain Rosenzweig ,  Andrew J. Curello ,  Paul Spahr ,  Michael R. Curello

IPC分类号： C01B3/50 ,  H01M8/06 ,  H01M8/0606 ,  C01B3/06 ,  H01M8/04082 ,  H01M8/04537 ,  H01M8/0612 ,  H01M8/065 ,  H01M8/0444

CPC分类号： H01M8/0606 ,  C01B3/065 ,  C01B3/50 ,  C01B3/501 ,  C01B2203/066 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  H01M8/04216 ,  H01M8/0444 ,  H01M8/04656 ,  H01M8/0631 ,  H01M8/065 ,  Y02E60/324 ,  Y02E60/362 ,  Y02E60/364 ,  Y02E60/50

摘要： The present application is directed to a gas-generating apparatus (10). Hydrogen is generated within the gas-generating apparatus and is transported to a fuel cell. The generation of hydrogen is regulated automatically by the selective exposure of a catalyst (48) to the fuel mixture depending on the pressure inside the reaction chamber (28) of the gas-generating apparatus. Catalyst sealing mechanisms (40, 42) are provided at least partially within the reaction chamber to regulate the hydrogen pressure and to minimize the fluctuations in pressure of the hydrogen received by the fuel cell.

公开(公告)号：US09809453B2

公开(公告)日：2017-11-07

申请号：US13837544

申请日：2013-03-15

申请人： LG Fuel Cell Systems, Inc.

发明人： John R. Budge

IPC分类号： B01J23/96 ,  C01B3/40 ,  C01B3/38 ,  H01M8/0612 ,  B01J37/20 ,  B01J23/40 ,  B01J23/46 ,  B01J23/74 ,  H01M8/124

CPC分类号： C01B3/40 ,  B01J23/40 ,  B01J23/464 ,  B01J23/74 ,  B01J23/96 ,  B01J37/20 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0244 ,  C01B2203/066 ,  C01B2203/1052 ,  C01B2203/1235 ,  C01B2203/1258 ,  H01M8/0618 ,  H01M2008/1293 ,  Y02P20/142 ,  Y02P20/52

摘要： In some examples, a method for treating a reforming catalyst, the method comprising heating a catalyst metal used for reforming hydrocarbon in a reducing gas mixture environment. The reducing gas mixture comprises hydrogen and at least one sulfur-containing compound. The at least one sulfur-containing compound includes one or more of hydrogen sulfide, carbonyl sulfide, carbonyl disulfide and organic sulfur-containing compounds such as thiophenes, thiophanes, sulfides (RSH), disulfides (RS2R′), tri-sulfides (RS3R′) and mercaptans (RSR′).

公开(公告)号：US09789471B2

公开(公告)日：2017-10-17

申请号：US14878300

申请日：2015-10-08

申请人： KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY

发明人： Jeong Kwon Suh ,  Young Woo You ,  Ji Hye Lee ,  Hongchan Ahn ,  Tae Sun Chang ,  Beon Sik Kim

IPC分类号： B01J23/00 ,  B01J23/755 ,  B01J35/04 ,  B01J21/04 ,  B01J21/08 ,  B01J23/75 ,  B01J35/00 ,  B01J37/02 ,  B01J37/04 ,  B01J37/08 ,  C01B3/40

CPC分类号： B01J23/755 ,  B01J21/04 ,  B01J21/08 ,  B01J23/75 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0236 ,  B01J37/04 ,  B01J37/088 ,  C01B3/40 ,  C01B2203/0238 ,  C01B2203/1023 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  Y02P20/52

摘要： The present invention relates to a monolith catalyst for a carbon dioxide reforming reaction and to a preparation method for same, and more specifically the invention provides a preparation method for a monolith catalyst for a methane reforming reaction using carbon dioxide, the method comprising a step of mixing and impregnating a support in a metal precursor solution, coating a monolith substrate with the solution resulting from the mixing and impregnating, drying same and then calcining the monolith substrate coated with the solution resulting from the mixing and impregnating.

公开(公告)号：US20170210622A1

公开(公告)日：2017-07-27

申请号：US15328811

申请日：2015-07-27

申请人： Rouge H2 Engineering GmbH

发明人： Stephan Nestl ,  Viktor Hacker ,  Gernot Voitic

IPC分类号： C01B3/10 ,  C01B3/38 ,  B01J19/24 ,  C01B3/36

CPC分类号： C01B3/105 ,  B01J19/24 ,  C01B3/061 ,  C01B3/063 ,  C01B3/08 ,  C01B3/10 ,  C01B3/36 ,  C01B3/386 ,  C01B2203/0255 ,  C01B2203/0261 ,  C01B2203/04 ,  C01B2203/0495 ,  C01B2203/06 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1241 ,  Y02E60/36

摘要： The present invention relates to a device for producing compressed hydrogen, comprising a pressure-resistant reactor (1) with a reactor chamber having a metal-containing contact mass (2), wherein the reactor (1) comprises at least one feed line (3) for feeding fluids into the reactor chamber and at least one discharge line (4) for discharging fluids from the reactor chamber, wherein the at least one discharge line is provided with a device (5a, 5b, 5c, 5d) for controlling or regulating the flow rate, preferably having a valve, for adjusting the pressure within the reactor chamber, wherein a conveyance means is provided on at least one feed line for introducing a water-containing medium into the reactor chamber and wherein at least one discharge line (4) protrudes into the reactor chamber or opens directly into the reactor chamber, through which the compressed hydrogen is discharged from the reactor chamber, wherein the reactor chamber exhibits at least two areas that are separate from each other and connected in a gas-conducting manner, of which at least one area comprises the metal-containing contacting mass (2) and at least one additional area comprises at least one inert material (7, 13).

公开(公告)号：US09562196B2

公开(公告)日：2017-02-07

申请号：US14799901

申请日：2015-07-15

申请人： Expander Energy Inc.

发明人： Steve Kresnyak ,  Timothy William Giles

IPC分类号： B01J19/00 ,  B01J19/24 ,  C01B3/00 ,  C01B3/02 ,  C01B3/32 ,  C01B3/34 ,  C01B3/38 ,  C10G2/00 ,  C10K3/00 ,  C10K3/06 ,  C10L1/00 ,  C10L1/04 ,  C10J3/02 ,  C10J3/20 ,  C10J3/82 ,  C10L1/08 ,  C10J3/00 ,  C10J3/72

CPC分类号： C10G2/32 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/062 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1235 ,  C10G2/30 ,  C10G2/34 ,  C10G2300/1003 ,  C10G2300/1011 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/26 ,  C10J3/02 ,  C10J3/20 ,  C10J3/82 ,  C10J2300/1618 ,  C10J2300/1659 ,  C10J2300/1846 ,  C10K3/06 ,  C10L1/04 ,  C10L1/08 ,  C10L2200/0492 ,  C10L2270/026 ,  C10L2270/04 ,  C10L2290/04 ,  C10L2290/24 ,  C10L2290/42 ,  Y02E50/32 ,  Y02E60/324 ,  Y02P30/20 ,  Y02T50/678

摘要： An enhanced Fischer-Tropsch process for the synthesis of sulfur free, clean burning, green hydrocarbon fuels, examples of which include syndiesel and aviation fuel. Naphtha is destroyed in a hydrogen generator and recycled as feedstock to a syngas (FT) reactor in order to enhance the production of syndiesel from the reactor. A further variation integrates a second hydrogen generator capturing light hydrocarbon gas for conversion to hydrogen and carbon monoxide which supplements the Fischer-Tropsch reactor. The result is a considerable increase in the volume of syndiesel formulated. A system for effecting the process is also characterized in the specification.

摘要翻译： 用于合成无硫，清洁燃烧，绿色碳氢化合物燃料的增强的费 - 托方法，其实例包括聚合物和航空燃料。 石脑油在氢发生器中被破坏，并作为原料再循环到合成气（FT）反应器中，以便增强反应器中的混合物的产生。 另外的变体集成了第二个氢发生器捕获轻质烃气体转化成补充费 - 托反应器的氢气和一氧化碳。 结果是制备的混合物的体积大大增加。 实施该方法的系统也在说明书中表征。

公开(公告)号：US20160368766A1

公开(公告)日：2016-12-22

申请号：US15185741

申请日：2016-06-17

申请人： Joshua J. Stanislowski ,  Michael J. Holmes ,  Michael L. Swanson

发明人： Joshua J. Stanislowski ,  Michael J. Holmes ,  Michael L. Swanson

IPC分类号： C01B3/34 ,  C10J3/82

CPC分类号： C01B3/34 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/06 ,  C01B2203/0877 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1241 ,  C01B2203/1247 ,  C10G2300/1022 ,  C10J3/00 ,  C10J3/82 ,  C10J2300/0913 ,  C10J2300/0916 ,  C10J2300/093 ,  C10J2300/0946 ,  C10J2300/0959 ,  C10J2300/0976 ,  C10J2300/1846 ,  C10J2300/1853 ,  C10J2300/1884 ,  C10K1/06 ,  C10K3/04 ,  Y02E20/16 ,  Y02E20/18

摘要： Various embodiments disclosed relate to cooling shale gas via reaction of methane, light hydrocarbons, or a combination thereof, with water. In various embodiments, the present invention provides a method of cooling syngas. The method includes contacting the hot syngas with methane or light hydrocarbons. The hot syngas includes water and has a temperature of about 800° C. to about 3000° C. The contacting is effective to endothermically react the methane or light hydrocarbons with the water in the hot syngas to form carbon monoxide and hydrogen and to provide a cooled syngas having a lower temperature than the hot syngas.

摘要翻译： 所公开的各种实施例涉及通过甲烷，轻质烃或其组合与水的反应来冷却页岩气。 在各种实施方案中，本发明提供冷却合成气的方法。 该方法包括使热合成气与甲烷或轻质烃接触。 热合成气包括水，并且具有约800℃至约3000℃的温度。该接触有效地将甲烷或轻质烃与热合成气中的水吸热反应以形成一氧化碳和氢气，并提供 冷却的合成气的温度低于热合成气。

公开(公告)号：US09506400B2

公开(公告)日：2016-11-29

申请号：US14267427

申请日：2014-05-01

申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA

发明人： Kyoichi Tange ,  Norihiko Nakamura ,  Haruyuki Nakanishi ,  Hidekazu Arikawa

IPC分类号： C01B3/36 ,  B01J7/00 ,  F02B43/10 ,  C01B3/04 ,  F02M25/12 ,  H01M8/04 ,  H01M8/06 ,  C01B3/06

CPC分类号： F02B43/10 ,  C01B3/047 ,  C01B3/06 ,  C01B2203/066 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1064 ,  F02D19/0644 ,  F02D19/0671 ,  F02D19/081 ,  F02D41/0025 ,  F02M25/12 ,  H01M8/04201 ,  H01M8/0606 ,  Y02E60/364 ,  Y02E60/50 ,  Y02T10/121

摘要： A hydrogen generator that can be operated in a broad temperature range is disclosed, which comprises a first ammonia conversion part having a hydrogen-generating material which reacts with ammonia in a first temperature range so as to generate hydrogen; a second ammonia conversion part having an ammonia-decomposing catalyst which decomposes ammonia into hydrogen and nitrogen in a second temperature range; an ammonia supply part which supplies ammonia; and an ammonia supply passage which supplies ammonia from said ammonia supply part to the first and second ammonia conversion parts. The first temperature range includes temperatures lower than the second temperature range, and hydrogen is generated from ammonia by selectively using the first and second ammonia conversion parts. An ammonia-burning internal combustion engine and a fuel cell having the hydrogen generator are also disclosed.

摘要翻译： 公开了可在宽温度范围内操作的氢发生器，其包括具有产生氢的物质的第一氨转化部分，其在第一温度范围内与氨反应以产生氢; 具有在第二温度范围内将氨分解成氢和氮的氨分解催化剂的第二氨转化部分; 供应氨的氨供应部分; 以及将氨从氨供给部供给到第一和第二氨转化部的氨供给通路。 第一温度范围包括低于第二温度范围的温度，并且通过选择性地使用第一和第二氨转化部分从氨产生氢。 还公开了一种氨燃烧内燃机和具有氢发生器的燃料电池。

公开(公告)号：US20160137497A1

公开(公告)日：2016-05-19

申请号：US14941903

申请日：2015-11-16

申请人： Allen L. Johnson

发明人： Allen L. Johnson

IPC分类号： C01B3/32 ,  C01B31/02 ,  B01J31/02 ,  B01J35/12 ,  B01J35/00

CPC分类号： C01B3/326 ,  B01J23/52 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J31/0202 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/12 ,  B01J37/035 ,  C01B3/22 ,  C01B32/05 ,  C01B2203/0277 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1217 ,  C01B2203/1229

摘要： A eutectic supported catalyst system is used in catalyzed chemical reactions. A metal catalyst particle is supported in a eutectic medium. The system may have a) a eutectic composition of at least two metals forming the eutectic composition; and b) metal catalyst particles, preferably of nanometer dimensions, such as from 0.5 to 50 nm. The particles are dispersed throughout the eutectic composition when the eutectic composition is solid, and the particles are dispersed or suspended throughout the eutectic composition when the eutectic composition is in liquid form. At least one metal of the eutectic may comprises lead and a metal in the metal catalyst is a different metal then the metals in the eutectic. The eutectic may be in a liquid state and the metal catalyst particles may be in an equilibrium state within the eutectic.

摘要翻译： 在催化化学反应中使用共晶负载催化剂体系。 金属催化剂颗粒负载在共晶介质中。 该系统可以具有a）形成共晶组合物的至少两种金属的共晶组成; 和b）金属催化剂颗粒，优选为纳米尺寸，例如0.5至50nm。 当共晶组合物为固体时，颗粒分散在整个共晶组合物中，并且当共晶组合物为液体形式时，颗粒分散或悬浮在整个共晶组合物中。 共晶中的至少一种金属可以包含铅和金属催化剂中的金属是不同的金属，然后是共晶中的金属。 共晶体可以处于液态，并且金属催化剂颗粒可以在共晶体内处于平衡状态。

公开(公告)号：US09259728B2

公开(公告)日：2016-02-16

申请号：US12943547

申请日：2010-11-10

申请人： Hee-Yeon Kim ,  Nam-Jo Jeong ,  Seong-Ok Han

发明人： Hee-Yeon Kim ,  Nam-Jo Jeong ,  Seong-Ok Han

IPC分类号： B01J31/02 ,  B01J37/34 ,  B01J27/20 ,  B01J23/28 ,  B01J23/42 ,  B01J23/75 ,  B01J23/755 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  C01B3/40 ,  C01B31/08 ,  C10G2/00 ,  B01J31/06

CPC分类号： B01J37/341 ,  B01J23/28 ,  B01J23/42 ,  B01J23/75 ,  B01J23/755 ,  B01J31/06 ,  B01J35/002 ,  B01J35/006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/34 ,  B01J37/343 ,  C01B3/40 ,  C01B32/324 ,  C01B2203/1052 ,  C10G2/332 ,  C10G2/333 ,  C10G2300/70 ,  Y02P20/52

摘要： The present disclosure relates to a catalyst having metal catalyst nanoparticles supported on natural cellulose fibers and a method of preparing the same, whereby natural cellulose fibers are subjected to specific pretreatment to increase a surface area and form defects on the surface thereof and metal catalyst nanoparticles are then supported on the cellulose catalyst support in a highly dispersed state, thereby providing improved catalysis while allowing production of the catalyst at low cost. The catalyst may be utilized for various catalytic reactions.

公开(公告)号：US20160024391A1

公开(公告)日：2016-01-28

申请号：US14771849

申请日：2014-03-25

申请人： Haldor Topsøe A/S

发明人： Thomas Sandahl CHRISTENSEN ,  Ole Frej ALKILDE

IPC分类号： C10G2/00 ,  C01B3/38 ,  C07C7/148 ,  C10G47/00 ,  C07C5/03

CPC分类号： C10G2/32 ,  C01B3/382 ,  C01B3/386 ,  C01B2203/0244 ,  C01B2203/062 ,  C01B2203/063 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/1264 ,  C01B2203/127 ,  C07C5/03 ,  C07C7/148 ,  C10G47/00 ,  C10G65/12 ,  C10G2300/1022 ,  C10G2300/4081 ,  C10G2400/02 ,  C10K3/026

摘要： The invention relates to a process for the production of liquid hydrocarbons by the use of light-end fractions from downstream synthesis in the reforming section of the plant.

摘要翻译： 本发明涉及通过在植物的重整段中使用来自下游合成的轻馏分来生产液态烃的方法。