公开(公告)号：US20230369641A1

公开(公告)日：2023-11-16

申请号：US18225927

申请日：2023-07-25

Applicant: CORNING INCORPORATED ,  SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES

Inventor： Michael Edward Badding ,  Yinghong Chen ,  Xiao Huang ,  Cai Liu ,  Xinyuan Liu ,  Yanxia Ann Lu ,  Zhen Song ,  Zhaoyin Wen ,  Tongping Xiu ,  Nathan Michael Zink

IPC: H01M10/0562 ,  C04B35/488 ,  C04B35/626 ,  C04B35/01 ,  C04B35/495 ,  C04B35/64 ,  C04B35/486 ,  H01M10/052 ,  C04B35/48

CPC classification number: H01M10/0562 ,  C04B35/488 ,  C04B35/6261 ,  C04B35/01 ,  C04B35/6262 ,  C04B35/495 ,  C04B35/64 ,  C04B35/486 ,  H01M10/052 ,  C04B35/62605 ,  C04B35/481 ,  C04B2235/602 ,  C04B2235/3208 ,  C04B2235/3244 ,  C04B2235/3227 ,  C04B2235/3203 ,  C04B2235/79 ,  C04B2235/5436 ,  C04B2235/786 ,  C04B2235/77 ,  C04B2235/3225 ,  C04B2235/3217 ,  C04B2235/6025 ,  C04B2235/96 ,  C04B2235/764 ,  C04B2235/3206 ,  C04B2235/85

Abstract: A composite ceramic including: a lithium garnet major phase; and a grain growth inhibitor minor phase, as defined herein. Also disclosed is a method of making composite ceramic, pellets and tapes thereof, a solid electrolyte, and an electrochemical device including the solid electrolyte, as defined herein.

公开(公告)号：US11695118B2

公开(公告)日：2023-07-04

申请号：US16877293

申请日：2020-05-18

Applicant: Corning Incorporated ,  Shanghai Institute of Ceramics Chinese Academy

Inventor： Michael Edward Badding ,  Jun Jin ,  Zhen Song ,  Qing Wang ,  Zhaoyin Wen ,  Tongping Xiu

IPC: H01M4/58 ,  H01M4/66 ,  H01M4/36 ,  H01M10/0562 ,  H01M10/0565 ,  H01M10/052 ,  H01M4/131

CPC classification number: H01M4/5815 ,  H01M4/131 ,  H01M4/366 ,  H01M4/663 ,  H01M4/664 ,  H01M10/052 ,  H01M10/0562 ,  H01M10/0565

Abstract: A lithium-sulfur battery includes: a substrate; a composite cathode disposed on the substrate; a solid-state electrolyte disposed on the composite cathode; and a lithium anode disposed on the solid-state electrolyte, such that the composite cathode comprises: active elemental sulfur, conductive carbon, sulfide electrolyte, and ionic liquid.

公开(公告)号：US11605836B2

公开(公告)日：2023-03-14

申请号：US17196355

申请日：2021-03-09

Applicant: Corning Incorporated ,  Shanghai Institute of Ceramics, Chinese Academy of Sciences

Inventor： Michael Edward Badding ,  Jun Jin ,  Zhen Song ,  Jianmeng Su ,  Zhaoyin Wen ,  Tongping Xiu

IPC: H01M10/0585 ,  H01M10/052 ,  H01M10/0562 ,  H01M4/36 ,  H01M4/62 ,  H01M4/38 ,  H01M4/02

Abstract: A lithium-metal battery, includes: a substrate; a cathode disposed on the substrate; a garnet solid-state electrolyte disposed on the cathode; and a lithium anode disposed on the garnet solid-state electrolyte, such that a discoloration layer is disposed at an interface of the lithium anode and garnet solid-state electrolyte, the discoloration layer includes: a first portion; and a second portion, such that the first portion has a lithium component and the second portion has a garnet component. A method of forming a lithium-metal battery, includes: stacking a garnet source with at least one lithium source; and heating the stack at a temperature of at least 300° C. for a time in a range of 1 sec to 20 min to form a discoloration layer, such that the discoloration layer is disposed at an interface of the garnet source and the lithium source.

公开(公告)号：US20220085405A1

公开(公告)日：2022-03-17

申请号：US17101853

申请日：2020-11-23

Applicant: Corning Incorporated ,  Shanghai Institute of Ceramics, Chinese Academy of Sciences

Inventor： Jun Jin ,  Yadong Ruan ,  Zhaoyin Wen

IPC: H01M10/0562 ,  H01M10/052 ,  C01G35/00 ,  C01G41/00 ,  C01G25/00

Abstract: A modified garnet-type solid electrolyte, includes: a garnet-type solid electrolyte; a modification layer, such that the modification layer is formed on at least one side of the garnet-type solid electrolyte, and possesses a three-dimensional crosslinking structure comprising at least one strongly acidic lithium salt and at least one weakly acidic lithium salt. A method of forming a modified garnet-type solid electrolyte, includes: exposing a garnet-type solid electrolyte in air to form a pre-passivation layer; mixing solutions of strong acid and weakly acidic salt to form a mixed solution; chemically treating at least one side of the garnet-type solid electrolyte with the mixed solution; and forming a modification layer on the at least one side of the garnet-type solid electrolyte.

公开(公告)号：US20210347697A1

公开(公告)日：2021-11-11

申请号：US17308646

申请日：2021-05-05

Applicant: Corning Incorporated ,  Shanghai Institute of Ceramics, Chinese Academy of Sciences

Inventor： Michael Edward Badding ,  Jun Jin ,  Zhen Song ,  Jianmeng Su ,  Zhaoyin Wen ,  Tongping Xiu ,  Chujun Zheng

IPC: C04B35/48 ,  C04B35/465 ,  H01M10/0525 ,  H01M10/0562

Abstract: A sintered composite ceramic includes: a lithium-garnet major phase; and a lithium-rich minor phase, such that the lithium-rich minor phase has LixTiO(x+4)/2, with 0.66≤x≤4. The sintered composite ceramic may exhibit a relative density of at least 90% of a theoretical maximum density of the ceramic, an ionic conductivity of at least 0.35 mS·cm−1, or a critical current density (CCD) of at least 1.0 mA·cm−2.

公开(公告)号：US12230766B2

公开(公告)日：2025-02-18

申请号：US18110045

申请日：2023-02-15

Applicant: Corning Incorporated ,  Shanghai Institute of Ceramics, Chinese Academy of Sciences

Inventor： Michael Edward Badding ,  Jun Jin ,  Zhen Song ,  Jianmeng Su ,  Zhaoyin Wen ,  Tongping Xiu

IPC: H01M10/0585 ,  H01M4/02 ,  H01M4/36 ,  H01M4/38 ,  H01M4/62 ,  H01M10/052 ,  H01M10/0562

Abstract: A lithium-metal battery, includes: a substrate; a cathode disposed on the substrate; a garnet solid-state electrolyte disposed on the cathode; and a lithium anode disposed on the garnet solid-state electrolyte, such that a modification layer is disposed at an interface of the lithium anode and garnet solid-state electrolyte, the modification layer includes: a first portion; and a second portion, such that the first portion has a lithium component and the second portion has a garnet component. A method of forming a lithium-metal battery, includes: stacking a garnet source with at least one lithium source; and heating the stack at a temperature of at least 300° C. for a time in a range of 1 sec to 20 min to form a modification layer, such that the modification layer is disposed at an interface of the garnet source and the lithium source.

公开(公告)号：US20230344010A1

公开(公告)日：2023-10-26

申请号：US18136603

申请日：2023-04-19

Applicant: CORNING INCORPORATED ,  Shanghai Institute of Ceramics, Chinese Academy of Sciences

Inventor： Michael Edward Badding ,  Mingli Cai ,  Jun Jin ,  Zhen Song ,  Zhaoyin Wen ,  Tongping Xiu ,  Liu Yao

IPC: H01M4/58 ,  H01M4/525 ,  H01M10/0562 ,  H01M4/36 ,  H01M10/0569 ,  H01M4/505 ,  H01M4/131

CPC classification number: H01M10/0569 ,  H01M4/131 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M10/0562 ,  H01M2300/0028 ,  H01M2300/0071 ,  H01M2300/0094

Abstract: A battery includes a substrate; a cathode disposed on the substrate; at least one interlayer disposed on the cathode; a solid-state electrolyte (SSE) disposed on the interlayer; and a lithium anode disposed on the solid-state electrolyte, such that the at least one interlayer is a deep-eutectic-solvent-based (DES) electrolyte.

公开(公告)号：US11749836B2

公开(公告)日：2023-09-05

申请号：US17682281

申请日：2022-02-28

Applicant: CORNING INCORPORATED ,  SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES

Inventor： Michael Edward Badding ,  Yinghong Chen ,  Xiao Huang ,  Cai Liu ,  Xinyuan Liu ,  Yanxia Ann Lu ,  Zhen Song ,  Zhaoyin Wen ,  Tongping Xiu ,  Nathan Michael Zink

IPC: H01M10/0562 ,  H01M10/052 ,  C04B35/486 ,  C04B35/495 ,  C04B35/64 ,  C04B35/48 ,  C04B35/626 ,  C04B35/01 ,  C04B35/488

CPC classification number: H01M10/0562 ,  C04B35/01 ,  C04B35/481 ,  C04B35/486 ,  C04B35/488 ,  C04B35/495 ,  C04B35/6261 ,  C04B35/6262 ,  C04B35/62605 ,  C04B35/64 ,  H01M10/052 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3217 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3244 ,  C04B2235/5436 ,  C04B2235/602 ,  C04B2235/6025 ,  C04B2235/764 ,  C04B2235/77 ,  C04B2235/786 ,  C04B2235/79 ,  C04B2235/85 ,  C04B2235/96

Abstract: A composite ceramic including: a lithium garnet major phase; and a grain growth inhibitor minor phase, as defined herein. Also disclosed is a method of making composite ceramic, pellets and tapes thereof, a solid electrolyte, and an electrochemical device including the solid electrolyte, as defined herein.

公开(公告)号：US20220359908A1

公开(公告)日：2022-11-10

申请号：US17682281

申请日：2022-02-28

Applicant: CORNING INCORPORATED ,  SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES

Inventor： Michael Edward Badding ,  Yinghong Chen ,  Xiao Huang ,  Cai Liu ,  Xinyuan Liu ,  Yanxia Ann Lu ,  Zhen Song ,  Zhaoyin Wen ,  Tongping Xiu ,  Nathan Michael Zink

IPC: H01M10/0562 ,  H01M10/052 ,  C04B35/486 ,  C04B35/495 ,  C04B35/64 ,  C04B35/48 ,  C04B35/626 ,  C04B35/01 ,  C04B35/488

Abstract: A composite ceramic including: a lithium garnet major phase; and a grain growth inhibitor minor phase, as defined herein. Also disclosed is a method of making composite ceramic, pellets and tapes thereof, a solid electrolyte, and an electrochemical device including the solid electrolyte, as defined herein.

公开(公告)号：US20210288352A1

公开(公告)日：2021-09-16

申请号：US17196355

申请日：2021-03-09

Applicant: Corning Incorporated ,  Shanghai Institute of Ceramics, Chinese Academy of Sciences

Inventor： Michael Edward Badding ,  Jun Jin ,  Zhen Song ,  Jianmeng Su ,  Zhaoyin Wen ,  Tongping Xiu

IPC: H01M10/0585 ,  H01M10/052 ,  H01M10/0562 ,  H01M4/38 ,  H01M4/36 ,  H01M4/62

Abstract: A lithium-metal battery, includes: a substrate; a cathode disposed on the substrate; a garnet solid-state electrolyte disposed on the cathode; and a lithium anode disposed on the garnet solid-state electrolyte, such that a discoloration layer is disposed at an interface of the lithium anode and garnet solid-state electrolyte, the discoloration layer includes: a first portion; and a second portion, such that the first portion has a lithium component and the second portion has a garnet component. A method of forming a lithium-metal battery, includes: stacking a garnet source with at least one lithium source; and heating the stack at a temperature of at least 300° C. for a time in a range of 1 sec to 20 min to form a discoloration layer, such that the discoloration layer is disposed at an interface of the garnet source and the lithium source.