公开(公告)号：US20110313212A1

公开(公告)日：2011-12-22

申请号：US13192835

申请日：2011-07-28

申请人： Tom N. Kalnes ,  John Q. Chen ,  Joseph A. Kocal ,  Tao Zhang ,  Aiqin Wang ,  Mingyuan Zheng ,  Changzhi Li ,  Jifeng Pang

发明人： Tom N. Kalnes ,  John Q. Chen ,  Joseph A. Kocal ,  Tao Zhang ,  Aiqin Wang ,  Mingyuan Zheng ,  Changzhi Li ,  Jifeng Pang

IPC分类号： C07C29/74

CPC分类号： C07C29/132 ,  C07C31/20

摘要： A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.

摘要翻译： 以包含纤维素的原料生成至少一种多元醇的催化方法是以连续方式进行的。 该方法包括使含有纤维素的氢，水和原料与催化剂连续地接触，以产生包含至少一种多元醇，水，氢和至少一种共同产物的流出物流。 将水，氢和至少一种副产物与流出物流分离并再循环至反应区。 从流出物流中回收多元醇。

公开(公告)号：US20110312487A1

公开(公告)日：2011-12-22

申请号：US13192907

申请日：2011-07-28

申请人： John Q. Chen ,  Tom N. Kalnes ,  Joseph A. Kocal

发明人： John Q. Chen ,  Tom N. Kalnes ,  Joseph A. Kocal

IPC分类号： B01J23/46 ,  B01J23/44 ,  B01J23/755 ,  B01J21/18 ,  B01J21/04 ,  B01J21/06 ,  B01J21/08 ,  B01J21/10 ,  B01J27/224 ,  B01J21/12 ,  B01J29/04 ,  B01J21/16 ,  B01J27/24 ,  B01J23/652 ,  B01J23/883 ,  B01J23/888 ,  B01J23/42

CPC分类号： B01J23/30 ,  B01J21/18 ,  B01J23/40 ,  B01J23/755 ,  B01J27/188 ,  B01J35/0006 ,  B01J37/0201

摘要： A catalyst system for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner. Generating the polyol involves, contacting, hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one unsupported component and at least one supported component.

摘要翻译： 以连续或间歇的方式进行从包含糖的原料产生至少一种多元醇的催化剂体系。 产生多元醇包括使氢，水和包含糖的原料与催化剂体系接触以产生包含至少一种多元醇的流出物流并从流出物流中回收多元醇。 催化剂体系包含至少一种未负载的组分和至少一种负载的组分。

公开(公告)号：US20110237852A1

公开(公告)日：2011-09-29

申请号：US13156976

申请日：2011-06-09

申请人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

发明人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

IPC分类号： C10G3/00 ,  C10G99/00

CPC分类号： C10L1/08 ,  C10G2300/1003 ,  C10G2300/1007 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/207 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/28 ,  Y02E50/13 ,  Y02P30/20

摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant and animal fats and oils, the process providing for sulfur management. The process involves catalytically treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel. The hydrocarbon fraction is isomerized to improve cold flow properties. A selective separation such as a hot high pressure hydrogen stripper is used to remove at least the carbon oxides from the first zone effluent before entering the isomerization zone, and to provide liquid recycle to the treating zone at pressure and temperature. A vapor stream is separated from the isomerization effluent and at least carbon dioxide is removed using at least one selective or flexible amine solution absorber. The resulting hydrogen-rich stream is recycled to the deoxygenation reaction zone

摘要翻译： 已经开发了用于从可再生原料如植物和动物脂肪和油生产柴油沸点燃料的方法，该方法提供硫管理。 该方法涉及通过氢化和脱氧催化处理可再生原料以提供可用作柴油沸程燃料的烃馏分。 烃馏分异构化以改善冷流动性能。 在进入异构化区之前，使用诸如热高压氢气汽提器的选择性分离来从第一区流出物中至少除去碳氧化物，并在压力和温度下向处理区提供液体循环。 将蒸汽流与异构化流出物分离，并使用至少一种选择性或柔性的胺溶液吸收剂除去至少二氧化碳。 将所得富氢流循环至脱氧反应区

公开(公告)号：US07982077B2

公开(公告)日：2011-07-19

申请号：US12193176

申请日：2008-08-18

申请人： Tom N. Kalnes ,  Terry L. Marker ,  John P. Brady

发明人： Tom N. Kalnes ,  Terry L. Marker ,  John P. Brady

IPC分类号： C07C1/00 ,  C07C4/00

CPC分类号： C10G3/45 ,  B01D2257/504 ,  C10G3/46 ,  C10G3/47 ,  C10G3/50 ,  C10G45/58 ,  C10G2300/1003 ,  C10G2300/1007 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/201 ,  C10G2300/207 ,  C10G2300/4081 ,  C10G2400/04 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20

摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as fats and oils from plants and animals where the process provides for sulfur-component management. The process involves catalytically treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel. A selective separation such as a hot high pressure hydrogen stripper may be used to remove at least the carbon oxides from the first zone effluent and provide a liquid recycle stream at pressure and temperature. A vapor stream is separated from the net process effluent and at least carbon dioxide is removed using at least one selective or flexible amine absorber. The resulting hydrogen-rich stream is recycled to the reaction zone.

摘要翻译： 已经开发了一种从可再生原料生产柴油沸点燃料的方法，例如来自植物和动物的脂肪和油，其中该方法提供硫成分管理。 该方法涉及通过氢化和脱氧催化处理可再生原料以提供可用作柴油沸程燃料的烃馏分。 选择性分离如热的高压氢气汽提器可用于从第一区流出物中至少除去碳氧化物，并在压力和温度下提供液体循环流。 蒸汽流与净处理流出物分离，并且使用至少一种选择性或柔性胺吸收剂除去至少二氧化碳。 将所得富氢流循环至反应区。

公开(公告)号：US07915460B2

公开(公告)日：2011-03-29

申请号：US12193170

申请日：2008-08-18

申请人： Tom N. Kalnes ,  John P. Brady ,  Marco Di Stanislao

发明人： Tom N. Kalnes ,  John P. Brady ,  Marco Di Stanislao

IPC分类号： C10G1/00

CPC分类号： C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/50 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1022 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/28 ,  C12N2310/30 ,  Y02E50/13 ,  Y02P30/20

摘要： A process has been developed for producing diesel boiling range fuel or fuel blending component from renewable feedstocks such as plant oils and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating i.e. decarboxylating and/or hydrodeoxygenating to provide a hydrocarbon fraction useful as a diesel fuel. The hydrocarbon fraction is isomerized to improve cold flow properties. At least one interstage stream of the hydrogenating and deoxygenating reaction zone is heat exchanged with the feed to the isomerization reaction zone, and/or the effluent of the hydrogenating and deoxygenating reaction zone is heat exchanged with the feed to the isomerization reaction zone.

摘要翻译： 已经开发了用于从可再生原料如植物油和油脂生产柴油沸程燃料或燃料混合组分的方法。 该方法包括通过氢化和脱氧处理可再生原料，即脱羧和/或加氢脱氧以提供可用作柴油燃料的烃馏分。 烃馏分异构化以改善冷流动性能。 氢化和脱氧反应区的至少一个级间流与异构化反应区的进料热交换，和/或氢化和脱氧反应区的流出物与异构化反应区的进料热交换。

公开(公告)号：US20110024327A1

公开(公告)日：2011-02-03

申请号：US12899221

申请日：2010-10-06

申请人： Terry L. Marker ,  Peter Kokayeff ,  Suheil F. Abdo ,  Tom N. Kalnes

发明人： Terry L. Marker ,  Peter Kokayeff ,  Suheil F. Abdo ,  Tom N. Kalnes

IPC分类号： C10G45/00

CPC分类号： C10G3/50 ,  C10G3/46 ,  C10G3/47 ,  C10G2300/1014 ,  C10G2300/1022 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2400/04 ,  Y02P30/20

摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant oils, animal fats and oils, and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide a diesel boiling range fuel hydrocarbon product. If desired, the hydrocarbon product can be isomerized to improve cold flow properties. A portion of the hydrocarbon product is recycled to the treatment zone to increase the hydrogen solubility of the reaction mixture.

摘要翻译： 已经开发了用于从可再生原料如植物油，动物油脂和油脂生产柴油沸点燃料的方法。 该方法包括通过氢化和脱氧处理可再生原料以提供柴油沸程燃料烃产物。 如果需要，烃产物可被异构化以改善冷流动性能。 一部分烃产物被再循环到处理区以提高反应混合物的氢溶解度。

公开(公告)号：US20100122939A1

公开(公告)日：2010-05-20

申请号：US12271857

申请日：2008-11-15

申请人： Lorenz J. Bauer ,  Tom N. Kalnes ,  James F. McGehee

发明人： Lorenz J. Bauer ,  Tom N. Kalnes ,  James F. McGehee

IPC分类号： C10G1/00 ,  C10G67/06 ,  C10G25/00

CPC分类号： C10G47/26 ,  C10G67/02

摘要： The recovery of solids, and particularly solid particulates used as catalysts in slurry hydroprocessing, from asphaltene containing hydrocarbons is improved by controlling asphaltene precipitation. The formation of agglomerates of the solid particulates, having an increased diameter, results in the presence of precipitated asphaltenes, possibly due to flocculation. Asphaltene precipitation is controlled by varying process parameters or introducing additional diluent or flush streams that change the polarity of an asphaltene containing liquid product recovered from an effluent of a slurry hydroprocessing reaction zone.

摘要翻译： 通过控制沥青质沉淀，改善了含沥青质烃的固体，特别是用作浆料加氢处理催化剂的固体颗粒。 具有直径增加的固体颗粒的附聚物的形成导致沉淀的沥青质的存在，这可能是由于絮凝。 沥青质沉淀通过变化的工艺参数控制或引入另外的稀释剂或冲洗流，其改变从浆料加氢处理反应区的流出物回收的含沥青质的液体产物的极性。

公开(公告)号：US20100087693A1

公开(公告)日：2010-04-08

申请号：US12633253

申请日：2009-12-08

申请人： Tom N. Kalnes ,  Robert B. James, JR. ,  Daniel H. Wei ,  Bryan K. Glover

发明人： Tom N. Kalnes ,  Robert B. James, JR. ,  Daniel H. Wei ,  Bryan K. Glover

IPC分类号： C07C1/00

CPC分类号： C10G11/16 ,  C07C1/20 ,  C07C1/24 ,  C07C4/06 ,  C10G3/42 ,  C10G3/57 ,  C10G11/14 ,  C10G2300/4081 ,  C10G2400/20 ,  C07C11/02

摘要： Improved processing of an oxygenate-containing feedstock for increased production or yield of light olefins. Such processing involves oxygenate conversion to olefins and subsequent cracking of heavier olefins wherein at least a portion of the products from each of the reactors is elevated in pressure, using a common compressor, prior to being routed to a common product fractionation and recovery section. In one particular embodiment, the cracked product gas can be treated to remove acid gas therefrom. In another embodiment, the olefin cracking reactor is a moving bed reactor.

摘要翻译： 改进含氧化合物原料的加工，以提高轻质烯烃的生产或产率。 这种处理涉及含氧化合物转化为烯烃并随后开裂较重的烯烃，其中使用普通的压缩机将来自每个反应器的产物的至少一部分在压力下升高，然后被送至共同的产物分馏和回收段。 在一个具体实施方案中，可以处理裂化产物气体以从其中除去酸性气体。 在另一个实施方案中，烯烃裂解反应器是移动床反应器。

公开(公告)号：US20100048965A1

公开(公告)日：2010-02-25

申请号：US12610108

申请日：2009-10-30

申请人： Tom N. Kalnes ,  Robert B. James, JR. ,  Daniel H. Wei ,  Bryan K. Glover

发明人： Tom N. Kalnes ,  Robert B. James, JR. ,  Daniel H. Wei ,  Bryan K. Glover

IPC分类号： C07C1/00

CPC分类号： C07C1/20 ,  C07C1/24 ,  C07C4/06 ,  C10G3/42 ,  C10G3/57 ,  C10G11/18 ,  C10G2400/20 ,  Y02P30/42 ,  Y02P30/48 ,  C07C11/02

摘要： Improved processing of an oxygenate-containing feedstock for increased production or yield of light olefins. Such processing involves oxygenate conversion to olefins and subsequent cracking of heavier olefins wherein at least a portion of the products from each of the reactors is elevated in pressure, using a common compressor, prior to being routed to a common product fractionation and recovery section. In one particular embodiment, the cracked product gas can be treated to remove acid gas therefrom. In another embodiment, the olefin cracking reactor is a moving bed reactor.

公开(公告)号：US20090077865A1

公开(公告)日：2009-03-26

申请号：US12193170

申请日：2008-08-18

申请人： Tom N. Kalnes ,  John P. Brady ,  Marco Di Stanislao

发明人： Tom N. Kalnes ,  John P. Brady ,  Marco Di Stanislao

IPC分类号： C10L1/02

CPC分类号： C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/50 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1022 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/28 ,  C12N2310/30 ,  Y02E50/13 ,  Y02P30/20

摘要： A process has been developed for producing diesel boiling range fuel or fuel blending component from renewable feedstocks such as plant oils and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating i.e. decarboxylating and/or hydrodeoxygenating to provide a hydrocarbon fraction useful as a diesel fuel. The hydrocarbon fraction is isomerized to improve cold flow properties. At least one interstage stream of the hydrogenating and deoxygenating reaction zone is heat exchanged with the feed to the isomerization reaction zone, and/or the effluent of the hydrogenating and deoxygenating reaction zone is heat exchanged with the feed to the isomerization reaction zone.

摘要翻译： 已经开发了用于从可再生原料如植物油和油脂生产柴油沸程燃料或燃料混合组分的方法。 该方法包括通过氢化和脱氧处理可再生原料，即脱羧和/或加氢脱氧以提供可用作柴油燃料的烃馏分。 烃馏分异构化以改善冷流动性能。 氢化和脱氧反应区的至少一个级间流与异构化反应区的进料热交换，和/或氢化和脱氧反应区的流出物与异构化反应区的进料热交换。