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公开(公告)号：US09079987B2
公开(公告)日：2015-07-14
申请号：US14512650
申请日：2014-10-13
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor： John N. Argyropoulos , Paul Foley , Eric Greyson , Jeff R. Anderson , Gary E. Spilman , Caroline Slone , Nahrain E. Kamber
IPC: C08G12/02 , C08G14/00 , C08F283/02 , C08G63/12 , C09J133/06 , C08F22/10 , C08G63/91 , C09D135/02 , C09D167/08
CPC classification number: C09D167/08 , C08F22/10 , C08G63/12 , C08G63/914 , C08L2312/00 , C09D135/02 , C09J133/066
Abstract: The instant invention provides crosslinkable compositions, and method of producing the same. The non-aqueous single phase crosslinkable composition comprises: (a) a polyol having an average of 2 or more hydroxyl functional groups; (b) polyaldehyde, or acetal or hemiacetal thereof; and (c) an acid catalyst having pK of less than 6; and (d) optionally one or more organic solvents.
Abstract translation: 本发明提供可交联组合物及其制备方法。 非水性单相交联性组合物包含：（a）平均具有2个以上羟基官能团的多元醇; （b）多醛，或其缩醛或半缩醛; （c）pK小于6的酸催化剂; 和（d）任选的一种或多种有机溶剂。
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公开(公告)号：US20140221554A1
公开(公告)日：2014-08-07
申请号：US14252117
申请日：2014-04-14
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor： Eric Greyson , John N. Argyropoulos , Paul Foley , Andrew Swartz , Nahrain E. Kamber , Caroline Slone , Manesh N. Sekharan
IPC: C09D133/14
CPC classification number: C09D133/14 , C08L61/02 , C08L75/14 , C09D175/04
Abstract: The instant invention provides a crosslinkable aqueous composition, method of producing the same, crosslinked compositions, and method of producing the same. The crosslinkable composition comprising: an aqueous dispersion comprising; (a) water; (b) a polycarbamate comprising at least an average of 2.0 carbamate functional groups; (c) a polyaldehyde comprising at least two aldehyde groups; (d) an acid catalyst; and (e) optionally one or more surfactants; wherein said aqueous dispersion has a pH in the range of less than 7; and wherein said composition is capable of being crosslinked at a temperature in range of less than 80° C. upon substantial removal of water.
Abstract translation: 本发明提供了一种可交联水性组合物，其制备方法，交联组合物及其制备方法。 所述可交联组合物包含：水分散体，其包含： （一杯水; （b）包含至少平均2.0个氨基甲酸酯官能团的聚氨酯; （c）包含至少两个醛基的多醛; （d）酸催化剂; 和（e）任选的一种或多种表面活性剂; 其中所述水性分散体的pH在小于7的范围内; 并且其中所述组合物能够在基本上除去水后在低于80℃的温度范围内交联。
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公开(公告)号：US20130165581A1
公开(公告)日：2013-06-27
申请号：US13727963
申请日：2012-12-27
Applicant: Dow Global Technologies LLC , Rohm and Haas Company
Inventor： John N. Argyropoulos , Paul Foley , Eric Greyson , Jeff R. Anderson , Gary E. Spilman , Caroline Slone , Nahrian E. Kamber
CPC classification number: C09D167/08 , C08F22/10 , C08G63/12 , C08G63/914 , C08L2312/00 , C09D135/02 , C09J133/066
Abstract: The instant invention provides crosslinkable compositions, and method of producing the same. The non-aqueous single phase crosslinkable composition comprises: (a) a polyol having an average of 2 or more hydroxyl functional groups; (b) polyaldehyde, or acetal or hemiacetal thereof; and (c) an acid catalyst having pK of less than 6; and (d) optionally one or more organic solvents.
Abstract translation: 本发明提供可交联组合物及其制备方法。 非水性单相交联性组合物包含：（a）平均具有2个以上羟基官能团的多元醇; （b）多醛，或其缩醛或半缩醛; 和（c）pK小于6的酸催化剂; 和（d）任选的一种或多种有机溶剂。
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公开(公告)号：US09650541B2
公开(公告)日：2017-05-16
申请号：US15042036
申请日：2016-02-11
Applicant: Dow Global Technologies LLC
Inventor： Gary E. Spilman , Jeff R. Anderson , John N. Argyropoulos , Paul Foley
IPC: C08L77/00 , C08G69/44 , C08G63/02 , C09D175/06 , C09D179/00 , C09D167/00 , C09D167/08
CPC classification number: C09D175/06 , C09D167/00 , C09D167/08 , C09D179/00
Abstract: The instant invention provides a crosslinkable coating composition, and method of producing the same. The crosslinkable coating composition according to the present invention comprises: (a) one or more polycarbamates derived from one or more polyesters comprising the condensation reaction product of one or more polyols with one or more polyacids, wherein said one or more polyols comprise at least 25 percent by weight of one or more units having 4 or more hydroxyl groups; (b) one or more crosslinking agents; (c) one or more acid catalysts; and (d) optionally one or more organic solvents.
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公开(公告)号：US20160194447A1
公开(公告)日：2016-07-07
申请号：US14908795
申请日：2014-07-28
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Xinrui Yu , Yiyong He , John W. Hull, JR. , Paul Foley
IPC: C08G71/04
CPC classification number: C08G71/04
Abstract: A first process to produce polycarbamate comprising providing urea in liquid form; and adding the liquid urea to a polyol is provided. A second process for producing polycarbamate comprising adding solid urea to a polyol in liquid form to form a reaction mixture is provided. Also provided is a reaction product produced by the first process or second process.
Abstract translation: 生产聚氨酯的第一种方法，包括提供液态尿素; 并提供液态尿素至多元醇。 提供了生产聚氨酯的第二种方法，其包括将固体尿素加入到液体形式的多元醇中以形成反应混合物。 还提供了通过第一工艺或第二工艺生产的反应产物。
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Patent Agency Ranking
公开(公告)号：US20160160076A1
公开(公告)日：2016-06-09
申请号：US15042036
申请日：2016-02-11
Applicant: Dow Global Technologies LLC
Inventor： Gary E. Spilman , Jeff R. Anderson , John N. Argyropoulos , Paul Foley
IPC: C09D175/06
CPC classification number: C09D175/06 , C09D167/00 , C09D167/08 , C09D179/00
Abstract: The instant invention provides a crosslinkable coating composition, and method of producing the same. The crosslinkable coating composition according to the present invention comprises: (a) one or more polycarbamates derived from one or more polyesters comprising the condensation reaction product of one or more polyols with one or more polyacids, wherein said one or more polyols comprise at least 25 percent by weight of one or more units having 4 or more hydroxyl groups; (b) one or more crosslinking agents; (c) one or more acid catalysts; and (d) optionally one or more organic solvents.
Abstract translation: 本发明提供一种可交联涂料组合物及其制备方法。 根据本发明的可交联涂料组合物包含：（a）一种或多种衍生自一种或多种聚酯的聚氨酯，其包含一种或多种多元醇与一种或多种多元酸的缩合反应产物，其中所述一种或多种多元醇包含至少25 一个或多个具有4个或更多个羟基的单元的重量百分比; （b）一种或多种交联剂; （c）一种或多种酸催化剂; 和（d）任选的一种或多种有机溶剂。
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公开(公告)号：US20160130472A1
公开(公告)日：2016-05-12
申请号：US14899659
申请日：2014-06-05
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Paul J. Popa , Ben W. Schaefer , John N. Argyropoulos , Kenneth E. Wohltmann , Sandra Hofmann , Daniel Haile , Yanxiang Li , Paul Foley
IPC: C09D175/14 , C08K3/22 , C08K3/34 , C08K3/36
CPC classification number: C09D175/14 , C08G12/46 , C08K3/22 , C08K3/34 , C08K3/36 , C08K2003/2241 , C09D133/10 , C09D161/20 , F01D5/288 , F05B2280/6011 , F05D2300/43 , Y02T50/672 , C09D133/14 , C08K5/07 , C08F2220/1825 , C08F220/20 , C08F2220/1858 , C08F220/14 , C08F2220/1875 , C08F220/06
Abstract: The instant invention provides cross-linkable coating compositions, process for producing the same, and substrates coated therewith. The cross-linkable coating composition comprises: (a) polyaldehyde, or acetal or hemiacetal thereof; (b) an acid catalyst having pKa of less than 6; (c) a liquid media; (d) an acrylic polycarbamate comprising at least an average of 2.0 carbamate functional groups, wherein said polycarbamate has a glass transition (Tg) of less than 25° C.; and (e) one or more fillers having a pH in the range of equal to or less than 9 and/or one or more pigments having a pH in the range of equal to or less than 9, and/or one or more additives having a pH in the range of equal to or less than 9, wherein said composition has a curing temperature in the range of less than 70° C.
Abstract translation: 本发明提供了可交联的涂料组合物，其制备方法和用其涂布的基材。 可交联涂料组合物包含：（a）多醛，或其缩醛或半缩醛; （b）pKa小于6的酸催化剂; （c）液体介质; （d）包含至少平均2.0个氨基甲酸酯官能团的丙烯酸聚氨酯，其中所述聚氨酯具有小于25℃的玻璃化转变温度（Tg）。 和（e）一种或多种pH值在等于或小于9的范围内的一种或多种填料和/或一种或多种pH值在等于或小于9的范围内的颜料，和/或一种或多种添加剂具有 pH在等于或小于9的范围内，其中所述组合物的固化温度在小于70℃的范围内。
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公开(公告)号：US20140371388A1
公开(公告)日：2014-12-18
申请号：US13920343
申请日：2013-06-18
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Gary E. Spilman , Jeff R. Anderson , John N. Argyropoulos , Paul Foley
IPC: C09D179/00
CPC classification number: C09D175/06 , C09D167/00 , C09D167/08 , C09D179/00
Abstract: The instant invention provides a crosslinkable coating composition, and method of producing the same. The crosslinkable coating composition according to the present invention comprises: (a) one or more polycarbamates derived from one or more polyesters comprising the condensation reaction product of one or more polyols with one or more polyacids, wherein said one or more polyols comprise at least 25 percent by weight of one or more units having 4 or more hydroxyl groups; (b) one or more crosslinking agents; (c) one or more acid catalysts; and (d) optionally one or more organic solvents.
Abstract translation: 本发明提供一种可交联涂料组合物及其制备方法。 根据本发明的可交联涂料组合物包含：（a）一种或多种衍生自一种或多种聚酯的聚氨酯，其包含一种或多种多元醇与一种或多种多元酸的缩合反应产物，其中所述一种或多种多元醇包含至少25 一个或多个具有4个或更多个羟基的单元的重量百分比; （b）一种或多种交联剂; （c）一种或多种酸催化剂; 和（d）任选的一种或多种有机溶剂。
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公开(公告)号：US08889818B2
公开(公告)日：2014-11-18
申请号：US13727963
申请日：2012-12-27
Applicant: Rohm and Haas Company , Dow Global Technologies LLC
Inventor： John N. Argyropoulos , Paul Foley , Eric Greyson , Jeff R. Anderson , Gary E. Spilman , Caroline Slone , Nahrain E. Kamber
IPC: C08G12/02 , C08G14/00 , C08F283/02 , C08G63/12 , C09J133/06 , C08F22/10
CPC classification number: C09D167/08 , C08F22/10 , C08G63/12 , C08G63/914 , C08L2312/00 , C09D135/02 , C09J133/066
Abstract: The instant invention provides crosslinkable compositions, and method of producing the same. The non-aqueous single phase crosslinkable composition comprises: (a) a polyol having an average of 2 or more hydroxyl functional groups; (b) polyaldehyde, or acetal or hemiacetal thereof; and (c) an acid catalyst having pK of less than 6; and (d) optionally one or more organic solvents.
Abstract translation: 本发明提供可交联组合物及其制备方法。 非水性单相交联性组合物包含：（a）平均具有2个以上羟基官能团的多元醇; （b）多醛，或其缩醛或半缩醛; 和（c）pK小于6的酸催化剂; 和（d）任选的一种或多种有机溶剂。
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公开(公告)号：US10457777B2
公开(公告)日：2019-10-29
申请号：US14855426
申请日：2015-09-16
Applicant: Dow Global Technologies LLC
Inventor： Daryoosh Beigzadeh , Thomas P. Clark , Paul Foley , Congcong Lu , Peter Margl , Duane R. Romer
Abstract: The present invention provides carbamylation compositions of one or more urea compounds, one or more polyols and a monovalent transition metal or alkali metal catalyst (i), such as lithium ethylhexanoate, which compositions are substantially isocyanate free, enjoy reduced toxicity in comparison to tin catalysts, and which are useful in making polycarbamates which themselves provide compositions for making crosslinked polyurethanes.
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