公开(公告)号：US10343983B2

公开(公告)日：2019-07-09

申请号：US15986271

申请日：2018-05-22

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, Jr. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C09D7/63 ,  C07C269/00 ,  C08G65/333 ,  C08G71/04 ,  C07C271/10 ,  C09D175/04

Abstract: A polycarbamate comprising having less than 5 wt % total of biuret, cyanuric acid, and polyallophanate; and has a Gardner level of equal or greater than 3 is provided. A coating comprising the polycarbamate is also provided.

公开(公告)号：US10000610B2

公开(公告)日：2018-06-19

申请号：US14912161

申请日：2014-08-15

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, Jr. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C08G73/00 ,  C08G71/04 ,  C09D175/12 ,  C08G65/333

CPC classification number: C08G71/04 ,  C08G65/33306 ,  C08G65/33324 ,  C09D175/12

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a divalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times two equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

公开(公告)号：US09920199B2

公开(公告)日：2018-03-20

申请号：US14835761

申请日：2015-08-26

Applicant: Dow Global Technologies LLC

Inventor： Syed Z. Mahdi ,  Yiyong He

IPC: C08L75/08 ,  C08G18/10

CPC classification number: C08L75/08 ,  C08G18/10 ,  C08G18/2865 ,  C08G18/289

Abstract: An improved silane modified polymer useful in adhesive compositions is made from a silane precursor material made by a process comprising reacting an organic compound having a backbone that is terminated by an amino group having at least one active amino hydrogen and a hydrolysable silane, wherein the backbone is comprised of at least one secondary amino group having one active amino hydrogen and a Michael addition acceptor compound, wherein the Michael addition compound fails to have a group reactive with an isocyanate group to form the silane precursor compound. The silane precursor compound is reacted with an isocyanate terminated polyurethane prepolymer to form a silane modified prepolymer. The silane modified prepolymer may then be cured with moisture and may be employed in an adhesive composition containing other components such as a plasticizer, catalyst and filler.

公开(公告)号：US20160185713A1

公开(公告)日：2016-06-30

申请号：US14912157

申请日：2014-08-15

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull ,  Daryoosh Beigzadeh ,  Duane Romer ,  Thomas Clark ,  Peter Margi ,  Congcong Lu

IPC: C07C269/00 ,  C07C271/10 ,  C09D7/12

CPC classification number: C07C269/00 ,  C07C271/10 ,  C08G65/33303 ,  C08G65/33324 ,  C08G71/04 ,  C09D7/63 ,  C09D175/04

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a trivalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times three equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

Abstract translation: 一种制备聚氨酯的方法，包括在至少一种选自具有下式MmZn的化合物的催化剂存在下将多元醇加入到多元醇中; 其中M是三价金属，Z是阴离子官能团或能够与M形成共价键的官能团，并且其中Z的数量等于X，m的三倍等于Y，其中X的绝对值等于绝对值 提供了Y值。 还提供了根据该方法制备的聚氨酯和包含聚氨酯的涂料组合物。

公开(公告)号：US12209201B2

公开(公告)日：2025-01-28

申请号：US17624321

申请日：2020-07-01

Applicant: ROHM AND HAAS COMPANY ,  DOW SILICONES CORPORATION ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： Tirtha Chatterjee ,  Milton H. Repollet-Pedrosa ,  Michael P. Tate ,  Yiyong He ,  Andrea Watts

IPC: C09D183/08 ,  C08K13/02

Abstract: A liquid applied, silicone-based air and water barrier coating composition and its use as a silicone-based air and water barrier is provided. The barrier is generally vapour permeable and suitable for the construction industry. The liquid coating composition generally has a shelf-life of at least 15 months. The liquid coating composition comprises: (i) a crosslinked polysiloxane dispersion comprising (c) a surfactant and (d) water; (ii) one or more rheology modifiers in an amount of from 0.25 to 5 wt. % of the composition; and (iii) an acidic pH stable colloidal silica in an amount of from 15 to 30 wt. % of the composition; and optionally (iv) one or more stabilizers.

公开(公告)号：US11680227B2

公开(公告)日：2023-06-20

申请号：US17896503

申请日：2022-08-26

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Lin Wang ,  Robin P. Ziebarth ,  Matthew E. Belowich ,  Scott Backer ,  Paul Mercando ,  Yiyong He

IPC: C11D1/72 ,  C11D1/75 ,  C11D3/33 ,  C11D3/395 ,  C11D3/22 ,  C11D3/04 ,  C11D3/10 ,  C11D3/20 ,  C11D3/30 ,  C11D3/36 ,  C11D3/386 ,  C11D3/39 ,  C11D11/00 ,  C11D17/06 ,  C11D1/722 ,  C11D3/08

CPC classification number: C11D3/223 ,  C11D1/72 ,  C11D1/722 ,  C11D3/046 ,  C11D3/08 ,  C11D3/10 ,  C11D3/2086 ,  C11D3/22 ,  C11D3/30 ,  C11D3/33 ,  C11D3/361 ,  C11D3/386 ,  C11D3/38609 ,  C11D3/3902 ,  C11D3/3907 ,  C11D3/3942 ,  C11D3/3951 ,  C11D11/0035 ,  C11D17/06 ,  C11D17/065

Abstract: A method of washing glassware is provided including: providing automatic dishwashing apparatus; providing soiled glassware; placing soiled glassware in automatic dishwashing apparatus; providing wash water; providing rinse water; selecting anhydrous mixed powder or mixed granule comprising: 2.5-5 wt % of oxidized maltodextrin, wherein oxidized maltodextrin has Degree of Oxidation of 0.4-1.7; 10-25 wt % of amino acid based builder; 20-75 wt % of additional builder, wherein additional builder includes at least one of sodium citrate, sodium carbonate and sodium percarbonate; 2.5-7.5 wt % of bleach activator; 0.5-10 wt % of nonionic surfactant; 0.5-1 wt % of phosphonate; 1-6 wt % of enzyme; 5-15 wt % of filler; and

公开(公告)号：US20220403296A1

公开(公告)日：2022-12-22

申请号：US17896503

申请日：2022-08-26

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Lin Wang ,  Robin P. Ziebarth ,  Matthew E. Belowich ,  Scott Backer ,  Paul Mercando ,  Yiyong He

IPC: C11D3/22 ,  C11D1/72 ,  C11D3/04 ,  C11D3/10 ,  C11D3/20 ,  C11D3/30 ,  C11D3/33 ,  C11D3/36 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D11/00 ,  C11D17/06

Abstract: A method of washing glassware is provided including: providing automatic dishwashing apparatus; providing soiled glassware; placing soiled glassware in automatic dishwashing apparatus; providing wash water; providing rinse water; selecting anhydrous mixed powder or mixed granule comprising: 2.5-5 wt % of oxidized maltodextrin, wherein oxidized maltodextrin has Degree of Oxidation of 0.4-1.7; 10-25 wt % of amino acid based builder; 20-75 wt % of additional builder, wherein additional builder includes at least one of sodium citrate, sodium carbonate and sodium percarbonate; 2.5-7.5 wt % of bleach activator; 0.5-10 wt % of nonionic surfactant; 0.5-1 wt % of phosphonate; 1-6 wt % of enzyme; 5-15 wt % of filler; and

公开(公告)号：US20210380613A1

公开(公告)日：2021-12-09

申请号：US17276899

申请日：2019-09-18

Applicant: Dow Global Technologies LLC

Inventor： Siyu Tu ,  Jessica L. Klinkenberg ,  Yiyong He ,  Xiaoyun Chen ,  Haoquan Li ,  Matthew S. Remy

IPC: C07F9/50

Abstract: A method for preparing phosphine-borane complexes from aryldihalophosphine includes mixing sodium borohydride, a solvent having at least 50 vol % glycol ethers, and the aryldihalophosphine to obtain a solution. The solution is maintained at a reaction temperature for a duration of time to obtain the phosphine-borane complexes. The solvent may include 1,2-dimethoxyethane and tetrahydrofuran. A ratio of tetrahydrofuran to 1,2-dimethoxyethane in the solvent may be from 0.1:1.0 to 2.5:1.0.

公开(公告)号：US10604626B2

公开(公告)日：2020-03-31

申请号：US14908795

申请日：2014-07-28

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, Jr. ,  Paul Foley

IPC: C08G71/04

Abstract: A first process to produce polycarbamate comprising providing urea in liquid form; and adding the liquid urea to a polyol is provided. A second process for producing polycarbamate comprising adding solid urea to a polyol in liquid form to form a reaction mixture is provided. Also provided is a reaction product produced by the first process or second process.

公开(公告)号：US10196484B2

公开(公告)日：2019-02-05

申请号：US14916555

申请日：2014-09-18

Applicant: Dow Global Technologies LLC

Inventor： Gary E. Spilman ,  Congcong Lu ,  Daryoosh Beigzadeh, Jr. ,  Yiyong He ,  Paul J. Popa ,  John N. Argyropoulos

IPC: C08G18/62 ,  C08G71/04 ,  C09D175/06 ,  C08F8/30

Abstract: A method for producing polycarbamate comprising: contacting at least one carbamylating agent with a polyol in the presence of a carbamylation catalyst to form a reaction mixture having an acid value from 3 to 50 mg KOH/g dry polyol is provided. Further provided are a polycarbamate produced by the method and a coating comprising the polycarbamate.