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公开(公告)号：US11932775B2
公开(公告)日：2024-03-19
申请号：US17253343
申请日：2019-07-17
发明人： Alan M. Piwowar , Ray E. Drumright , Erin B. Vogel , Gary M. Wieber , Patrick J. Fryfogle , Yanxiang Li , Susan M. Machelski , Paul J. Popa , Adam C. Tomasik , Gerald Lawrence Witucki
IPC分类号： C09D183/08 , C08F220/14 , C08F220/18 , C08F220/20 , C08F220/32 , C08G77/00 , C08G77/08 , C08G77/26 , C09D133/08 , C09D133/10
CPC分类号： C09D183/08 , C08F220/14 , C08F220/1808 , C08F220/20 , C08F220/325 , C08G77/08 , C08G77/26 , C08G77/80 , C09D133/08 , C09D133/10
摘要： A curable coating composition is provided having multi-functionalized acrylic copolymer and silicone imine resin curing agents. The acrylic copolymer of the curable coating composition has, in polymerized form, epoxy functionalized groups and cure compatibility groups and the silicone imine forms an amino-functional silicone in the presence of water. The coating compositions are useful in the field of superior weatherable and durable coatings and are useful to replace isocyanate-containing polyurethane based coatings. Also provided are coated articles produced from the curable composition.
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公开(公告)号：US20210253900A1
公开(公告)日：2021-08-19
申请号：US17253341
申请日：2019-07-17
发明人： Erin B. Vogel , Susan M. Machelski , Ray E. Drumright , Paul J. Popa , Gary M. Wieber , Gerald Lawrence Witucki , Patrick J. Fryfogle , Adam C. Tomasik
IPC分类号： C09D183/08 , C09D133/12 , C09D133/06
摘要： A curable coating composition is provided having multi-functionalized acrylic copolymer and amino-functional silicone resin curing agents. The acrylic copolymer of the curable coating composition has, in polymerized form, epoxy functionalized groups and cure compatibility groups. The coating compositions are useful in the field of superior weatherable and durable coatings and are useful to replace isocyanate-containing polyurethane based coatings. Also provided are coated articles produced from the curable composition.
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公开(公告)号：US20180355189A1
公开(公告)日：2018-12-13
申请号：US16060085
申请日：2015-12-30
发明人： Yan Huang , Hongyu Chen , Xinyu Cao , Yu Zhang , Paul J. Popa , Yuteng Lin , John A. Roper , Gerald A. Vandezande
IPC分类号： C09D5/16 , C09D163/00 , C08G59/56 , C08G59/66 , C08G77/26
CPC分类号： C09D5/1675 , C08G59/1494 , C08G59/504 , C08G59/56 , C08G59/66 , C08G77/26 , C09D5/16 , C09D5/1637 , C09D7/63 , C09D7/65 , C09D163/00
摘要： Curable coating compositions for preventing biofouling include a) at least one epoxy resin; b) at least one amine-functional poly(dialkylsiloxane) polymer in an amount from 1 to 70% based on the combined weights of components a) and b); and c) at least one alkylene polyamine, polyalkylene polyamine or polymercaptan epoxy curing agent; wherein components b) and c) together provide about 0.75 to 1.5 equivalents of amine nitrogen atoms and/or thiol groups per equivalent of epoxy groups provided by component a). When cured to form an antifouling coating, the coating exhibits a water contact angle of at least 100° as measured using an optical contact angle meter at 22° C. The coating composition adheres well to many substrates, provides good anticorrosion protection and is an effective anti-biofouling measure.
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公开(公告)号：US20160130472A1
公开(公告)日：2016-05-12
申请号：US14899659
申请日：2014-06-05
发明人： Paul J. Popa , Ben W. Schaefer , John N. Argyropoulos , Kenneth E. Wohltmann , Sandra Hofmann , Daniel Haile , Yanxiang Li , Paul Foley
IPC分类号： C09D175/14 , C08K3/22 , C08K3/34 , C08K3/36
CPC分类号： C09D175/14 , C08G12/46 , C08K3/22 , C08K3/34 , C08K3/36 , C08K2003/2241 , C09D133/10 , C09D161/20 , F01D5/288 , F05B2280/6011 , F05D2300/43 , Y02T50/672 , C09D133/14 , C08K5/07 , C08F2220/1825 , C08F220/20 , C08F2220/1858 , C08F220/14 , C08F2220/1875 , C08F220/06
摘要： The instant invention provides cross-linkable coating compositions, process for producing the same, and substrates coated therewith. The cross-linkable coating composition comprises: (a) polyaldehyde, or acetal or hemiacetal thereof; (b) an acid catalyst having pKa of less than 6; (c) a liquid media; (d) an acrylic polycarbamate comprising at least an average of 2.0 carbamate functional groups, wherein said polycarbamate has a glass transition (Tg) of less than 25° C.; and (e) one or more fillers having a pH in the range of equal to or less than 9 and/or one or more pigments having a pH in the range of equal to or less than 9, and/or one or more additives having a pH in the range of equal to or less than 9, wherein said composition has a curing temperature in the range of less than 70° C.
摘要翻译： 本发明提供了可交联的涂料组合物，其制备方法和用其涂布的基材。 可交联涂料组合物包含：（a）多醛，或其缩醛或半缩醛; （b）pKa小于6的酸催化剂; （c）液体介质; （d）包含至少平均2.0个氨基甲酸酯官能团的丙烯酸聚氨酯，其中所述聚氨酯具有小于25℃的玻璃化转变温度（Tg）。 和（e）一种或多种pH值在等于或小于9的范围内的一种或多种填料和/或一种或多种pH值在等于或小于9的范围内的颜料，和/或一种或多种添加剂具有 pH在等于或小于9的范围内，其中所述组合物的固化温度在小于70℃的范围内。
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公开(公告)号：US20140186621A1
公开(公告)日：2014-07-03
申请号：US14132119
申请日：2013-12-18
发明人： Paul J. Popa , Yanxiang Li , Hongyu Chen
IPC分类号： C09D7/12
CPC分类号： C09D183/08 , B05D3/007 , C08G18/10 , C08G18/61 , C08G18/77 , C09D7/63 , C09D175/04 , Y10T428/269 , Y10T428/31551
摘要： A two-part moisture curable coating compositions capable of forming polyurethane-polysiloxane networks is provided. The coating compositions which are useful in marine antifouling coatings provide a two-part moisture curable composition comprising: (a) a first part comprising at least one multifunctional polyol; (b) a second part comprising: (i) at least one polysiloxane polymer with at least two isocyanate or mercapto functional groups and (ii) at least one isocyanate functional organic compound; and (c) solvent. Also provided are methods of coating substrates with the curable composition and articles produced from such coated substrates.
摘要翻译： 提供了能够形成聚氨酯 - 聚硅氧烷网络的两部分湿度可固化涂料组合物。 可用于海洋防污涂料的涂料组合物提供两部分湿气可固化组合物，其包含：（a）包含至少一种多官能多元醇的第一部分; （b）第二部分，其包含：（i）至少一种具有至少两个异氰酸酯或巯基官能团的聚硅氧烷聚合物和（ii）至少一种异氰酸酯官能化有机化合物; 和（c）溶剂。 还提供了用可固化组合物和由这种涂覆的基材制备的制品涂覆基材的方法。
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公开(公告)号：US20190105884A1
公开(公告)日：2019-04-11
申请号：US16094627
申请日：2017-05-25
发明人： Anne M. Kelly-Rowley , Mechelle Ann Churchfield , Nicole L. Wagner , Paul J. Popa , Larry Jopko , Cristina Serrat
摘要： The present invention provides coated films and packages formed from such films. In one aspect, a coated film comprises (a) a film comprising (i) a first layer comprising from 70 to 100 percent by weight of a polyethylene having a density 0.930 g/cm3 or less and a peak melting point of less than 126° C.; (ii) a second layer comprising from 60 to 100 percent by weight polyethylene having a density of 0.905 to 0.970 g/cm3 and a peak melting point in the range of 100° C. to 135° C.; and (iii) at least one inner layer between the first layer and the second layer comprising from 40 to 100 percent by weight of a polyethylene having a density from 0.930 to 0.970 g/cm3 and a peak melting point in the range of 120° C. to 135° C., wherein the polyethylene is a medium density polyethylene or a high density polyethylene; and (b) a coating on an outer surface of the second layer of the film comprising a crosslinked polyurethane, wherein the coating is substantially free of isocyanate groups. In some embodiments, the coated film is thermally resistant when subjected to a W-fold test at a temperature of at least 230° F., and/or has a gloss of at least 70 units at 60°.
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公开(公告)号：US10131813B2
公开(公告)日：2018-11-20
申请号：US15214907
申请日：2016-07-20
IPC分类号： C08K5/00 , C09D175/12 , C09D5/08
摘要： The present invention provides substantially isocyanate-free multicomponent compositions useful in making rapid dry primer compositions and coatings, the compositions comprising one or more carboxylic acid compounds that contain one of a benzothiazole, benzoxazole, or benzimidazole group, preferably, that contain a benzothiazole group, one or more hydrophobic sulfonic acid catalyst, one or more pigment, extender or filler, one or more a) polycarbamates from alkyd polyol or acrylic polyol and one or more b) a polyaldehydes or the acetal or hemiacetal thereof as a second component. The multicomponent compositions cure quickly at a temperature of from 0° C. to less than 80° C. to form a crosslinked polyurethane coating having improved humidity and corrosion resistance.
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8.发明申请Crosslinkable Composition, a Method of Making the Same and a Crosslinked Composition Produced Therefrom 有权可交联组合物，其制备方法和由其制备的交联组合物公开(公告)号：US20150166828A1
公开(公告)日：2015-06-18
申请号：US14556286
申请日：2014-12-01
IPC分类号： C09D175/04 , C09D175/16
CPC分类号： C09D175/04 , C08F8/30 , C08G16/0225 , C08G16/06 , C09D133/066 , C09D161/00 , C09D175/16 , Y10T428/31551 , Y10T428/31591 , Y10T428/31598 , Y10T428/31605 , C08F2220/1858 , C08F220/14 , C08F220/20 , C08F220/06
摘要： A crosslinkable composition comprising: (i) one or more polycarbamates; (ii) one or more polyaldehydes; (iii) one or more polyols; and (iv) an acid catalyst is provided. Further provided are a method for making the crosslinkable composition, a crosslinked composition made therefrom, a coating comprising the crosslinked composition and articles comprising a substrate and the coating.
摘要翻译： 一种可交联组合物，其包含：（i）一种或多种聚氨基甲酸酯; （ii）一种或多种聚醛; （ⅲ）一种或多种多元醇; 和（iv）提供酸催化剂。 还提供了制备可交联组合物的方法，由其制备的交联组合物，包含交联组合物的涂层和包含基材和涂层的制品。
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公开(公告)号：US11834584B2
公开(公告)日：2023-12-05
申请号：US17253341
申请日：2019-07-17
发明人： Erin B. Vogel , Susan Machelski , Ray E. Drumright , Paul J. Popa , Gary M. Wieber , Gerald Lawrence Witucki , Patrick J. Fryfogle , Adam C. Tomasik
IPC分类号： C09D133/12 , C09D133/14 , C09D183/08 , C09D133/06 , C08G77/26 , C08L83/08 , C08F220/32 , C08L33/14 , C08L33/06
CPC分类号： C09D183/08 , C09D133/068 , C09D133/12 , C08F220/325 , C08G77/26 , C08L33/068 , C08L33/14 , C08L83/08 , C09D133/14
摘要： A curable coating composition is provided having multi-functionalized acrylic copolymer and amino-functional silicone resin curing agents. The acrylic copolymer of the curable coating composition has, in polymerized form, epoxy functionalized groups and cure compatibility groups. The coating compositions are useful in the field of superior weatherable and durable coatings and are useful to replace isocyanate-containing polyurethane based coatings. Also provided are coated articles produced from the curable composition.
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10.发明申请公开(公告)号：US20180371259A1
公开(公告)日：2018-12-27
申请号：US16116602
申请日：2018-08-29
CPC分类号： C09D5/002 , C08G2150/90 , C08K3/36 , C09D5/08 , C09D5/082 , C09D7/61 , C09D7/63 , C09D17/004 , C09D175/04 , C09D175/06
摘要： The present invention provides substantially isocyanate-free multicomponent compositions useful in making rapid dry primer compositions and coatings, the compositions comprising one or more carboxylic acid compounds that contain one of a benzothiazole, benzoxazole, or benzimidazole group, preferably, that contain a benzothiazole group, one or more hydrophobic sulfonic acid catalyst, one or more pigment, extender or filler, one or more a) polycarbamates from alkyd polyol or acrylic polyol and one or more b) a polyaldehydes or the acetal or hemiacetal thereof as a second component. The multicomponent compositions cure quickly at a temperature of from 0° C. to less than 80° C. to form a crosslinked polyurethane coating having improved humidity and corrosion resistance.
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