摘要:
This invention is drawn to a process for isomerizing a non-equilibrium mixture of alkylaromatics in two sequential zones, the first zone operating in the absence of hydrogen using a platinum-free catalyst and the second zone using a catalyst comprising a molecular sieve and a platinum-group metal component to obtain an improved yield of para-xylene from the mixture relative to prior art processes.
摘要:
This invention is drawn to a process for isomerizing a non-equilibrium mixture of alkylaromatics in two sequential zones, the first zone operating in the absence of hydrogen using a platinum-free catalyst and the second zone using a catalyst comprising a molecular sieve and a platinum-group metal component to obtain improved yield of para-xylene from the mixture relative to prior art processes.
摘要:
A process for the conversion of a hydrocarbon feedstock to produce xylene compounds. The feedstock is selectively hydrocracked and introduced into a transalkylation zone with a hydrocarbonaceous stream rich in benzene, toluene and C9+ hydrocarbons.
摘要翻译:烃原料转化生产二甲苯化合物的方法。 原料被选择性地加氢裂化并引入含烷烃流的烷基转移区域中,所述烃物流富含苯,甲苯和C 9 O 12+烃。
摘要:
An offshore co-current vapor-liquid contacting apparatus includes stages having contacting modules. Each contacting module includes a downcomer extending in a direction and has downcomer baffles distanced from each other in the direction to define downcomer cells within the downcomer. Each downcomer includes an outlet proximate to a co-current flow channel. A receiving pan extends substantially parallel to the downcomer and has receiving pan baffles distanced from each other in the direction to define receiving pan sections within the receiving pan. A vapor-liquid separation device has an inlet surface proximate to the co-current flow channel and an outlet surface above the receiving pan. Ducts are provided, with each duct having an upper end in fluid communication with a respective receiving pan section and a lower end in fluid communication with a selected downcomer cell in an immediately inferior stage.
摘要:
The present invention provides a membrane/amine column system and process for removing acid gases from natural gas on a floating liquefied natural gas vessel. Several process configurations are provided to deal with a reduction in the effectiveness of the amine column by increasing the amount of acid gases being removed by the membrane system prior to the natural gas being sent to the amine column.
摘要:
The present invention involves the use of a multi-stage membrane system for gas, vapor, and liquid separations. In this multi-stage membrane system, high selectivity and high permeance or at least high selectivity polybenzoxazole membranes or cross-linked polybenzoxazole membranes are applied for a pre-membrane or both the pre-membrane and the secondary membrane. A primary membrane can be from conventional glassy polymers. This multi-stage membrane system can reduce inter-stage compression cost, increase product recovery and product purity for gas, vapor, and liquid separations. It can also save the cost compared to the system using all the high cost polybenzoxazole membranes or cross-linked polybenzoxazole membranes.
摘要:
The present invention discloses a new process of treating natural gas using high gas permeability polybenzoxazole polymer membranes operated at high temperatures that can provide sufficient dew point margin for the product gas. The high gas permeability polybenzoxazole polymer membranes can be used for a single stage membrane system or for the first stage membrane in a two stage membrane system for natural gas upgrading. Simulation study has demonstrated that a costly membrane pretreatment system such as a MemGuard™ system will not be required in the present new process. The new process can achieve significant capital cost saving and reduce the existing membrane footprint greater than 50%.
摘要:
The present invention discloses a blends of an aromatic polyimide polymer and a polymer containing aromatic sulfonic acid groups that can be converted into polybenzoxazole (PBO) membranes for gas, vapor, and liquid separations. The PBO membranes that were prepared by thermal treating aromatic polyimide membranes containing between 0.05 and 20 wt-% of a poly(styrene sulfonic acid) polymer. These polymers showed up to 95% improvement in selectivity for CO2/CH4 and H2/CH4 separations compared to PBO membranes prepared from corresponding aromatic polyimide membranes without a poly(styrene sulfonic acid) polymer.
摘要:
A process is provided for the simultaneous removal of carbon dioxide and sulfur oxides from a flue gas stream by a potassium carbonate solvent. As a part of the regeneration of the contaminated stream, a portion of that stream is removed and cooled to allow for filtration of potassium sulfate, the reaction product of the solvent and the sulfur oxides.
摘要:
In the present invention high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes and methods for making and using these membranes have been developed. The cross-linked polybenzoxazole and polybenzothiazole polymer membranes are prepared by: 1) first synthesizing polyimide polymers comprising pendent functional groups (e.g., —OH or —SH) ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone; 2) fabricating polyimide membranes from these polymers; 3) converting the polyimide membranes to polybenzoxazole or polybenzothiazole membranes by heating under inert atmosphere such as nitrogen or vacuum; and 4) finally converting the membranes to high performance cross-linked polybenzoxazole or polybenzothiazole membranes by a crosslinking treatment, preferably UV radiation. The membranes can be fabricated into any convenient geometry. The high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes of the present invention are suitable for a variety of liquid, gas, and vapor separations.