PARTICLE-DISPERSED POLYIMIDE PRECURSOR SOLUTION, METHOD FOR PRODUCING POROUS POLYIMIDE FILM, AND POROUS POLYIMIDE FILM

    公开(公告)号:US20220119596A1

    公开(公告)日:2022-04-21

    申请号:US17380016

    申请日:2021-07-20

    Abstract: A particle-dispersed polyimide precursor solution contains a polyimide precursor having a unit represented by the following formula (I), particles, and a solvent, in which the particle-dispersed polyimide precursor solution satisfies both the following conditions (1) and (2), (in the formula (I), A represents a tetravalent organic group, and B represents a divalent organic group represented by any of the following formulas (B1) to (B4)), (in the formulas (B1) to (B4), Ar1, Ar10, and Ar11 each independently represent a trivalent aromatic group which may have a substituent, Ar2, Ar4, Ar5, Ar7 and Ar8 each independently represent a divalent aromatic group which may have a substituent, Ar3 and Ar6 each independently represent a tetravalent aromatic group which may have a substituent or a group represented by the following formula (II), Ar9 represents a divalent aromatic group which may have a substituent or a group represented by the following formula (III), X1 to X7 each independently represent NRa, O, or S, Ra represents a hydrogen atom, an alkyl group which may have a substituent, or an aryl group, and * represents a bonding site with an adjacent linking group), and (in the formulas (II) and (III), Ar12 and Ar13 each independently represent a trivalent aromatic group which may have a substituent, Ar14 and Ar15 each independently represent a divalent aromatic group which may have a substituent, Y and Z each independently represent O, S, S(═O)2, or CRbRc, Rb and Rc each independently represent a hydrogen atom, an alkyl group which may have a substituent, or an aryl group, and * represents a bonding site with an adjacent linking group), Condition (1): a total content of the groups represented by the formulas (B1) to (B4) is 1% by mass or more and 40% by mass or less with respect to a total amount of the polyimide precursor, and
    Condition (2): a content of the particles is 5% by mass or more and 90% by mass or less with respect to a total content of the polyimide precursor and the particles.

    METHOD FOR PRODUCING PRINTED MATERIAL AND SYSTEM FOR PRODUCING PRINTED MATERIAL

    公开(公告)号:US20210294228A1

    公开(公告)日:2021-09-23

    申请号:US16984161

    申请日:2020-08-04

    Abstract: A method for producing a printed material includes providing pressure-induced phase transition particles on a recording medium having an arithmetic average roughness Ra of 0.07 μm or more and 3.80 μm or less to form a pressure-induced phase transition particle layer having a coverage C within a range of 30% to 90%; bonding the pressure-induced phase transition particles onto the recording medium; and folding the recording medium having the pressure-induced phase transition particles bonded thereon and pressure-bonding the folded recording medium, or pressure-bonding the recording medium having the pressure-induced phase transition particles bonded thereon and another recording medium placed on top of each other. The pressure-induced phase transition particles contain a styrene resin containing styrene and a vinyl monomer other than styrene as polymerization components, and a (meth)acrylic acid ester resin that contains at least two(meth)acrylic acid esters as polymerization components, and a mass ratio of the (meth)acrylic acid esters relative to a total of polymerization components of the (meth)acrylic acid ester resin is 90 mass % or more. The pressure-induced phase transition particles have at least two glass transition temperatures, and the difference between the lowest glass transition temperature and the highest glass transition temperature among the glass transition temperatures exhibited by the pressure-induced phase transition particles is 30° C. or more.

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