公开(公告)号：US20110178251A1

公开(公告)日：2011-07-21

申请号：US13060347

申请日：2009-09-08

申请人： Veit Stegmann ,  Klemens Massonne ,  Franz Niklaus Windlin ,  Reinhold Schwalm ,  Dieter Hermeling ,  Thomas Daniel ,  Stefan Bruhns

发明人： Veit Stegmann ,  Klemens Massonne ,  Franz Niklaus Windlin ,  Reinhold Schwalm ,  Dieter Hermeling ,  Thomas Daniel ,  Stefan Bruhns

IPC分类号： C08F8/42

CPC分类号： A61L15/60 ,  C08J3/28 ,  C08J2300/14

摘要： The present invention relates to a water-absorbing material obtainable by a process comprising the steps of A) treating a particulate, non-surface-crosslinked, water-absorbing polymer with a mixture comprising an aqueous solvent and at least one salt of a transition metal and B) irradiating the polymer treated according to A) with UV radiation, to a process for its production and to articles comprising the water-absorbing material.

摘要翻译： 本发明涉及通过包括以下步骤的方法获得的吸水材料：A）用包含水性溶剂和至少一种过渡金属盐的混合物处理颗粒状非表面交联的吸水性聚合物 和B）用UV辐射将根据A）处理的聚合物照射到其生产方法和包含吸水材料的制品上。

公开(公告)号：US07981969B2

公开(公告)日：2011-07-19

申请号：US10588671

申请日：2005-02-18

申请人： Ulrich Riegel ,  Thomas Daniel ,  Matthias Weismantel ,  Mark Elliott ,  Dieter Hermeling

发明人： Ulrich Riegel ,  Thomas Daniel ,  Matthias Weismantel ,  Mark Elliott ,  Dieter Hermeling

IPC分类号： C08J3/24 ,  C08F20/06

CPC分类号： C08J3/245 ,  C08F220/06 ,  C08J2300/14

摘要： The invention concerns a process for producing water-absorbing polymer, which comprises a base polymer A being mixed with a first aqueous solution B of at least one surface postcrosslinker and a second aqueous solution C of at least one polyvalent cation and thermally treated, wherein said base polymer A is based on at least 50% neutralized acid-functional monomer and said solutions B and C are metered wholly or partly concurrently through separate nozzles whereby a water-absorbing polymer having a high saline flow conductivity value is obtained.

摘要翻译： 本发明涉及一种生产吸水聚合物的方法，其包括将基础聚合物A与至少一个表面后交联剂的第一水溶液B和至少一种多价阳离子的第二水溶液C混合并进行热处理，其中所述 基础聚合物A基于至少50％中和的酸官能单体，并且所述溶液B和C通过单独的喷嘴全部或部分同时计量，从而获得具有高盐水流动电导率值的吸水聚合物。

公开(公告)号：US20110121230A1

公开(公告)日：2011-05-26

申请号：US12946602

申请日：2010-11-15

申请人： Norbert Herfert ,  Thomas Daniel

发明人： Norbert Herfert ,  Thomas Daniel

IPC分类号： B01J20/26 ,  C08F2/38 ,  C08F8/08 ,  C08F8/30

CPC分类号： C08F220/06 ,  A61L15/24 ,  A61L15/56 ,  C08F2/10 ,  C08F2/38 ,  C08J3/12 ,  C08J3/126 ,  C08J2300/102

摘要： A process for producing water-absorbing polymer particles, wherein at least one aliphatic aldehyde or reaction product thereof with an aliphatic alcohol, an aliphatic amine, ammonia, a hypophosphite or a phosphite is added.

摘要翻译： 一种生产吸水性聚合物颗粒的方法，其中加入至少一种脂族醛或其与脂族醇，脂族胺，氨，次磷酸盐或亚磷酸酯的反应产物。

公开(公告)号：US20110042612A1

公开(公告)日：2011-02-24

申请号：US12519669

申请日：2008-01-29

申请人： Ulrich Riegel ,  Thomas Daniel ,  Uwe Stueven ,  Mark Elliott ,  Volker Braig ,  Michael De Marco

发明人： Ulrich Riegel ,  Thomas Daniel ,  Uwe Stueven ,  Mark Elliott ,  Volker Braig ,  Michael De Marco

IPC分类号： B01J20/26

CPC分类号： C08F20/06

摘要： Water-absorbing polymeric particles are produced by polymerizing a monomer solution or suspension comprising at least one unsaturated carboxylic acid, at least one hydroquinone monoether and at least one inorganic peroxide and coating the polymeric particles with at least one basic salt of a bivalent metal cation.

摘要翻译： 通过使包含至少一种不饱和羧酸，至少一种氢醌单醚和至少一种无机过氧化物的单体溶液或悬浮液聚合并用至少一种二价金属阳离子的碱性盐涂覆聚合物颗粒来制备吸水聚合物颗粒。

公开(公告)号：US07786211B2

公开(公告)日：2010-08-31

申请号：US12158502

申请日：2006-12-28

申请人： Uwe Stueven ,  Rüdiger Funk ,  Matthias Weismantel ,  Thomas Daniel ,  Annemarie Hillebrecht ,  Dominicus van Esbroeck ,  Karl J. Possemiers

发明人： Uwe Stueven ,  Rüdiger Funk ,  Matthias Weismantel ,  Thomas Daniel ,  Annemarie Hillebrecht ,  Dominicus van Esbroeck ,  Karl J. Possemiers

IPC分类号： C08G18/63

CPC分类号： C08F2/44 ,  C08F220/06 ,  C08F222/1006

摘要： The invention relates to a process for producing a water-absorbing resin by polymerization of a reaction mixture comprising at least one hydrophilic monomer and, if appropriate, at least one crosslinker in a reactor, which comprises admixing the reaction mixture with at least one first portion of a particulate additive before the reaction mixture has reached a residence time of 40% of the overall residence time in the reactor and with at least one second portion of a particulate additive when the reaction mixture has reached a residence time of 45% or more of the overall residence time in the reactor, the additive being selected from water-absorbing resin powders, fillers and mixtures thereof, the total solids content of monomer and additive being in the range from 30% to 60% by weight, the amount of additive being in the range from 5% to 50% by weight, based on the monomers, and the weight ratio of the first portion to the second portion of the additive being in the range from 10:1 to 1:5. The resin powder is recycled fine-sized material for example. Not only the residual monomer content, specifically the residual crosslinker content, but also the level of extractables in the water-absorbing resin are reduced by the method of addition described. A high fraction of additives can be incorporated without the properties of the water-absorbing resin obtained being adversely affected. The additives enter a sufficiently firm bond with the resin, so that no excessive dusting occurs on exposure to mechanical stress.

摘要翻译： 本发明涉及通过聚合包含至少一种亲水单体和如果合适的反应器中至少一种交联剂的反应混合物来生产吸水树脂的方法，其包括将反应混合物与至少一个第一部分 的反应混合物在反应混合物的停留时间达到总反应器停留时间的40％的停留时间和至少一个第二部分的颗粒状添加剂之前，当反应混合物达到45％或更多的停留时间时， 在反应器中的总停留时间，添加剂选自吸水树脂粉末，填料及其混合物，单体和添加剂的总固体含量在30重量％至60重量％的范围内，添加剂的量为 基于单体的5重量％至50重量％的范围，并且添加剂的第一部分与第二部分的重量比在10:1至 1：5。 树脂粉末是例如再循环的精细尺寸的材料。 通过所述的添加方法，不仅残留单体含量，特别是残留交联剂含量，而且吸水性树脂中的可萃取物的含量都降低。 可以并入高分数的添加剂，而不会对获得的吸水性树脂的性能产生不良影响。 添加剂与树脂进行足够牢固的粘合，使得在暴露于机械应力时不会发生过度的除尘。

公开(公告)号：US07759422B2

公开(公告)日：2010-07-20

申请号：US11665883

申请日：2005-10-14

申请人： Ulrich Riegel ,  Thomas Daniel ,  Dieter Hermeling ,  Mark Elliott

发明人： Ulrich Riegel ,  Thomas Daniel ,  Dieter Hermeling ,  Mark Elliott

IPC分类号： C08G63/60

CPC分类号： A61L15/60 ,  C08L33/02

摘要： The invention relates to finely divided water-absorbing polymeric particles having high fluid transportation and absorption performance, the Centrifuge Retention Capacity (CRC) being not less than 26 g/g, the absorbency under a load of 4.83 kPa (AUL0.7 psi) not less than 23 g/g and the Transportation Value (TV) not less than 15,000 cm3s, the Transportation Value (TV) being the product of Saline Flow Conductivity (SFC) and wicking absorption after 60 minutes (DA60) multiplied by 107, and wherein the wicking absorption after 60 minutes (DA60) is the weight of 0.9% by weight sodium chloride solution absorbed by 70 g of the water-absorbing polymeric particles in 60 minutes, wherein the water-absorbing polymeric particles are situated, during measurement, in a circularly round vessel which has an internal diameter of 6 cm and is sealed at its lower end by a sieve base of 36 μm mesh size, and the sieve base is in atmospheric contact with 0.9% by weight sodium chloride solution, processes for their preparation and also their use in hygiene articles and packaging materials.

摘要翻译： 本发明涉及具有高流体输送和吸收性能的细分散的吸水聚合物颗粒，离心保留容量（CRC）不小于26g / g，负荷4.83kPa（AUL0.7psi）下的吸收性不是 运输价值（TV）不小于15,000立方厘米，运输价值（TV）是盐水流动电导率（SFC）的乘积和60分钟后的吸液吸收（DA60）乘以107，其中 60分钟后的芯吸吸收（DA60）是在60分钟内由70g吸水性聚合物颗粒吸收的0.9重量％氯化钠溶液的重量，其中吸水聚合物颗粒在测量期间位于 内径6厘米的圆形圆形容器，其下端由36微米的筛孔尺寸的筛基密封，筛基与0.9重量％氯化钠溶液大气接触， 他们的准备以及在卫生用品和包装材料中的使用。

公开(公告)号：US07655733B2

公开(公告)日：2010-02-02

申请号：US11630949

申请日：2005-07-28

申请人： Kai Michael Exner ,  Thomas Daniel ,  Mark Elliott ,  Ulrich Riegel

发明人： Kai Michael Exner ,  Thomas Daniel ,  Mark Elliott ,  Ulrich Riegel

IPC分类号： C08F8/30 ,  C08B37/00

CPC分类号： A61L15/60

摘要： Disclosed is a process for postcrosslinking a water absorbing polymer by the polymer being treated with at least one postcrosslinker and postcrosslinked and dried during or after the treatment by raising the temperature, the at least one postcrosslinker being a cyclic carbamate or a cyclic urea, wherein the cyclic carbamate or the cyclic urea was obtained by reacting respectively an aminoalcohol or a diamine with a cyclic carbonate.

摘要翻译： 公开了一种通过用至少一种后交联剂处理的聚合物后交联吸水聚合物的方法，并且在处理期间或之后通过升高温度进行后交联和干燥，所述至少一种后交联剂是环状氨基甲酸酯或环脲，其中 通过使氨基醇或二胺与环状碳酸酯反应，得到环状氨基甲酸酯或环状脲。

公开(公告)号：US07553903B2

公开(公告)日：2009-06-30

申请号：US10581562

申请日：2004-12-17

申请人： Ulrich Riegel ,  Thomas Daniel ,  Matthias Weismantel ,  Mark Elliott ,  Dieter Hermeling

发明人： Ulrich Riegel ,  Thomas Daniel ,  Matthias Weismantel ,  Mark Elliott ,  Dieter Hermeling

IPC分类号： C08G63/60 ,  C08G69/26

CPC分类号： A61L15/60 ,  C08G63/20 ,  C08G63/60 ,  C08K3/34 ,  C08L5/00 ,  C08L67/00 ,  C08L91/06 ,  C09D179/02 ,  Y10S524/916 ,  C08L2666/26

摘要： Swellable hydrogel-forming polymer comprising at least one hydrophilic polymer of dendritic structure, a process for preparing the swellable hydrogel-forming polymer and also its use in hygiene articles.

摘要翻译： 包含至少一种树枝状结构的亲水性聚合物的可膨胀的水凝胶形成性聚合物，制备可溶胀水凝胶形成聚合物的方法以及其在卫生制品中的用途。

公开(公告)号：US20090030155A1

公开(公告)日：2009-01-29

申请号：US12146530

申请日：2008-06-26

申请人： Thomas Daniel ,  Ulrich Riegel ,  Mark Elliott ,  Stefan Bruhns ,  Dieter Hermeling

发明人： Thomas Daniel ,  Ulrich Riegel ,  Mark Elliott ,  Stefan Bruhns ,  Dieter Hermeling

IPC分类号： C08F8/40

CPC分类号： A61L15/60 ,  A61F13/15658 ,  A61F13/5323 ,  C08J3/245

摘要： The invention refers to absorbent structures for use in an absorbent article, the absorbent structure comprising a water absorbing material. The water absorbing material is obtainable by a process comprising the steps of bringing particles of a non surface-crosslinked water-absorbing polymer in contact with at least one post-crosslinker, at least one water-insoluble metal phosphate, and at least one further ingredient. The at least one ingredient is selected from at least one Nitrogen-containing water-soluble polymer, and at least one hydrophobic polymer. The particles are heat-treated at a temperature in the range from 120° C. to 300° C.

摘要翻译： 本发明涉及用于吸收制品的吸收结构，该吸收结构包括吸水材料。 吸水材料可以通过以下方法获得，该方法包括以下步骤：使非表面交联的吸水聚合物的颗粒与至少一种后交联剂，至少一种水不溶性金属磷酸盐和至少一种其它成分 。 所述至少一种成分选自至少一种含氮水溶性聚合物和至少一种疏水性聚合物。 颗粒在120℃至300℃的温度下进行热处理。

公开(公告)号：US20090029044A1

公开(公告)日：2009-01-29

申请号：US12146521

申请日：2008-06-26

申请人： Thomas Daniel ,  Ulrich Riegel ,  Mark Elliott ,  Stefan Bruhns ,  Dieter Hermeling

发明人： Thomas Daniel ,  Ulrich Riegel ,  Mark Elliott ,  Stefan Bruhns ,  Dieter Hermeling

IPC分类号： B05D3/02

CPC分类号： A61L15/60

摘要： The invention refers to absorbent structures for use in an absorbent article, the absorbent structure comprising a water absorbing material. The water absorbing material is obtainable by a process comprising the steps of bringing particles of a non surface-crosslinked water-absorbing polymer in contact with at least one postcrosslinker, at least one Nitrogen-containing water-soluble polymer, and at least one hydrophobic polymer. The particles are heat-treated at a temperature in the range from 120° C. to 300° C.

摘要翻译： 本发明涉及用于吸收制品的吸收结构，该吸收结构包括吸水材料。 吸水材料可以通过包括以下步骤的方法获得，所述方法包括使非表面交联的吸水聚合物的颗粒与至少一种后交联剂，至少一种含氮水溶性聚合物和至少一种疏水性聚合物接触 。 颗粒在120℃至300℃的温度下进行热处理。