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29 条记录 (耗时 0.032 秒)

    Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
    11.
    发明授权
    Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts 有权
    用于使伯醇脱氢以制备羧酸盐的方法和催化剂

    公开(公告)号：US06376708B1

    公开(公告)日：2002-04-23

    申请号：US09547373

    申请日：2000-04-11

    申请人： David A. Morgenstern ,  Juan P. Arhancet ,  Howard C. Berk ,  William L. Moench, Jr. ,  James C. Peterson

    发明人： David A. Morgenstern ,  Juan P. Arhancet ,  Howard C. Berk ,  William L. Moench, Jr. ,  James C. Peterson

    IPC分类号： C07C5116

    CPC分类号： C07F9/3813 ,  B01J23/70 ,  B01J23/72 ,  B01J23/80 ,  B01J23/835 ,  B01J35/04 ,  B01J37/348 ,  C07C51/235 ,  C07C227/02 ,  C07C229/16

    摘要： This invention is directed to a process for making a salt of a carboxylic acid. The process comprises contacting a catalyst with an alkaline mixture comprising a primary alcohol. In one embodiment, for example, the catalyst comprises a metal support (preferably a metal sponge support) coated with copper. The support comprises at least about 10% (by weight) non-copper metal, and the copper-containing coating comprises from about 0.005 to about 0.5 grams of copper (per gram of said metal support). In another embodiment, the catalyst comprises a metal support (preferably a metal sponge support) coated with silver. The support comprises at least about 10% (by weight) non-silver metal, and the silver-containing coating comprises from about 0.005 to about 0.5 grams of copper (per gram of said metal support). In another embodiment, the catalyst comprises at least about 15% (by weight) non-copper metal, and at least about 10% (by weight) copper. In yet another embodiment, the catalyst comprises at least about 15% (by weight) non-silver metal, and at least about 10% (by weight) silver. In both these embodiments, it is particularly preferable for the catalyst to be in the form of a metal sponge. This invention is also directed to copper-containing and silver-containing catalysts which may, for example, be used in the above process. This invention is further directed to processes for making such catalysts.

    摘要翻译： 本发明涉及一种制备羧酸盐的方法。 该方法包括使催化剂与包含伯醇的碱性混合物接触。在一个实施方案中，例如，催化剂包含涂覆有铜的金属载体（优选金属海绵载体）。 载体包含至少约10％（重量）的非铜金属，并且含铜涂层包含约0.005至约0.5克铜（每克所述金属载体）。在另一个实施方案中，催化剂包含 金属支撑体（优选金属海绵支撑体）涂覆银。 载体包含至少约10％（重量）的非银金属，并且含银涂层包含约0.005至约0.5克铜（每克所述金属载体）。在另一个实施方案中，催化剂包含 至少约15％（重量）的非铜金属和至少约10％（重量）的铜。 在另一个实施方案中，催化剂包含至少约15％（重量）的非银金属和至少约10％（重量）的银。 在这两个实施方案中，特别优选催化剂为金属海绵形式。本发明还涉及可以在上述方法中使用的含铜和含银催化剂。 本发明还涉及制备这种催化剂的方法。

    Process for making 1,3-propanediol and 3-hydroxypropanal
    12.
    发明授权
    Process for making 1,3-propanediol and 3-hydroxypropanal 失效
    制备1,3-丙二醇和3-羟基丙醛的方法

    公开(公告)号：US5304691A

    公开(公告)日：1994-04-19

    申请号：US91108

    申请日：1993-07-13

    申请人： Juan P. Arhancet ,  Lynn H. Slaugh

    发明人： Juan P. Arhancet ,  Lynn H. Slaugh

    IPC分类号： C07C29/16 ,  C07C45/58 ,  C07C27/20 ,  C07C27/00

    CPC分类号： C07C29/16 ,  C07C45/58

    摘要： This invention relates to a process for making 1,3-propanediol and 3-hydroxypropanal by intimately contacting(a) ethylene oxide,(b) tertiary phosphine-complexed cobalt carbonyl catalyst(c) ruthenium catalyst,(c) carbon monoxide, and(d) hydrogen, the molar ratio of carbon monoxide to hydrogen being from about 4:1 to about 1:6,in liquid-phase solution in an inert reaction solvent, at a temperature of from about 30.degree. C. to about 150.degree. C. and a pressure of from about 50 psi to about 10,000 psi.

    摘要翻译： 本发明涉及一种通过紧密接触（a）环氧乙烷，（b）叔膦络合的羰基钴催化剂（c）钌催化剂，（c）一氧化碳和（a）环氧乙烷的方法，制备1,3-丙二醇和3-羟基丙醛， d）氢气，一氧化碳与氢的摩尔比约为4:1至约1:6，在惰性反应溶剂中的液相溶液中，温度为约30℃至约150℃ 并且压力为约50psi至约10,000psi。

    Process or making 3-hydroxyaldehydes
    20.
    发明授权
    Process or making 3-hydroxyaldehydes 失效
    制备或制备3-羟基醛

    公开(公告)号：US5344993A

    公开(公告)日：1994-09-06

    申请号：US130258

    申请日：1993-10-01

    申请人： Lynn H. Slaugh ,  Juan P. Arhancet

    发明人： Lynn H. Slaugh ,  Juan P. Arhancet

    IPC分类号： C07C29/16 ,  C07C31/20 ,  C07C45/58 ,  C07C45/50 ,  C07C45/57

    CPC分类号： C07C45/58 ,  C07C29/16 ,  C07C31/20

    摘要： This invention relates to a process for making 3-hydroxyaldehydes having 4 or more carbon atoms by intimately contacting(a) 1,2-epoxides having 3 or more carbon numbers,(b) ditertiary phosphine-modified cobalt carbonyl catalyst, said phosphine being a hydrocarbylene-bis(monophosphabicyclononane) in which each phosphorus atom is joined to hydrocarbylene and is a member of a bridge linkage without being a bridgehead atom and which hydrocarbylene-bis(monophosphabicyclononane) has 11 to 80 carbon atoms, 5 to 12 carbon atoms thereof together with a phosphorus atom being members of each of the two bicyclic skeletal structures,(c) carbon monoxide, and(d) hydrogen, the molar ratio of carbon monoxide to hydrogen being from about 4:1 to about 1:6, in liquid-phase solution in an inert reaction solvent, at a temperature of from about 30.degree. C. to about 150.degree. C. and a pressure of from about 50 psi to about 10,000 psi. Acids and promoter salts may be added to the reaction mixture to promote the hydroformylation reaction.

    摘要翻译： 本发明涉及一种通过紧密接触（a）具有3个或更多个碳数的1,2-环氧化物制备具有4个或更多个碳原子的3-羟基醛的方法，（b）二膦膦改性的羰基钴催化剂，所述膦是 其中每个磷原子连接到亚烃基并且不是桥头原子的桥连构件的亚烃基 - 双（单磷酰基二环壬烷），并且亚烃基 - 双（单磷杂二环壬烷）具有11至80个碳原子，5至12个碳原子在一起 其中磷原子是两个双环骨架结构中的每一个的成员，（c）一氧化碳和（d）氢，一氧化碳与氢的摩尔比为约4:1至约1:6， 在惰性反应溶剂中，在约30℃至约150℃的温度和约50psi至约10,000psi的压力下进行。 可以向反应混合物中加入酸和促进剂盐以促进加氢甲酰化反应。