公开(公告)号：US5756836A

公开(公告)日：1998-05-26

申请号：US591947

申请日：1996-01-23

申请人： Masahiko Shimizu ,  Kazuyuki Akita ,  Yasuteru Kajikawa ,  Takashi Ueno ,  Yasuo Tsuji ,  Yoshiaki Morimoto

发明人： Masahiko Shimizu ,  Kazuyuki Akita ,  Yasuteru Kajikawa ,  Takashi Ueno ,  Yasuo Tsuji ,  Yoshiaki Morimoto

IPC分类号： B01J31/28 ,  C07C51/10 ,  C07C51/12 ,  C07C51/44 ,  C07C51/487 ,  C07C53/08 ,  C07C51/42

CPC分类号： C07C51/12 ,  C07C51/44 ,  C07C51/487

摘要： The present invention relates to a process for producing a highly purified acetic acid characterized in that in the process for producing acetic acid comprising the step of continuously reacting methanol and/or an aqueous solution of methyl acetate with carbon monoxide in a reactor, a treatment is conducted to limit the concentration of unsaturated compounds in crude acetic acid obtained in the process to 5 ppm or lower, and the resultant crude acetic acid is ozonized. The present invention also relates to a process for producing a highly purified acetic acid, characterized by comprising the step of continuously reacting methanol and/or an aqueous solution of methyl acetate with carbon monoxide in a reactor while maintaining the concentration of acetaldehyde in a reaction fluid in the reactor at 1500 ppm or lower.

摘要翻译： 本发明涉及一种生产高纯度乙酸的方法，其特征在于在制备乙酸的方法中，包括在反应器中使甲醇和/或乙酸甲酯的水溶液与一氧化碳连续反应的步骤，处理为 进行以将该方法中得到的粗乙酸中的不饱和化合物的浓度限制在5ppm以下，将所得粗乙酸臭化。 本发明还涉及一种生产高纯度乙酸的方法，其特征在于包括使甲醇和/或乙酸甲酯的水溶液与一氧化碳在反应器中连续反应，同时保持乙醛浓度在反应流体中的步骤 在反应器中为1500ppm以下。

公开(公告)号：US5625095A

公开(公告)日：1997-04-29

申请号：US458348

申请日：1995-06-02

申请人： Hiroyuki Miura ,  Masahiko Shimizu ,  Takashi Sato ,  Yoshiaki Morimoto ,  Masahiro Kagotani

发明人： Hiroyuki Miura ,  Masahiko Shimizu ,  Takashi Sato ,  Yoshiaki Morimoto ,  Masahiro Kagotani

IPC分类号： C07C51/12 ,  C07C51/44

CPC分类号： C07C51/12 ,  C07C51/44

摘要： A high purity acetic acid is prepared by reacting methanol with carbon monoxide in the presence of a rhodium catalyst, iodide salts, and methyl iodide, wherein an acetaldehyde concentration in the reaction liquid is maintained at 400 ppm or lower. This may be attained by contacting the liquid containing carbonyl impurities with water to separate and remove the carbonyl impurities. After that, the liquid can be returned to the reactor.

摘要翻译： 在铑催化剂，碘化物盐和碘甲烷的存在下，使甲醇与一氧化碳反应制备高纯度乙酸，其中反应液中的乙醛浓度保持在400ppm以下。 这可以通过使含有羰基杂质的液体与水接触以分离和除去羰基杂质来实现。 之后，液体可以返回到反应器。

公开(公告)号：US4178004A

公开(公告)日：1979-12-11

申请号：US853231

申请日：1977-11-18

申请人： Akibumi Shinoda ,  Masahiko Shimizu

发明人： Akibumi Shinoda ,  Masahiko Shimizu

IPC分类号： B60K15/06

CPC分类号： B60K15/06 ,  Y10T137/4824 ,  Y10T137/86228

摘要： A spare fuel tank used for a main fuel tank, being a container with a bottom, having a reasonable volumetric capacity, of vertically elongated shape, and having a spare fuel suction pipe thereinside. It is separately manufactured from the main tank, nevertheless, does not need separate fuel supplying nor specific piping connection with the main fuel tank, owing to its oil tight but detachable securing to the inside of the main fuel tank, by means either of fixing the same to an upper cover plate of the main fuel tank or of fastening the same to a wall of the main fuel tank with suitable fastening means, and to the disposition of a fuel inlet opening for automatical and simultaneous fuel supplying at the time of fuel supplying to the main fuel tank.

摘要翻译： 用于主燃料箱的备用燃料箱，具有底部的容器，具有合理的容积，具有垂直细长形状，并且在其内部具有备用燃料吸入管。 由主油箱分开制造，但是由于油主要油箱的油压不能单独供油，也不需要与主油箱的特定管路连接。 与主燃料箱的上盖板相同或者用适当的紧固装置将其紧固到主燃料箱的壁上，以及在燃料供应时配置用于自动和同时燃料供应的燃料入口 到主燃油箱。

公开(公告)号：US08581791B2

公开(公告)日：2013-11-12

申请号：US13179153

申请日：2011-07-08

申请人： Hiroyuki Egawa ,  Masahiko Shimizu

发明人： Hiroyuki Egawa ,  Masahiko Shimizu

IPC分类号： G01R29/10

CPC分类号： H01Q1/521 ,  H01Q1/242 ,  H01Q21/28

摘要： A first adjustment circuit adjusts an impedance of a first antenna, and a second adjustment circuit adjusts an impedance of a second antenna. A coupling reduction circuit reduces an amount of coupling of the first and second antennas. A first reception power measurement unit measures first reception power received from the first antenna, and a second reception power measurement unit measures second reception power received from the second antenna. A selection unit selects a circuit from among the first adjustment circuit, the second adjustment circuit, and the coupling reduction circuit. A circuit control unit controls the impedance of the selected circuit so that the value of the evaluation function proportional to the product of the first reception power and the second reception power becomes larger.

摘要翻译： 第一调整电路调整第一天线的阻抗，第二调整电路调整第二天线的阻抗。 耦合减小电路减少了第一和第二天线的耦合量。 第一接收功率测量单元测量从第一天线接收的第一接收功率，第二接收功率测量单元测量从第二天线接收的第二接收功率。 选择单元从第一调整电路，第二调整电路和耦合减小电路中选择电路。 电路控制单元控制所选电路的阻抗，使得与第一接收功率和第二接收功率的乘积成比例的评估功能的值变大。

公开(公告)号：US20130264186A1

公开(公告)日：2013-10-10

申请号：US13993109

申请日：2011-12-01

申请人： Masahiko Shimizu ,  Ryuji Saito ,  Hiroyuki Miura ,  Takashi Ueno

发明人： Masahiko Shimizu ,  Ryuji Saito ,  Hiroyuki Miura ,  Takashi Ueno

IPC分类号： C07C51/44

CPC分类号： C07C51/44 ,  C07C51/50 ,  C07C53/08

摘要： Acetic acid is produced while efficiently inhibiting condensation of hydrogen iodide in a distillation column (second distillation column) for purifying crude acetic acid by further distillation.A process for producing acetic acid comprises an acetic acid collection step for feeding a first distillation column with a volatile component at least containing acetic acid, methyl acetate, methyl iodide, water, and hydrogen iodide, separating a first lower boiling point component as an overhead, and collecting a first liquid stream mainly containing acetic acid, and an acetic acid purification step for feeding a second distillation column with the first liquid stream, further separating a second lower boiling point component as an overhead, and collecting a second liquid stream containing acetic acid, wherein an alkali component is added or mixed to the first liquid stream in the manners (1) and/or (2) for distilling a liquid object to be treated containing the first liquid stream and the alkali component in the second column: (1) the alkali component is added to or mixed with the first liquid stream before the first liquid stream is fed to the second column, (2) in the second column, the alkali component is added or mixed at the same height level as or at a height level upper than a height level at which the first liquid stream is fed.

摘要翻译： 产生乙酸，同时有效地抑制通过进一步蒸馏纯化粗乙酸的蒸馏塔（第二蒸馏塔）中碘化氢的冷凝。 一种生产乙酸的方法包括乙酸收集步骤，用于向至少含有乙酸，乙酸甲酯，甲基碘，水和碘化氢的挥发性成分进料第一蒸馏塔，分离作为塔顶馏分的第一低沸点组分 并收集主要含有乙酸的第一液体物流，以及用于向第二蒸馏塔供给第一液体物流的乙酸净化步骤，进一步分离作为塔顶馏出物的第二低沸点成分，并收集含有乙酸的第二液体物流 酸，其中以第（1）和/或（2）的方式将碱组分加入或混合到第一液体流中，用于蒸馏含有第二液体流和第二塔中的碱组分的待处理液体物质： 1）在将第一液体流送入第二塔之前，将碱成分加入或混合第一液体流，（2）在第二柱中 n，碱成分以与供给第一液体流的高度水平高度相同的高度水平添加或混合。

公开(公告)号：US08537932B2

公开(公告)日：2013-09-17

申请号：US12262395

申请日：2008-10-31

申请人： Tsuyoshi Hasegawa ,  Masahiko Shimizu ,  Akira Ito

发明人： Tsuyoshi Hasegawa ,  Masahiko Shimizu ,  Akira Ito

IPC分类号： H03K9/00 ,  H04L27/01

CPC分类号： H04L25/03012 ,  H04L25/0242 ,  H04L2025/03375 ,  H04L2025/03477 ,  H04L2025/03605

摘要： In an equalizer arranged in a wireless communication device: information on correlation in one or more first wireless signals is generated; a channel vector is generated on the basis of the one or more first wireless signals; an extended correlation matrix which contains a correlation matrix indicating the information on correlation and is extended so as to become a circulant matrix is generated; an extended channel vector is generated by extending the channel vector so that the extended channel vector contains elements of the channel vector and has rows the number of which is identical to the number of rows of the extended correlation matrix; and weight coefficients are calculated as a solution, in the frequency domain, of an equation expressed by the extended correlation matrix and the extended channel vector, where the solution is obtained by solving the equation.

摘要翻译： 在布置在无线通信设备中的均衡器中，生成关于一个或多个第一无线信号中的相关性的信息; 基于一个或多个第一无线信号生成信道向量; 生成包含相关矩阵的扩展相关矩阵，该相关矩阵指示关于相关性的信息并被扩展以成为循环矩阵; 通过扩展信道向量来生成扩展信道向量，使得扩展信道向量包含信道向量的元素，其行数与扩展相关矩阵的行数相同; 并且计算权重系数作为频域中由扩展相关矩阵和扩展信道向量表示的等式的解，其中通过求解方程获得解。

公开(公告)号：US08532208B2

公开(公告)日：2013-09-10

申请号：US12716409

申请日：2010-03-03

申请人： Masahiko Shimizu ,  Akira Ito

发明人： Masahiko Shimizu ,  Akira Ito

IPC分类号： H04L25/49 ,  H04L25/03

CPC分类号： H04B7/0413 ,  H04L1/0067 ,  H04L1/1812 ,  H04L1/1893

摘要： A transmission apparatus obtains, for each transmission to a reception apparatus, information on a per-bit transmission of a transmission bit string, and controls a per-bit transmission condition for a current transmission bit string such that a per-bit transmission quality of the transmission bit string approaches evenly based on cumulative information on the transmissions up to the last transmission.

摘要翻译： 发送装置对于对接收装置的每次发送，获得关于发送比特串的每比特传输的信息，并且控制当前传输比特串的每比特传输条件，使得每个比特的传输质量 传输比特串基于到最后传输的传输的累积信息均匀地接近。

公开(公告)号：US20130116470A1

公开(公告)日：2013-05-09

申请号：US13806290

申请日：2011-07-11

申请人： Hiroyuki Miura ,  Masahiko Shimizu ,  Takashi Ueno ,  Kazuo Yamaguchi ,  Kensuke Goto

发明人： Hiroyuki Miura ,  Masahiko Shimizu ,  Takashi Ueno ,  Kazuo Yamaguchi ,  Kensuke Goto

IPC分类号： C07C51/12

CPC分类号： C07C51/12 ,  C07C51/43 ,  C07C51/44 ,  Y02P20/124 ,  C07C53/08

摘要： A production process of acetic acid comprises a reaction step for continuously allowing at least one member selected from the group consisting of methanol, dimethyl ether, and methyl acetate to react with carbon monoxide in a catalyst system comprising a rhodium catalyst, an iodide salt, and methyl iodide in the presence of acetic acid and water in a plant compromising a reactor 1; a flasher 2; and a distillation column 3; wherein part of the vaporized stream is introduced into a heat exchanger 7. The process achieves a production of acetic acid with a high purity in a resource-saving and energy-saving equipment by efficiently removing a reaction heat even in a large-sized plant.

摘要翻译： 乙酸的制备方法包括在包含铑催化剂，碘化物盐和催化剂体系的催化剂体系中连续地使选自甲醇，二甲醚和乙酸甲酯中的至少一种与一氧化碳反应的反应步骤 甲基碘在乙酸和水的存在下在损害反应器1的植物中; 闪光灯2 和蒸馏塔3; 其中部分蒸发的物流被引入热交换器7.该方法通过有效地除去大型设备中的反应热量，在资源节约和节能设备中实现了高纯度的乙酸生产。

公开(公告)号：US08331470B2

公开(公告)日：2012-12-11

申请号：US12575785

申请日：2009-10-08

申请人： Masahiko Shimizu

发明人： Masahiko Shimizu

IPC分类号： H04L5/12

CPC分类号： H04L1/0066 ,  H03M13/258 ,  H03M13/2707 ,  H03M13/2957 ,  H03M13/6362 ,  H04L1/0041 ,  H04L1/005 ,  H04L1/0055 ,  H04L1/006 ,  H04L1/0068 ,  H04L1/0071

摘要： A communication system that performs encoding and decoding for communication includes a transmitting apparatus and a receiving apparatus. The transmitting apparatus includes a turbo encoding unit including a first encoding unit that encodes an input signal and generates a first parity bit by bit-based encoding and n (n=1, 2, 3, . . . ) second encoding units that encode the input signal and generate second parity bits by bit-based encoding, and a symbol mapping unit that maps an output from the turbo encoding unit to a symbol by bit-based mapping operation and modulates the output. And the receiving apparatus includes a demodulating unit that demodulates a transmission signal, and a turbo decoding unit that performs turbo decoding on the demodulated signal by bit-based decoding.

摘要翻译： 执行通信的编码和解码的通信系统包括发送装置和接收装置。 发送装置包括：turbo编码单元，包括：第一编码单元，其对输入信号进行编码，并通过基于位的编码生成第一奇偶校验位;以及n（n = 1,2,3，...）个第二编码单元， 输入信号并通过基于位的编码生成第二奇偶校验位，以及符号映射单元，其将来自turbo编码单元的输出映射到基于位的映射操作的符号，并调制输出。 并且接收装置包括对发送信号进行解调的解调部，以及通过基于位解码对解调信号进行turbo解码的turbo解码部。

公开(公告)号：US08301352B2

公开(公告)日：2012-10-30

申请号：US13227677

申请日：2011-09-08

申请人： Akira Ito ,  Takashi Dateki ,  Masahiko Shimizu

发明人： Akira Ito ,  Takashi Dateki ,  Masahiko Shimizu

IPC分类号： G06F19/00

CPC分类号： H04W52/262 ,  H04W52/146 ,  H04W52/225 ,  H04W52/246

摘要： A cubic metric calculator performs a calculation of a time average of power of the amplitude of a transmission signal when a cubic metric value is calculated as a product-sum operation between a transmission power-dependent term including an amplitude value depending on the transmission power of a transmission signal and a time average term including only a modulation parameter not depending on the transmission power of the transmission signal. When the transmission signal is transmitted, the operator inputs the amplitude value to calculate the transmission power-dependent term, reads the value of the time average term from coefficient memory, and performs the product-sum operation using an operation result of the transmission power-dependent term and the read value of the time average term, thereby calculating a time average of the power of the amplitude of the transmission signal.

摘要翻译： 当三次度量值被计算为包括根据发射功率的发射功率的幅度值的发射功率相关项之间的乘积和运算时，三次量度计算器执行传输信号的幅度的功率的时间平均值的计算 传输信号和仅包括不依赖于发送信号的发送功率的调制参数的时间平均项。 当发送发送信号时，操作员输入振幅值来计算发送功率相关项，从系数存储器读取时间平均项的值，并使用发送功率相关项的运算结果进行乘积和运算， 依赖项和时间平均项的读取值，从而计算发送信号的幅度的功率的时间平均。