Abstract:
The present application provides Calcia-Magnesia-Alumina-Silica (CMAS) (or molten silicate) resistant thermal barrier coatings (IBC). The coatings include elongate growth domains of non-equiaxed, randomly arranged overlapping grains or splats. The elongate growth domains include overlapping individual, randomly distributed splats of tough and soft phases. In some embodiments, the elongate growth domains are formed via air plasma spray. In some embodiments, the tough phases are at least partially stabilized zirconia and/or hafnia compositions, and the soft phases are CMAS (or molten silicate) reactive or resistant compositions. Within each elongate growth domain, the mixture of the tough and soft phases act together to limit penetration of CMAS and also provide sufficient domain toughness to minimize cracking forces produced during crystallization of infiltrated CMAS. The soft phases may react with the CMAS and increase its melting point, increase its viscosity, and reduce the destabilization of the tough phases.
Abstract:
Coating systems for components of a gas turbine engine, such as a compressor blade tip, are provided. The coating system can include a ceramic material disposed along the compressor blade tip and may be used with a bare compressor casing. The ceramic coating is harder than the bare compressor casing and can reduce the rub ratio thereby increasing the lifetime of the compressor blades. Methods are also provided for applying the coating system onto a compressor blade.
Abstract:
A coated component, along with methods of its formation, restoration, and use, is provided. The coated component may include a substrate defining a surface; a thermal barrier coating on the surface of the substrate; a layer of environmental contaminant compositions (e.g., CMAS) on the thermal barrier coating; and a chemical barrier coating on the layer of environmental contaminant compositions.
Abstract:
An article having a damage-tolerant thermal barrier coating includes a plurality of coating layers disposed over a substrate. The plurality of coatings comprises an inner layer and an outer layer. The outer layer is more resistant to infiltration by nominal CMAS relative to 8 weight percent yttria-stabilized zirconia at a temperature of 1300 degrees Celsius. The inner layer has, in a temperature range from about 1000 degrees Celsius to about 1200 degrees Celsius, a thermal resistance in a range from about 9×10−5 degree Kelvin per watt to about 23×10−5 degree Kelvin per watt.
Abstract:
Articles suitable for use as high-temperature machine components include a substrate and an environmental barrier coating disposed over the substrate, where the environmental barrier coating includes at least one hermetic self-sealing layer formed from a mixture including an alkaline earth metal aluminosilicate and a rare-earth silicate, and where the at least one hermetic self-sealing layer exhibits substantially no net remnant or residual expansion when subjected to high temperature heat treatment. The environmental barrier coating can further include a bondcoat disposed between the substrate and the hermetic self-sealing layer, a topcoat disposed over the hermetic self-sealing layer, and/or an intermediate layer disposed between the hermetic self-sealing layer and the bondcoat. The intermediate layer can include a barrier material that is substantially inert with respect to silica.
Abstract:
Coating systems for components of a gas turbine engine, such as a compressor blade tip, are provided. The coating system can include a ceramic material disposed along the compressor blade tip and may be used with a bare compressor casing. The ceramic coating is harder than the bare compressor casing and can reduce the rub ratio thereby increasing the lifetime of the compressor blades. Methods are also provided for applying the coating system onto a compressor blade.
Abstract:
A turbine system including a sealing component is presented. The sealing component is positioned in a gap between adjacent turbine components of the turbine system. The sealing component includes a metallic shim including a high-temperature-resistant alloy in a single crystal form. A turbine shroud assembly including the sealing component is also presented.
Abstract:
A method for coating a surface of a substrate is provided. The method includes providing a suspension or a precursor comprising feedstock material suspended in a liquid medium. Further, the method includes spraying the suspension or the precursor onto the surface at a spray angle less than about 75 degrees to a tangent of the surface.
Abstract:
Articles for high temperature service, especially where enhanced strain tolerance coupled with resistance to ingested dust and debris (CMAS) is desirable, are provided herein. The article comprises a substrate and a multi-layered coating system disposed over the substrate. The coating system comprises a first layer comprising a first material and a second layer comprising a second material, with the first layer disposed between the second layer and the substrate. The second material is more resistant to infiltration by a nominal CMAS composition relative to 8 weight percent yttria-stabilized zirconia at a temperature of 1300 degrees Celsius. The second layer comprises a plurality of through-thickness cracks, wherein at least 90 percent of the cracks have a mean crack opening displacement, measured in a distal surface region, of up to about 5 micrometers.
Abstract:
A method of forming an article includes forming a silicon-containing layer on a silicon-containing region of a surface of a substrate of the article; forming a plurality of channels and ridges in the silicon-containing layer; and forming at least one outer layer overlying the surface of the silicon-containing region. The plurality of channels and ridges may be formed by adding silicon-containing material to the silicon-containing layer. The channels and ridges may be formed by subtracting material from the silicon-containing layer. The channels and ridges may be formed by forming channels or grooves in the silicon-containing region of the surface of the substrate prior to formation of the silicon-containing layer.