CMAS resistant thermal barrier coatings

    公开(公告)号:US10179945B2

    公开(公告)日:2019-01-15

    申请号:US14107225

    申请日:2013-12-16

    Abstract: The present application provides Calcia-Magnesia-Alumina-Silica (CMAS) (or molten silicate) resistant thermal barrier coatings (TBC). The coatings include elongate growth domains of non-equiaxed, randomly arranged overlapping grains or splats. The elongate growth domains include overlapping individual, randomly distributed splats of tough and soft phases. In some embodiments, the elongate growth domains are formed via air plasma spray. In some embodiments, the tough phases are at least partially stabilized zirconia and/or hafnia compositions, and the soft phases are CMAS (or molten silicate) reactive or resistant compositions. Within each elongate growth domain, the mixture of the tough and soft phases act together to limit penetration of CMAS and also provide sufficient domain toughness to minimize cracking forces produced during crystallization of infiltrated CMAS. The soft phases may react with the CMAS and increase its melting point, increase its viscosity, and reduce the destabilization of the tough phases.

    ARTICLES FOR HIGH TEMPERATURE SERVICE AND METHOD FOR MAKING
    5.
    发明申请
    ARTICLES FOR HIGH TEMPERATURE SERVICE AND METHOD FOR MAKING 有权
    高温服务和制造方法的文章

    公开(公告)号:US20160177746A1

    公开(公告)日:2016-06-23

    申请号:US14576760

    申请日:2014-12-19

    Abstract: Articles, such as components for high temperature turbomachinery components, include one or more coatings bearing certain perovskite compositions resistant to incursion by liquid calcium-magnesium-aluminum-silicon-oxide (CMAS) materials during service. The CMAS-reactive material includes a perovskite-structured oxide, which comprises a) a rare earth element, b) niobium, tantalum or a combination of tantalum and niobium, and c) oxygen. The CMAS-reactive material is present in an effective amount to react with a CMAS composition at an operating temperature, thereby forming a reaction product having one or both of melting temperature and viscosity greater than that of the CMAS composition.

    Abstract translation: 诸如用于高温涡轮机组件的部件的制品包括一种或多种在使用期间承载某种钙钛矿组合物以耐受液态钙镁 - 铝 - 氧化硅(CMAS)材料侵入的涂层。 CMAS反应性材料包括钙钛矿结构氧化物,其包括a)稀土元素,b)铌,钽或钽和铌的组合,以及c)氧。 CMAS反应性材料以有效量存在,以在操作温度下与CMAS组合物反应,从而形成具有比CMAS组合物的熔融温度和粘度更大的熔融温度和粘度中的一个或两个的反应产物。

    Article with thermal barrier coating and method for making

    公开(公告)号:US10822696B2

    公开(公告)日:2020-11-03

    申请号:US15378232

    申请日:2016-12-14

    Abstract: An article for service at high temperatures comprises a substrate comprising a first region and a second region; and a coating disposed over the substrate. The coating comprises a first portion disposed over the first region of the substrate and a second portion disposed over the second region of the substrate. The coating includes a layer comprising a ceramic material and further including a quantity of surface-connected voids, and a protective agent is disposed within at least some of the surface-connected voids of the layer. Within the first portion, the agent is present within the layer at a concentration of less than or equal to 4 percent by volume of the layer exclusive of the voids, while, within the second portion, the agent is present within the layer at a concentration up to the carrying capacity of the layer. Methods for forming the article are also presented.

    ARTICLE FOR HIGH TEMPERATURE SERVICE
    10.
    发明申请
    ARTICLE FOR HIGH TEMPERATURE SERVICE 审中-公开
    高温服务条款

    公开(公告)号:US20150159507A1

    公开(公告)日:2015-06-11

    申请号:US14098864

    申请日:2013-12-06

    Abstract: Articles for high temperature service, especially where enhanced strain tolerance coupled with resistance to ingested dust and debris (CMAS) is desirable, are provided herein. The article comprises a substrate and a multi-layered coating system disposed over the substrate. The coating system comprises a first layer comprising a first material and a second layer comprising a second material, with the first layer disposed between the second layer and the substrate. The second material is more resistant to infiltration by a nominal CMAS composition relative to 8 weight percent yttria-stabilized zirconia at a temperature of 1300 degrees Celsius. The second layer comprises a plurality of through-thickness cracks, wherein at least 90 percent of the cracks have a mean crack opening displacement, measured in a distal surface region, of up to about 5 micrometers.

    Abstract translation: 具有耐高温性能的产品,特别是在增加耐应变性以及耐吸收性粉尘和碎屑(CMAS)的情况下,本文提供了这些。 该制品包括基底和设置在基底上的多层涂层系统。 该涂层系统包括包含第一材料的第一层和包含第二材料的第二层,其中第一层设置在第二层和衬底之间。 在1300摄氏度的温度下,第二种材料相对于8重量%的氧化钇稳定的氧化锆,更能抵抗标称CMAS组合物的渗透。 第二层包括多个贯穿厚度的裂缝,其中至少90%的裂纹具有高达约5微米的在远端表面区域中测得的平均裂纹开口位移。

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