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33 条记录 (耗时 0.023 秒)

    Process for the preparation of polyurea greases
    13.
    发明授权
    Process for the preparation of polyurea greases 失效
    聚脲润滑脂的制备工艺

    公开(公告)号：US5314982A

    公开(公告)日：1994-05-24

    申请号：US945867

    申请日：1992-09-17

    申请人： Christian Rasp ,  Ralf Timmermann ,  Hermann Perrey ,  Bernhard Lehmann ,  Siegfried Kussi

    发明人： Christian Rasp ,  Ralf Timmermann ,  Hermann Perrey ,  Bernhard Lehmann ,  Siegfried Kussi

    IPC分类号： C08G18/32 ,  C10M119/24 ,  C10N20/06 ,  C10N50/10 ,  C10N70/00 ,  C08G18/08

    CPC分类号： C08G18/3228 ,  C08G18/2865 ,  C10M119/24 ,  C10M2217/042 ,  C10M2217/043 ,  C10N2220/02

    摘要： The invention relates to a new three-part process, which can also be employed on a large industrial scale, for the preparation of polyurea lubricating greases, which is characterised(a) in that polyureas which carry oleophilic groups are prepared by reaction of diisocyanates with amines either in the absence of a solvent on a reaction screw at 80.degree.-120.degree. C., preferably at 85.degree.-95.degree. C., (variant A) or in a toluene medium at 20.degree.-80.degree. C., preferably at 30.degree.-60.degree. C., (variant B),(b) in that, after complete reaction, the polyureas prepared according to (a) are ground in the solid, dry state to give powders (at least 70% by weight of the powder having particle sizes of about 100-400.mu.) and(c) in that the ground crude product, after being made into a "paste" (wetted) at elevated temperature in the base oil employed (10-30 minutes at 140.degree.-180.degree. C.) and cooled again to room temperature, is processed to a grease by complete homogenisation--if appropriate in several passes--in a high-pressure homogeniser under a pressure of 400-1,500 bar (spontaneous heating occurring up to about 100.degree. C.),greases having readily reproducible and essentially the same properties as in the case of the previously customary in situ manufacture being produced.

    摘要翻译： 本发明涉及一种新的三部分方法，其也可用于大型工业规模，用于制备聚脲润滑脂，其特征在于（a）通过二异氰酸酯与二异氰酸酯反应制备携带亲油基团的聚脲 在80°-120℃，优选85℃-95℃，（变体A）或在20-80℃的甲苯介质中，在反应螺杆上不存在溶剂的胺，优选 在30°-60℃，（变体B），（b），完全反应后，根据（a）制备的聚脲在固体，干燥状态下研磨，得到粉末（至少70重量％ 的颗粒大小为100-400微米的粉末）和（c）因为所研磨的粗产物在所用基础油中在升高的温度下制成“糊”（润湿）（在140℃下10-30分钟 DEG-180℃），并再次冷却至室温，通过完全均化（如果合适的话）在几种情况下加工成润滑脂 在400-1,500巴的压力（自发加热直到约100℃）下进入高压均化器，具有与先前常规原位制造情况相同的容易重复性和基本上相同性质的润滑脂 生产。

    Immobilization of biological material within a polymer matrix
    15.
    发明授权
    Immobilization of biological material within a polymer matrix 失效
    在聚合物基质内固定生物材料

    公开(公告)号：US4774178A

    公开(公告)日：1988-09-27

    申请号：US727693

    申请日：1985-04-26

    申请人： Peter Egerer ,  Wilfried Haese ,  Hermann Perrey ,  Gunter Schmidt-Kastner

    发明人： Peter Egerer ,  Wilfried Haese ,  Hermann Perrey ,  Gunter Schmidt-Kastner

    IPC分类号： C12N11/04 ,  C12N11/08 ,  C12P19/24 ,  C12P1/00 ,  C07K17/08

    CPC分类号： C12N11/08 ,  C12N11/04 ,  C12P19/24 ,  Y10S530/817

    摘要： Biological material such as microorganisms is immobilized by polymerizing in the presence of the biological material a readily soluble polyetherpolyol having some hydroxyl groups esterified with acrylic and/or methacrylic acid and remaining hydroxyl groups reacted with an isocyanate group-containing derivative of an unsaturated carboxylic acid or a polyfunctional isocyanate. Preferably, the isocyanate derivative of an unsaturated carboxylic acid is isocyanatoethyl acrylate, isocyanatoethyl methacrylate of 4-isocyanato-3-methyl-2-butyl-acrylate and the polyfunctional isocyanate is a diisocyanate or polyisocyanate. Beads can be produced by forming droplets in a water-immiscible medium and polymerizing. Polymerization can be carried out under inert gas in the presence of radical initiators or by irradiation with actinic light.

    摘要翻译： 生物材料如微生物通过在生物材料存在下聚合来固定，其中具有一些羟基的丙烯酸和/或甲基丙烯酸酯化的残留羟基和与不饱和羧酸的含异氰酸酯基的衍生物反应的残留羟基的易溶聚醚多元醇或 多官能异氰酸酯。 优选地，不饱和羧酸的异氰酸酯衍生物是丙烯酸异氰酸根合乙酯，甲基丙烯酸异氰酸根合乙酯，4-异氰酸基-3-甲基-2-丁基 - 丙烯酸酯，多官能异氰酸酯是二异氰酸酯或多异氰酸酯。 可以通过在与水不混溶的介质中形成液滴并聚合来制备珠粒。 聚合反应可以在惰性气体下，在自由基引发剂的存在下进行，也可以通过光化光照射进行。

    Fungicidal phosphorylated azolyl derivatives
    16.
    发明授权
    Fungicidal phosphorylated azolyl derivatives 失效
    杀真菌性磷酸化唑基衍生物

    公开(公告)号：US4535074A

    公开(公告)日：1985-08-13

    申请号：US593323

    申请日：1984-03-26

    申请人： Reinhard Preuss ,  Hermann Perrey ,  Helmut Ritter ,  Paul Reinecke ,  Wilhelm Brandes

    发明人： Reinhard Preuss ,  Hermann Perrey ,  Helmut Ritter ,  Paul Reinecke ,  Wilhelm Brandes

    IPC分类号： A01N57/32 ,  A01N57/24 ,  C07F9/6506 ,  C07F9/6518 ,  C07F9/65

    CPC分类号： A01N57/24 ,  C07F9/65061 ,  C07F9/65181

    摘要： Fungicidally active novel phosphorylated azolyl derivatives of the formula ##STR1## in which A represents a nitrogen atom or the CH group,R represents optionally substituted phenyl or the grouping ##STR2## wherein X and Y are identical or different and represent hydrogen or halogen,R.sup.1 represents hydrogen andR.sup.2 represents hydrogen, optionally substituted phenoxy or optionally substituted benzyl, orR.sup.1 and R.sup.2 together represent the grouping .dbd.CH--Z, wherein Z represents optionally substituted cycloalkyl or optionally substituted phenyl,R.sup.3 represents alkyl, optionally substituted phenyl or optionally substituted benzyl,R.sup.4 represents hydrogen or alkyl andR.sup.5 represents hydrogen or alkyl,or salts or addition products thereof with metal salts.

    摘要翻译： 其中A表示氮原子或CH基团，R表示任选取代的苯基或分组，其中X和Y相同或不同，表示氢或卤素，R1， 表示氢，R 2表示氢，任选取代的苯氧基或任选取代的苄基，或R 1和R 2一起代表基团= CH-Z，其中Z表示任选取代的环烷基或任选取代的苯基，R 3表示烷基，任选取代的苯基或任选取代的苄基 R4代表氢或烷基，R5代表氢或烷基，或其盐或其加成产物与金属盐。