公开(公告)号：US09045565B2

公开(公告)日：2015-06-02

申请号：US13390733

申请日：2010-08-17

Applicant: Helmut Ritter ,  Bernd Mueller ,  Dirk-Henning Menz

Inventor： Helmut Ritter ,  Bernd Mueller ,  Dirk-Henning Menz

IPC: C08B13/00 ,  A61L27/20 ,  C08B11/20 ,  C08L1/32 ,  C09K19/36 ,  C09K19/38 ,  C08B15/00 ,  A61K9/00

CPC classification number: C08B13/00 ,  A61K9/0051 ,  A61L27/20 ,  C08B11/20 ,  C08B15/00 ,  C08L1/32 ,  C09K19/36 ,  C09K19/3819 ,  C08L1/28

Abstract: The invention relates to modified polysaccharide ethers having a weight-averaged molecular weight of 40,000 to 500,000 g/mole, zero shear viscosity of more than 10 Pa·s, and pseudo-plasticity of more than 20. These modified polysaccharide ethers are obtainable by reacting cellulose-based polysaccharide ether(s) with at least one mesogenic modification agent or modified polysaccharide ethers, obtainable by reacting polysaccharide ether(s) selected from hydroxypropylmethyl cellulose (HPMC), hydroxyethylmethyl cellulose (HEMC), methyl cellulose, and cellulose ethers with methyl and/or ethyl and/or propyl groups and mixtures thereof, with at least one mesogenic modification agent. These substances can be used to produce gel-like to stable aqueous preparations having viscoelastic flow properties, which are suited for use in the human body, particularly within the scope of ophthalmologic procedures.

Abstract translation: 本发明涉及重均分子量为40,000至500,000g / mol，零剪切粘度大于10Pa·s，假塑性大于20的改性多糖醚。这些改性多糖醚可通过使 通过使选自羟丙基甲基纤维素（HPMC），羟乙基甲基纤维素（HEMC），甲基纤维素和纤维素醚的多糖醚与甲基的纤维素醚反应获得的具有至少一种介晶改性剂或改性多糖醚的纤维素基多糖醚 和/或乙基和/或丙基及其混合物与至少一种介晶改性剂。 这些物质可以用于制备具有粘弹性流动性的稳定的水性制剂，其适用于人体，特别是在眼科手术范围内。

公开(公告)号：US20140350205A1

公开(公告)日：2014-11-27

申请号：US14115539

申请日：2012-05-02

Applicant: Alexander Lerch ,  Manfred Schade ,  Alexander Burkhart ,  Helmut Ritter

Inventor： Alexander Lerch ,  Manfred Schade ,  Alexander Burkhart ,  Helmut Ritter

IPC: C08F220/58

CPC classification number: C08F220/58 ,  A61K8/8158 ,  A61K9/0014 ,  A61K2800/10 ,  A61K2800/48 ,  A61Q19/00 ,  C04B24/163 ,  C04B24/2652 ,  C04B28/04 ,  C04B2103/22 ,  C04B2103/44 ,  C04B2111/00672 ,  C08F220/36 ,  C08F220/38 ,  C08F2220/387 ,  C08F2220/585 ,  C08F2500/19 ,  C09K3/00 ,  C09K8/24 ,  C08F222/1006 ,  C04B14/06 ,  C04B24/383

Abstract: The present invention relates to thickener polymers which comprise the following structural elements 1-3: a) as structural feature 1 at least one betainic monomer unit according to the formula below with a proportion by weight of from 0.1 to 99.9% by weight, based on the copolymer in which the mutually independent definitions are as follows: m=integer≧1; R1═H, C1-3 alkyl, —COOH; R2═H, C1-3 alkyl; R3=n- or isoalkylene of the formula —(CxH2x)—, in which x is an integer from 1 to 30; R4=—H, cycloalkyl, n- or isoalkyl, aryl; R5=n- or isoalkylene of the formula —(CyH2y)—, in which y is an integer from 1 to 30; A=—S—, —O—, —NR2, in which R2═H, C1-3 alkyl; b) as structural feature 2 at least one anionically charged monomer unit according to the following formula with a proportion by weight of from 0.1 to 99.9% by weight, based on the copolymer in which the mutually independent definitions are: l=integer≧1; R1═H, C1-3 alkyl, —COOH; R2═H, C1-3 alkyl; R6=—OH, —OOH, —SH, —(CxH2x)—COOH, —(CxH2x)—SO3H, —N (R2)—(CxH2x)—SO3H, in which —(CxH2x)—=n- or isoalkylene and x is an integer from 1 to 30; c) optionally as structural feature 3 one or more non-ionic comonomer units with a proportion by weight of from 0 to 50% by weight, based on the copolymer. When compared with the prior art, the thickener polymers have increased shear resistance in aqueous formulations.

Abstract translation: 本发明涉及包含以下结构单元1-3的增稠剂聚合物：a）作为结构特征1，根据下式的至少一种甜菜碱单体单元，其重量比为0.1至99.9重量％，基于 其中相互独立定义的共聚物如下：m =整数≧1; R1 = H，C1-3烷基，-COOH; R2 = H，C1-3烷基; R3 =式 - （CxH2x） - 的n-或异亚烷基，其中x为1至30的整数; R4 = -H，环烷基，正或异烷基，芳基; R5 =式 - （CyH2y） - 的n-或异亚烷基，其中y为1至30的整数; A = -S-，-O-，-NR2，其中R2 = H，C1-3烷基; b）结构特征2至少一个根据下式的阴离子带电单体单元，其重量比为0.1至99.9重量％，基于相互独立定义的共聚物：l =整数≥1; R1 = H，C1-3烷基，-COOH; R2 = H，C1-3烷基; R6 = -OH，-OOH，-SH， - （CxH2x）-COOH， - （CxH2x）-SO3H，-N（R2） - （CxH2x）-SO3H，其中 - （CxH2x） - = x是1至30的整数; c）任选地作为结构特征3一种或多种基于共聚物的重量比为0至50重量％的非离子共聚单体单元。 当与现有技术相比时，增稠剂聚合物在水性配方中具有增加的抗剪切性。

公开(公告)号：US08883931B2

公开(公告)日：2014-11-11

申请号：US12747582

申请日：2008-12-10

Applicant: Hakan Cinar ,  Helmut Ritter

Inventor： Hakan Cinar ,  Helmut Ritter

IPC: C08C19/22 ,  C08L67/00 ,  C08G18/10 ,  C09D5/03 ,  C08K5/00 ,  C09D5/34 ,  C08K5/32 ,  C09D7/00 ,  C07C291/02

CPC classification number: C08K5/32 ,  C07C291/02 ,  C08K5/0025 ,  C09D5/033 ,  C09D5/34 ,  C09D7/42

Abstract: The present invention relates to polyfunctional nitrones (optionally in the form of nitrone-terminated polymers) and to their use as crosslinking agents and matting agents, preferably for producing stable molding compounds, knifing fillers, and use thereof in inks, coatings, and adhesives. Low crosslinking temperatures characterize the invention. Through the use of polyfunctional nitrones it is possible for all unsaturated polymers to be cured, solidified and/or structured at low temperatures, preferably without use of a catalyst. Depending on the amount of nitrone-terminated polymers and/or low molecular mass polyfunctional nitrone used it is possible to exert a strong influence over the optical and the mechanical properties of the coated surfaces. By optical properties are meant, among others, the gloss of the coating systems and the surface structuring, e.g., the matte effect.

Abstract translation: 本发明涉及多官能硝酮（任选以硝酮封端的聚合物的形式）及其作为交联剂和消光剂的用途，优选用于制备稳定的模塑料，切割填料及其在油墨，涂料和粘合剂中的用途。 低交联温度表征本发明。 通过使用多官能硝酸盐，所有不饱和聚合物可以在低温下固化，固化和/或结构化，优选不使用催化剂。 取决于所使用的硝酮封端的聚合物和/或低分子量多官能硝酮的量，可能对涂覆表面的光学和机械性能产生强烈的影响。 光学性质尤其是涂层体系的光泽度和表面结构，例如无光泽效应。

公开(公告)号：US08729207B2

公开(公告)日：2014-05-20

申请号：US13177867

申请日：2011-07-07

Applicant: Christian Hartung ,  Michael Ferenz ,  Wilfried Knott ,  Helmut Ritter ,  Michael Fiedel

Inventor： Christian Hartung ,  Michael Ferenz ,  Wilfried Knott ,  Helmut Ritter ,  Michael Fiedel

IPC: C08G77/445

CPC classification number: C08G77/445 ,  C08L83/10

Abstract: The invention relates to new types of polyester-polysiloxane block copolymers, to processes for their preparation and to their use.

Abstract translation: 本发明涉及新型的聚酯 - 聚硅氧烷嵌段共聚物，其制备方法和用途。

公开(公告)号：US20130289216A1

公开(公告)日：2013-10-31

申请号：US13988049

申请日：2011-12-20

Applicant: Joachim E. Klee ,  Helmut Ritter ,  Maximilliam Maier ,  Julia Gansel ,  Andreas Facher ,  Oliver Eelsner ,  Sven Pohle

Inventor： Joachim E. Klee ,  Helmut Ritter ,  Maximilliam Maier ,  Julia Gansel ,  Andreas Facher ,  Oliver Eelsner ,  Sven Pohle

IPC: A61K6/083

CPC classification number: A61K6/0835 ,  C08F8/00 ,  C08F8/12 ,  C08F8/46 ,  C08F220/06 ,  C08F220/18 ,  C08F220/12 ,  C08L33/08 ,  C08L33/10 ,  C08L33/26

Abstract: A process for producing a water-soluble, hydrolysis-stable, polymerizable polymer, comprising a) a step of copolymerizing a mixture comprising (i) a first copolymerizable monomer comprising at least one optionally protected carboxylic acid group and a first polymerizable organic moiety, and (ii) a second copolymerizable monomer comprising one or more optionally protected primary and/or secondary amino groups and a second polymerizable organic moiety, for obtaining an amino group containing copolymer; b) a step of coupling to the amino group containing copolymer a compound having a polymerizable moiety and a functional group reactive with an amino group of repeating units derived from the second copolymerizable monomer in the amino group containing copolymer obtained in the first step wherein the optionally protected amino group is deprotected, so that polymerizable pendant groups are linked to the backbone by hydrolysis-stable linking groups, and, optionally, a step of deprotecting the protected carboxylic acid group after step (a) or step (b), for obtaining a polymerizable polymer.

Abstract translation: 一种制备水溶性，水解稳定的可聚合聚合物的方法，包括：a）使包含（i）包含至少一个任选保护的羧酸基团的第一可共聚单体和第一可聚合有机部分的混合物共聚的步骤，以及 （ii）包含一个或多个任选保护的伯和/或仲氨基和第二可聚合有机部分的第二可共聚单体，用于获得含氨基的共聚物; b）在第一步骤中获得的含氨基的共聚物中偶联到具有可聚合部分的化合物和与衍生自第二可共聚单体的重复单元的氨基反应的官能团的步骤，其中任选地 保护的氨基被脱保护，使得可聚合侧基通过水解稳定的连接基团连接到骨架上，并且任选地在步骤（a）或步骤（b）之后将保护的羧酸基脱保护的步骤，以获得 可聚合聚合物。

公开(公告)号：US08101785B2

公开(公告)日：2012-01-24

申请号：US12444669

申请日：2007-10-05

Applicant: Matthias Krull ,  Roman Morschhaeuser ,  Peter Klug ,  Alexander Lerch ,  Christoph Kayser ,  Helmut Ritter ,  Sarah Schmitz

Inventor： Matthias Krull ,  Roman Morschhaeuser ,  Peter Klug ,  Alexander Lerch ,  Christoph Kayser ,  Helmut Ritter ,  Sarah Schmitz

IPC: C07C231/00 ,  B01J19/00

CPC classification number: C07C231/02 ,  C07C233/18

Abstract: The invention relates to a method for producing fatty acid alkanol amides by reacting at least one amine that contains at least one primary or secondary amino group and at least one hydroxyl group with at least one fatty acid to form an ammonium salt, said ammonium salt being subsequently converted into the alkanol amide by means of microwave radiation.

Abstract translation: 本发明涉及一种生产脂肪酸链烷醇酰胺的方法，该方法是使至少一种含有至少一个伯或仲氨基和至少一个羟基的胺与至少一种脂肪酸反应形成铵盐，所述铵盐为 随后通过微波辐射转化成链烷醇酰胺。

公开(公告)号：US20120010302A1

公开(公告)日：2012-01-12

申请号：US13177867

申请日：2011-07-07

Applicant: Christian HARTUNG ,  Michael Ferenz ,  Wilfried Knott ,  Helmut Ritter ,  Michael Fiedel

Inventor： Christian HARTUNG ,  Michael Ferenz ,  Wilfried Knott ,  Helmut Ritter ,  Michael Fiedel

IPC: A61K8/90 ,  C08G77/08 ,  A61K47/34 ,  C08L67/04 ,  C11D3/37 ,  C08G77/445 ,  C09D183/10

CPC classification number: C08G77/445 ,  C08L83/10

Abstract: The invention relates to new types of polyester-polysiloxane block copolymers, to processes for their preparation and to their use.

Abstract translation: 本发明涉及新型的聚酯 - 聚硅氧烷嵌段共聚物，其制备方法和用途。

公开(公告)号：US20110028667A1

公开(公告)日：2011-02-03

申请号：US12746895

申请日：2008-12-05

Applicant: Helmut Ritter ,  Daniel Schmitz ,  Juergen Nachbaur

Inventor： Helmut Ritter ,  Daniel Schmitz ,  Juergen Nachbaur

IPC: C08F224/00

CPC classification number: C08F224/00 ,  A61L27/16 ,  A61L2430/16 ,  C08F220/28 ,  C08L33/08

Abstract: The invention relates to a copolymer, which includes 20 to 95 percent by weight, based on the total weight of the copolymer, of structural units derived from at least one hydrophilic monomer, and 5 to 80 percent by weight, based on the total weight of the copolymer, of structural units derived from at least one monomer according to the general formula I wherein R1, R2 and R3 each independently of each other denote hydrogen or alkyl-, Y: denotes O or NR4 with R4 selected from hydrogen or alkyl-, X: denotes O, S, SO or SO2, S denotes a structural unit selected from CHR5 or (CHR5CHR5O)iCH2, wherein all of the R5 each independently of each other denote hydrogen or alkyl-, n and i independently of each other denote an integer between 1 and 10 and m denotes an integer between 2 and 6, and wherein the copolymer has a water content from 1 to 59 percent by weight based on the total weight of the copolymer. Furthermore, the invention relates to an ophthalmologic composition.

Abstract translation: 本发明涉及一种共聚物，其包含基于共聚物总重量的20至95重量％的衍生自至少一种亲水性单体的结构单元和基于总重量的5-80重量％ 衍生自根据通式I的至少一种单体的结构单元的共聚物，其中R 1，R 2和R 3各自彼此独立地表示氢或烷基 - ，Y表示O或NR 4，其中R 4选自氢或烷基 - ， X表示O，S，SO或SO 2，S表示选自CHR 5或（CHR 5 CHR 5 O）i CH 2的结构单元，其中所有的R 5各自独立地表示氢或烷基，n和i彼此独立地表示 1〜10的整数，m表示2〜6的整数，共聚物的共聚物的总重量为1〜59重量％。 此外，本发明涉及眼科组合物。

公开(公告)号：US20100311863A1

公开(公告)日：2010-12-09

申请号：US12859052

申请日：2010-08-18

Applicant: Norbert Moszner ,  Helmut Ritter ,  Urs-Karl Fischer ,  Monir Tabatabai ,  Matthias Schaub ,  Andreas Utterodt

Inventor： Norbert Moszner ,  Helmut Ritter ,  Urs-Karl Fischer ,  Monir Tabatabai ,  Matthias Schaub ,  Andreas Utterodt

IPC: A61K6/08

CPC classification number: A61K6/0023 ,  A61K6/0017 ,  A61K6/083 ,  A61K6/087 ,  C08F222/1006 ,  C08L61/14 ,  C08L33/04

Abstract: The present invention relates to dental materials composed of calix[n]arenes and also to the use thereof for cements, composites, adhesives and coating materials in the dental field. The materials include (a) 0.5 to 90% by weight of at least one polymerizable calix[n]arene according to formula (I), (b) 0.01 to 5% by weight of initiator, (c) 0 to 90% by weight of at least one additional monomer which can polymerize under cationic and/or radical conditions and/or which can polymerize by ring opening, (d) 0 to 85% by weight of filler, (e) 0.01 to 5% by weight of additive and (f) 0 to 70% by weight of solvent.

Abstract translation: 本发明涉及由杯形[n]芳烃组成的牙科用材料，以及其在牙科领域中用于粘合剂，复合材料，粘合剂和涂层材料的用途。 这些材料包括：（a）0.5至90重量％的至少一种根据式（I）的可聚合杯[n]芳烃，（b）0.01至5重量％的引发剂，（c）0至90重量％ 的至少一种可在阳离子和/或自由基条件下聚合的另外的单体和/或可以通过开环聚合，（d）0至85重量％的填料，（e）0.01至5重量％的添加剂和 （f）0〜70重量％的溶剂。

公开(公告)号：US20070142588A1

公开(公告)日：2007-06-21

申请号：US10568971

申请日：2004-08-25

Applicant: Jonas Scherble ,  Peter Stein ,  Julian Alupei ,  Helmut Ritter ,  Sabine Schwarz-Barac

Inventor： Jonas Scherble ,  Peter Stein ,  Julian Alupei ,  Helmut Ritter ,  Sabine Schwarz-Barac

IPC: C08F120/00

CPC classification number: C08F220/18 ,  C08F220/54

Abstract: The invention relates to a method for producing polymethacrylimides in two steps: 1) radical copolymerization of (meth)acrylamides (A, (Me,H)HC=CHCONHR2) and alkyl(meth)acrylic esters (B) and optionally further ethylenically unsaturated monomers in the presence of an aqueous solvent. The monomers (A) include, in addition to acrylamide and methacrylamide, (meth)acrylamides that are substituted on their nitrogen group (R2<>H). The monomers (B) are the (meth)acrylic esters of secondary or tertiary alcohols, preferably tert. butylmethacrylate. 2) Thermal or catalytic reaction of the copolymers produced in 1) to polymethacrylimide or for R2<>H to N-substituted polymethacrylimides while alkenes are separated.

Abstract translation: 本发明涉及以下两个步骤制备聚甲基丙烯酰胺的方法：1）（甲基）丙烯酰胺（A，（Me，H）HC = CHCONHR 2）和（甲基）丙烯酸烷基酯（B）和任选的其它烯属不饱和单体 在水溶剂的存在下。 单体（A）除了丙烯酰胺和甲基丙烯酰胺之外还包括在其氮基团（R 2 H）上被取代的（甲基）丙烯酰胺。 单体（B）是仲醇或叔醇的（甲基）丙烯酸酯，优选叔。 甲基丙烯酸丁酯 2）在分离烯烃时，在1）中产生的共聚物与聚甲基丙烯酰亚胺或R2