摘要:
Heat-sensitized polymer latex mixtures, wherein they contain from 0.05 to 10% by weight, based on polymer, of a heat-sensitizer and, as stabilizer, from 0.1 to 10% by weight, based on polymer, of a sulphonamide corresponding to the general formula ##STR1## IN WHICH R represents alkyl, chloroalkyl or cycloalkyl with 8 to 30 carbon atoms or alkaryl with 10 to 30 carbon atoms,R.sub.1 and R.sub.2 independently of one another represent hydrogen, chloromethyl, methyl, ethyl, phenyl;m is an integer from 0 to 50 andR.sub.3 represents hydrogen, alkyl, alkaryl, aryl or --(CHR.sub.1 --CHR.sub.2 --O).sub.m H with the above meanings for R.sub.1, R.sub.2 and m.
摘要:
A method for the production of dipped articles of rubber latices, wherein rubber latices are used which have an average rubber-particle diameter of no more than 200 nm and contain a rubber having a Defo value of less than 2000, the rubber latices having been prepared by the polymerization of a monomer mixture of 85 to 50 parts by weight of butadiene and/or isoprene, 10 to 40 parts by weight of acrylonitrile or methacrylonitrile, 0 to 40 parts by weight of styrene, 0 to 10 parts by weight of acrylamide, methacrylamide and/or their methylol derivatives and 0.1 to 10 parts by weight of an .alpha.-.beta.-unsaturated carboxylic acid, in aqueous emulsion in the presence of 0.5 to 6.0% by weight, based on monomer, of an alkylaryl sulphonate and 0 to 5% by weight, based on monomer, of one or more other surface-active substances as emulsifier, at a pH-value below 7, and wherein the pH of the latex is adjusted to a value above 8 with an alkali hydroxide on completion of polymerization and the dipped article of rubber produced by said method.
摘要:
Low-foam carboxylated styrene-butadiene-latices obtained by the emulsion polymerization of monomer mixtures of:73.5 to 18.5 parts by weight of butadiene;20 to 80 parts by weight of styrene;0 to 10 parts by weight of acrylonitrile;0 to 5 parts by weight of ethylenically unsaturated carboxylic acid amides or methylol derivatives thereof; and1.5 to 10 parts by weight of ethylenically unsaturated carboxylic acids;Wherein the ethylenically unsaturated carboxylic acids consist of a mixture of:1.0 to 4 parts by weight of acrylic acid and0.5 to 6 parts by weight of methacrylic acidAnd wherein less than 0.5 parts by weight of anionic emulsifiers are used for polymerisation. The latices can be used inter alia as an impregnating material for soft non-wovens, cardboards and fiber fleece carpets.
摘要:
Method for coagulating polymer dispersions with heat sensitizing agents which contain specific urethane groups. These new heat sensitizing agents provide at room temperature stable latices which coagulate completely when heated.
摘要:
This invention relates to mixtures of at least one elastomer latex with at least one dispersion of an aromatic polycarbonate, aromatic polyester or aromatic polyester carbonate.
摘要:
Mixtures of ammonia and alkoxylated polysiloxanes may be used as heat sensitizer for rubber latices. The latices thus obtained are stable so that no coagulation occurs even in the event of prolonged storage or under mechanical stressing.
摘要:
Method for coagulating polymer dispersions with heat sensitizing agents which contain specific urethane groups. These new heat sensitizing agents provide at room temperature stable latices which coagulate completely when heated.
摘要:
Synthetic rubber dispersions containing carboxyl groups, free from specks and with little tendency to foaming, with advantages for their technical application contain a copolymer of 0.3 to 1.0 parts by weight of itaconic acid and 99.0 to 99.7 parts by weight of a mixture of 10 to 90 parts by weight of one or more acyclic conjugated dienes having 4 to 9 carbon atoms and 10 to 90 parts by weight of one or more aryl vinyl monomers having 8 to 12 carbon atoms and/or (meth)acrylonitrile, in which the quantity of (meth)acrylonitrile is at most 50 parts by weight and wherein up to 25 parts by weight of the non-dissociating monomers may optionally be replaced by one or more other non-dissociating copolymerizable monomers, which dispersions are stabilized with 0.05 to 0.5% by weight, based on the copolymer, of an anionic emulsifier.